Two-dimensional-lag complex logistic map with complex parameters and its encryption application

With the rapid development of internet technology,security protection of information has become more and more prominent,especially information encryption.Considering the great advantages of chaotic encryption,we propose a 2D-lag complex logistic map with complex parameters(2D-LCLMCP)and corresponding encryption schemes.Firstly,we present the model of the 2D-LCLMCP and analyze its chaotic properties and system stability through fixed points,Lyapunov exponent,bifurcation diagram,phase diagram,etc.Secondly,a block cipher algorithm based on the 2D-LCLMCP is proposed,the plaintext data is preprocessed using a pseudorandom sequence generated by the 2D-LCLMCP.Based on the generalized Feistel cipher structure,a round function F is constructed using dynamic S-box and DNA encoding rules as the core of the block cipher algorithm.The generalized Feistel cipher structure consists of two F functions,four XOR operations,and one permutation operation per round.The symmetric dynamic round keys that change with the plaintext are generated by the 2D-LCLMCP.Finally,experimental simulation and performance analysis tests are conducted.The results show that the block cipher algorithm has low complexit,good diffusion and a large key space.When the block length is 64 bits,only six rounds of encryption are required to provide sufficient security and robustness against cryptographic attacks.

Split-Ring Structured All-Inorganic Perovskite Photodetector Arrays for Masterly Internet of Things

Photodetectors with long detection distances and fast response are important media in constructing a non-contact human-machine interface for the Masterly Internet of Things(MIT).All-inorganic perovskites have excellent optoelectronic performance with high moisture and oxygen resistance,making them one of the promising candidates for high-performance photodetectors,but a simple,low-cost and reliable fabrication technology is urgently needed.Here,a dual-function laser etching method is developed to complete both the lyophilic split-ring structure and electrode patterning.This novel split-ring structure can capture the perovskite precursor droplet efficiently and achieve the uniform and compact deposition of CsPbBr3 films.Furthermore,our devices based on laterally conducting split-ring structured photodetectors possess outstanding performance,including the maximum responsivity of 1.44×105 mA W^(−1),a response time of 150μs in 1.5 kHz and one-unit area<4×10-2 mm2.Based on these split-ring photodetector arrays,we realized three-dimensional gesture detection with up to 100 mm distance detection and up to 600 mm s^(−1) speed detection,for low-cost,integrative,and non-contact human-machine interfaces.Finally,we applied this MIT to wearable and flexible digital gesture recognition watch panel,safe and comfortable central controller integrated on the car screen,and remote control of the robot,demonstrating the broad potential applications.

材料、能源、机械工程中高效的电流变技术——从机理到应用

电流变(ER)技术是一种基于电流变效应的先进技术。电流变技术中最常见的材料是电流变液(ERF)。电流变液是一种软物质智能材料,其黏度可以通过施加电场来可逆地调节。电流变液的衍生物、一种新型的电响应软物质材料——电流变弹性体(ERE),由于其不沉降、易封装的优点也得到了越来越多的关注。电流变材料由于其可逆可调、快速响应、低能耗等特性在机械工程中有着广泛的应用。除了基础的电流变材料的合成和应用以外,电流变技术还应用在了能源材料制备、石油运输、储能等诸多领域。电流变技术在能源领域的应用为其在其他领域的潜在应用提供了一个很好的范例。本文结合最新的研究成果,从机理到应用,系统地综述了电流变技术在材料、能源和机械工程等领域的研究现状和未来发展前景。

Robust adaptive control for a nonholonomic mobile robot with unknown parameters

A robust adaptive controller for a nonholonomic mobile robot with unknown kinematic and dynamic parameters is proposed. A kinematic controller whose output is the input of the relevant dynamic controller is provided by using the concept of backstepping. An adaptive algorithm is developed in the kinematic controller to approximate the unknown kinematic parameters, and a simple single-layer neural network is used to express the highly nonlinear robot dynamics in terms of the known and unknown parameters. In order to attenuate the effects of the uncertainties and disturbances on tracking performance, a sliding mode control term is added to the dynamic controller. In the deterministic design of feedback controllers for the uncertain dynamic systems, upper bounds on the norm of the uncertainties are an important clue to guarantee the stability of the closed-loop system. However, sometimes these upper bounds may not be easily obtained because of the complexity of the structure of the uncertainties. Thereby, simple adaptation laws are proposed to approximate upper bounds on the norm of the uncertainties to address this problem. The stability of the proposed control system is shown through the Lyapunov method. Lastly, a design example for a mobile robot with two actuated wheels is provided and the feasibility of the controller is demonstrated by numerical simulations.

