It has been demonstrated that the diffusion couple technique is a powerful and efficient approach in establishing phase relationships of ternary systems. Accurate data on the phase equilibria can be obtained if the ap...It has been demonstrated that the diffusion couple technique is a powerful and efficient approach in establishing phase relationships of ternary systems. Accurate data on the phase equilibria can be obtained if the appropriate alloys are employed as end members of the diffusion couple. It is desirable to combine the diffusion couple technique with an investigation of the afterwards selected equilibrated alloys so that the precision and reliability of the obtained information about a ternary isotherm could be guaranteed.展开更多
The isothermal section of the W-Ni-Cu ternary system at 1017℃ was determined by means of diffusion couple specimens,EMPA and X-ray diffraction.Body-centered tetragonal Ni_4W and orthorhombic NiW but no NiW_2 observed...The isothermal section of the W-Ni-Cu ternary system at 1017℃ was determined by means of diffusion couple specimens,EMPA and X-ray diffraction.Body-centered tetragonal Ni_4W and orthorhombic NiW but no NiW_2 observed in the W-Ni binary sys- tem at this temperature.The solubility ranges of W and Cu in Ni_4W are 16.95- 20.51 at.-% and 0-4.36 at.-%,respectively.The maximum solubility of W in γ(Ni) is 13.11 at.-%.展开更多
基金This work is financially supported by the National Natural Science Foundation of China (No. 50571114) and the Open Project Program of the Key Laboratory of Advanced Materials & Rheological Properties (Xiangtan University), Ministry of Education, China (No. KF0508).
文摘It has been demonstrated that the diffusion couple technique is a powerful and efficient approach in establishing phase relationships of ternary systems. Accurate data on the phase equilibria can be obtained if the appropriate alloys are employed as end members of the diffusion couple. It is desirable to combine the diffusion couple technique with an investigation of the afterwards selected equilibrated alloys so that the precision and reliability of the obtained information about a ternary isotherm could be guaranteed.
文摘The isothermal section of the W-Ni-Cu ternary system at 1017℃ was determined by means of diffusion couple specimens,EMPA and X-ray diffraction.Body-centered tetragonal Ni_4W and orthorhombic NiW but no NiW_2 observed in the W-Ni binary sys- tem at this temperature.The solubility ranges of W and Cu in Ni_4W are 16.95- 20.51 at.-% and 0-4.36 at.-%,respectively.The maximum solubility of W in γ(Ni) is 13.11 at.-%.
