Symmetrical diynes were synthesized by ligand-free copper-catalyzed homocoupling reaction of 1,1-dibromo-1- alkenes using a DBU/DMSO system at room temperature in good to excellent yields.
基金Project supported by the National Natural Science Foundation of China (No. 30873153), and the Key Projects of Shanghai in Biomedical (No. 08431902700).
文摘Symmetrical diynes were synthesized by ligand-free copper-catalyzed homocoupling reaction of 1,1-dibromo-1- alkenes using a DBU/DMSO system at room temperature in good to excellent yields.