多孔电磁波吸收材料

近年来,通过改善孔结构来提升材料的电磁波吸收性能成为研究热点。多孔结构既有利于电磁波进入材料的内部,又能有效地调整材料的电磁参数,提高材料与电磁波间的阻抗匹配,进而增大材料对电磁波的吸收;此外,在电磁波吸收材料中生成的不同尺度的孔隙可以对入射电磁波产生多重散射和反射,延长其传播路径从而增加了损耗过程;同时,多孔材料的相对密度小,为许多性能高但受限于密度太大而不能在电磁波吸收领域高效应用的材料提供了解决问题的途径。基于此,本文综述了零维和三维多孔电磁波吸收材料(PEMAM)的研究现状及亟待解决的问题,同时也展望了多孔电磁波吸收材料未来可能的研究热点及发展方向。

Chlorine capped SnO_2 quantum-dots modi?ed TiO_2 electron selective layer to enhance the performance of planar perovskite solar cells

SnO_2 quantum dots(QDs) ended with chlorine ions are introduced at the interface of spin-coated TiO_2 electron selective layer(ESL)/perovskite to fill the pinholes in the layer and passivate the trapping defects. As a result of the increased interface electron collection and reduced bulk recombination, the planar perovskite solar cell with the QDs modified ESL gives the large power conversion efficiency enhancement from 14.9% to 17.3% and greatly improved stability under the continuous light irradiation.

钙钛矿上单原子位点实现高灵敏定量化表面拉曼增强

表面增强拉曼散射(SERS)是一种快速且无损的化学和生物分子检测技术.高灵敏且定量化的SERS检测技术对其在实际中的应用至关重要,尤其是对生物分子如氨基酸和碱基的便携化检测.但是鲜有技术手段能够实现对这些最基本的生物分子进行高灵敏且定量化的拉曼检测.我们提出了一种无需贵金属的单原子位点修饰芯片策略,用钨单原子氧化物修饰铅卤钙钛矿芯片,实现了多种检测物的高灵敏定量化识别,包括罗丹明、酪氨酸和胞嘧啶.芯片上单原子位点技术能够实现对罗丹明、酪氨酸和胞嘧啶的线性检测,相应的定量化区间分别为:10^(−6)–1 mmol L^(−1),0.06–1 mmol L^(−1)和0.2–45 mmol L^(−1),同时我们的拉曼增强芯片对这三种分子的增强因子在非等离子激元半导体中是最高的.我们通过实验测试结合理论模拟揭示了由可控单原子位点实现拉曼增强的机理:束缚由钙钛矿基底产生的光生电子,同时高效且定量地将这些电子转移到待测分子上.不仅如此,芯片上单原子位点技术可以在便携式拉曼设备下得到与台式拉曼设备类似的增强效果,这意味着这项技术有机会应用于多种生物分子的低成本、广谱、即时检测和体外检测.

Facile fabrication of drug-loaded PEGDA microcapsules for drug evaluation using droplet-based microchip

Droplet-based microfluidic technology can be utilized as a microreactor to prepare novel functional monodisperse microcapsules.In this study,a droplet-based microfluidic chip with surface modification,which allowed the one-step preparation of double emulsion microcapsules.An O/W/O double emulsion using polyethylene(glycol)diacrylate(PEGDA)solution as the intermediate water phase was prepared by regulating the hydrophilicity and hydrophobicity of the chip surface,with PEGDA microcapsules prepared using UV polymerization.And then anti-tumor drug paclitaxel and neurotoxin 6-OHDA were encapsulated in microcapsules for drug and toxicology evaluation,respectively.Compared to controls,drug-loaded mi-crocapsules caused a significant increase in the death rate of PC12 cells.This indicates that the obtained drug-loaded microcapsules could be used in drug evaluation and potentially in drug screening and deliv-ery.

Influence of Dislocation Pile-Up on Main Crack Propagation in Nanocrystals in the Hydrogen Environment

The influence of material micro-defects on the main crack growth under pure shear loading is studied theoretically.The mechanism behind the initiation of micro-cracks and crack propagation induced by dislocation accumulation near the grain boundary(GB)ismainly considered,and the influence of dislocation accumulation on the main crack propagation is analyzed.The research results reveal that the initiation of micro-cracks near the GB is prior to the propagation of the main crack.In a hydrogen environment,hydrogen can cause serious embrittlement of the crack tip and promote crack growth.The energy release rate in the main crack growth direction in the dislocation emission direction is the highest.Therefore,the main crack will eventually merge with the micro-cracks at the GB along the direction of the slip band,resulting in fracture of the crystal material.The research presented in this paper provides some new information for the first stage of crack propagation and contributes to the analysis of the mechanism of crystal metal fracture.