A simple and convenient electrochemical detection cell for capillary electrophoresis is described in this paper. In this cell, alignment of the capillary working electrode with the separation capillary outlet can be a...A simple and convenient electrochemical detection cell for capillary electrophoresis is described in this paper. In this cell, alignment of the capillary working electrode with the separation capillary outlet can be achieved precisely and easily without the aid of the micropositioner or microscope. With end-column detection, the applicability of the cell as an amperometric detector for capillary electrophoresis is demonstrated by running several phenolic compounds in 50 mu m i.d, capillary with a capillary Pt electrode as the working electrode. Results obtained are satisfactory.展开更多
The proposed method of spline wavelet overlapped peaks analysis is based on the model of wavelet multifrequency channel decomposition. If the suitable optimal wavelet basis and frequency scale value are selected, the ...The proposed method of spline wavelet overlapped peaks analysis is based on the model of wavelet multifrequency channel decomposition. If the suitable optimal wavelet basis and frequency scale value are selected, the useful information can be extracted from noised overlapped signal. Then, according to the linear relationship between individual components in blurred version, multiple linear regression in low frequency domain is employed to resolve highly overlapped peaks. The results show that even signal-to-noise (S/N) decreases to 0.2, relative errors of peak intensity are less than 12% and the sum of square deviations Q is less than 0.展开更多
According to the main characteristic of sharp peak, the method of spline wavelet combined with spline interpolation interruption filtering analysis is proposed for a sudden change (an unstable) noised signal and is ap...According to the main characteristic of sharp peak, the method of spline wavelet combined with spline interpolation interruption filtering analysis is proposed for a sudden change (an unstable) noised signal and is applied in V and Mn CCD-ICP-AEC spectral signal. The satisfactory results show that the new technique is effective-on enhancing the clarity and accuracy of an unstable signal.展开更多
文摘A simple and convenient electrochemical detection cell for capillary electrophoresis is described in this paper. In this cell, alignment of the capillary working electrode with the separation capillary outlet can be achieved precisely and easily without the aid of the micropositioner or microscope. With end-column detection, the applicability of the cell as an amperometric detector for capillary electrophoresis is demonstrated by running several phenolic compounds in 50 mu m i.d, capillary with a capillary Pt electrode as the working electrode. Results obtained are satisfactory.
文摘The proposed method of spline wavelet overlapped peaks analysis is based on the model of wavelet multifrequency channel decomposition. If the suitable optimal wavelet basis and frequency scale value are selected, the useful information can be extracted from noised overlapped signal. Then, according to the linear relationship between individual components in blurred version, multiple linear regression in low frequency domain is employed to resolve highly overlapped peaks. The results show that even signal-to-noise (S/N) decreases to 0.2, relative errors of peak intensity are less than 12% and the sum of square deviations Q is less than 0.
文摘According to the main characteristic of sharp peak, the method of spline wavelet combined with spline interpolation interruption filtering analysis is proposed for a sudden change (an unstable) noised signal and is applied in V and Mn CCD-ICP-AEC spectral signal. The satisfactory results show that the new technique is effective-on enhancing the clarity and accuracy of an unstable signal.
