With the continued depletion of non-renewable energy resources,it is essential to seek new methods of harnessing clean and renewable energy.In this regard,second-generation bioethanol derived from lignocellulosic biom...With the continued depletion of non-renewable energy resources,it is essential to seek new methods of harnessing clean and renewable energy.In this regard,second-generation bioethanol derived from lignocellulosic biomass has attracted increasing attention in recent years.The choice of the pretreatment method of lignocellulose is critical to the subsequent bioconversion processes.Compared with other conventional chemical pretreatment methods,hydrothermal pretreatment is a simple,low-cost,and economically feasible process that requires water as the only reagent.This paper reviews the research efforts that have been made toward hydrothermal pretreatment of lignocellulosic biomass and focuses on the transformations involving cellulose,hemicellulose,and lignin during this process.展开更多
Recalcitrance of lignocellulosic biomass is closely related to the presence of lignin in secondary cell walls,which has a negative effect on enzyme digestibility,biomass-to-biofuels conversion,and chemical pulping.The...Recalcitrance of lignocellulosic biomass is closely related to the presence of lignin in secondary cell walls,which has a negative effect on enzyme digestibility,biomass-to-biofuels conversion,and chemical pulping.The lignification process and structural heterogeneity of the cell wall for various parts of moso bamboo were investigated.There were slight differences among three different column parts of moso bamboo in terms of chemical compositions,including cellulose,hemicelluloses,and lignin.However,the detailed analysis of the fractionated lignin indicated that the acid-soluble lignin was first biosynthesized,and the largest molecular weight value was detected from the bottom part of the moso bamboo,as well as the highest syringyl-to-guaiacyl ratio.Although the main b-O-4 aryl ethers and resinol structures were clearly present in all lignin samples examined by NMR analysis,the relatively small lignin biomacromolecule in the top part of the moso bamboo lead to poor thermal stability.For the bioconversion process,no significant difference was found among all the moso bamboo samples,and the relatively higher hydrolysis efficiency was largely dependent on the low crystallinity of cellulose rather than the degree of lignin biosynthesis.展开更多
基金the financial support from the Beijing Natural Science Foundation (6174046)the Research Fund for the Doctoral Programme of Higher Education of China (20120014120004)
文摘With the continued depletion of non-renewable energy resources,it is essential to seek new methods of harnessing clean and renewable energy.In this regard,second-generation bioethanol derived from lignocellulosic biomass has attracted increasing attention in recent years.The choice of the pretreatment method of lignocellulose is critical to the subsequent bioconversion processes.Compared with other conventional chemical pretreatment methods,hydrothermal pretreatment is a simple,low-cost,and economically feasible process that requires water as the only reagent.This paper reviews the research efforts that have been made toward hydrothermal pretreatment of lignocellulosic biomass and focuses on the transformations involving cellulose,hemicellulose,and lignin during this process.
基金the financial support from the Natural Science Foundation of China(31770622)the Innovation Program of College of Materials Science and Technology
文摘Recalcitrance of lignocellulosic biomass is closely related to the presence of lignin in secondary cell walls,which has a negative effect on enzyme digestibility,biomass-to-biofuels conversion,and chemical pulping.The lignification process and structural heterogeneity of the cell wall for various parts of moso bamboo were investigated.There were slight differences among three different column parts of moso bamboo in terms of chemical compositions,including cellulose,hemicelluloses,and lignin.However,the detailed analysis of the fractionated lignin indicated that the acid-soluble lignin was first biosynthesized,and the largest molecular weight value was detected from the bottom part of the moso bamboo,as well as the highest syringyl-to-guaiacyl ratio.Although the main b-O-4 aryl ethers and resinol structures were clearly present in all lignin samples examined by NMR analysis,the relatively small lignin biomacromolecule in the top part of the moso bamboo lead to poor thermal stability.For the bioconversion process,no significant difference was found among all the moso bamboo samples,and the relatively higher hydrolysis efficiency was largely dependent on the low crystallinity of cellulose rather than the degree of lignin biosynthesis.
