PMMA films in the high global chain orientation and nearly random segmental orientation (GOLR) state were prepared by uni-axially drawing at temperatures 20 similar to 30 degrees C above its glass transition temperatu...PMMA films in the high global chain orientation and nearly random segmental orientation (GOLR) state were prepared by uni-axially drawing at temperatures 20 similar to 30 degrees C above its glass transition temperature, T-g, and their isotropic and anisotropic properties were studied. Experimental results show that this kind of amorphous state, the GOLR state, is nearly isotropic in optical birefringence, IR-dichroism and X-ray diffraction patterns, but is very anisotropic in behaviors of thermal expansion, solvent-swelling and stress-strain.展开更多
基金This work is supported by the National Key Projects for Fundamental Research,"Macromolecular Condensed State",the State Science and Technology Commission of China
文摘PMMA films in the high global chain orientation and nearly random segmental orientation (GOLR) state were prepared by uni-axially drawing at temperatures 20 similar to 30 degrees C above its glass transition temperature, T-g, and their isotropic and anisotropic properties were studied. Experimental results show that this kind of amorphous state, the GOLR state, is nearly isotropic in optical birefringence, IR-dichroism and X-ray diffraction patterns, but is very anisotropic in behaviors of thermal expansion, solvent-swelling and stress-strain.
