Gaining in-depth insights into the effects of particle shapes and packing style on ethylene oxidation reaction is of paramount industrial importance.In this work,reactor models of five packing structures with differen...Gaining in-depth insights into the effects of particle shapes and packing style on ethylene oxidation reaction is of paramount industrial importance.In this work,reactor models of five packing structures with different particle shapes and three packing structures with different packing styles are established by employing software Blender and COMSOL Multiphysics to explore how the reaction-diffusion behaviors affect ethylene oxidation process.The reliabilities of rigid body dynamics model and particle-resolved reactor model are verified by comparing simulated and experimental pressure drops and ethylene conversions.In all the five packing structures with laminar flow conditions,the high bed porosity and low total particle surface area for the trilobe packing structure give rise to the lowest pressure drop of 27.8 Pa/m,while the internal voids cutting mode provides the excellent heat transfer capacity for the Raschig ring packing structure and the highest ethylene conversion and thereby the highest bed temperature rise of 25.1 K for the four-hole cylinder packing structure.Based on these analyses,changing the packing style to the bottom-up Raschig ring-four hole cylinder packing structure would be a good strategy for the effectively lowered reactor temperature rise by 4.8 K together with the slightly reduced ethylene conversion.展开更多
基金financially supported by the National Key R&D Program of China(grant No.2022YFA1503503)the National Natural Science Foundation of China(grant No.22038003,21922803,22178100 and 22008066)+1 种基金the Innovation Program of Shanghai Municipal Education Commission,the Program of Shanghai Academic/Technology Research Leader(grant No.21XD1421000)the Shanghai Science and Technology Innovation Action Plan(grant No.22JC1403800).
文摘Gaining in-depth insights into the effects of particle shapes and packing style on ethylene oxidation reaction is of paramount industrial importance.In this work,reactor models of five packing structures with different particle shapes and three packing structures with different packing styles are established by employing software Blender and COMSOL Multiphysics to explore how the reaction-diffusion behaviors affect ethylene oxidation process.The reliabilities of rigid body dynamics model and particle-resolved reactor model are verified by comparing simulated and experimental pressure drops and ethylene conversions.In all the five packing structures with laminar flow conditions,the high bed porosity and low total particle surface area for the trilobe packing structure give rise to the lowest pressure drop of 27.8 Pa/m,while the internal voids cutting mode provides the excellent heat transfer capacity for the Raschig ring packing structure and the highest ethylene conversion and thereby the highest bed temperature rise of 25.1 K for the four-hole cylinder packing structure.Based on these analyses,changing the packing style to the bottom-up Raschig ring-four hole cylinder packing structure would be a good strategy for the effectively lowered reactor temperature rise by 4.8 K together with the slightly reduced ethylene conversion.
