Geochemical characteristics of REY, Li, Ga trace elements in the No. 9 coal seam of the Daheng mine, Ningwu coalfield, Shanxi Province, China

To understand the geochemical characteristics of the No.9 coal in the Daheng Mine of the Ningwu coalfield,the trace element analysis was conducted through X-ray fluorescence spectroscopy(XRF)and inductively coupled plasma mass spectrometry(ICP-MS).The sedimentary environment was discussed according to the element geochemical parameters.The results show that Li,Ga,Hf,Zr,Nb,Th,and Ta are slightly enriched in the No.9 coal of Daheng Mine.The average value of the rare earth elements and yttrium(ΣREY)in coal here is 144.20μg/g(excluding parting),which is higher than the average value ofΣREY in the world’s coal and China’s coal.The light rare earth elements(LREY)are enriched.The content of Eu was 0.12‒2.10μg/g with an average of 0.57μg/g,and the Eu is obviously negatively abnormal.Most of the trace elements in the coal are positively correlated with the ash content,which shows that the occurrence of these trace elements is related to inorganic minerals.The results of sequential chemical extraction experiments show that rare earth elements mainly exist in coal in the form of aluminosilicate.The value of the Sr/Ba and the content of S reflect that the coal-forming environment was influenced by seawater.The values of V/Cr and Ni/Co reflect that the peat swamp is in an anaerobic environment and a strongly reducing environment during the coal-forming period.

Analysis of the dominant diseases and clinical application characteristics of traditional Chinese cutting therapy based on data mining technology

Objective: To analyze the advantages of Traditional Chinese Cutting Therapy at the present stage and the characteristics of clinical research and application, so as to provide a basis for clinical treatment and research. Methods: Search the Chinese and English databases of relevant literatures on Traditional Chinese Cutting Therapy, and make statistics and Analysis on the distribution, types, distribution, indications and dominant diseases, the number of cases, clinical efficiency, intervention measures and operation sites of the published literatures. Results: A total of 311 articles were included. There are 40 indications for Traditional Chinese Cutting Therapy at this stage. The dominant diseases are psoriasis, asthma, facial paralysis, rhinitis, neurodermatitis, facial neuritis, chloasma, acne, migraine and insomnia. Traditional Chinese Cutting Therapy is closely related to meridian theory. At present, there are few theoretical and basic studies, the quality of relevant clinical studies is low, and the writing standard of research reports is inadequate. Conclusion: At present, the indications of Traditional Chinese Cutting Therapy are extensive, and the dominant diseases are concentrated, with dermatological diseases and neurological diseases as the main diseases. In the future, we should increase theoretical research and basic research, attach importance to the combination of meridian theory and Traditional Chinese Cutting Therapy, and standardize the implementation of clinical research and the writing of reports.

南祁连盆地木里坳陷中侏罗统烃源岩原始有机碳含量恢复及与微孔隙演化的相关性

泥页岩有机质碳含量(TOC)是页岩油气评价的重要参数之一。然而,受有机质热演化生排烃影响,利用现今TOC评价与预测页岩油气资源时会出现一定的偏差。因此,进行烃源岩原始有机碳恢复对油气资源评价具有重要意义。木里坳陷位于南祁连盆地东北部,陆相中侏罗统广泛分布。中侏罗统为一套湖泊—三角洲相沉积的细粒碎屑岩,发育多套厚层富有机质暗色泥页岩,生烃潜力巨大。该层段内油气资源丰富,页岩有机质从低成熟到高成熟阶段均有分布,为原始有机碳含量的恢复提供了必要条件。以木里坳陷中侏罗统富有机质页岩为研究对象,利用岩石热解数据,采用物质平衡法有机碳恢复模型,对中侏罗统页岩原始有机碳含量进行了恢复。结果表明,中侏罗统页岩原始TOC含量与现今TOC含量的比值介于1.04~1.62之间,且随着热演化程度增高,比值变大。现今TOC含量与有机质孔隙发育之间没有必然的联系,然而,原始TOC含量与现今TOC含量之间的比值可以间接判断页岩有机质微孔隙发育情况。木里坳陷侏罗系页岩有机质类型以Ⅱ型和Ⅲ型为主,热演化参数(T_(max))大于440℃时,烃类转化率和排烃率都大于40%。相比样品矿物(石英和黏土矿物)含量、T_(max)参数和现今TOC含量,原始TOC含量与页岩兰氏体积拟合性更好,结合热解参数T_(max),可以更好地判断页岩油气的吸附能力。因此,开展木里坳陷中侏罗统烃源岩原始有机碳含量恢复的研究,可以为木里坳陷烃源岩评价提供理论基础;同时对木里坳陷油气资源勘探提供新的思路。