The Baoshan Cu–Pb–Zn deposit, located in the central part of the Qin–Hang belt in South China, is closely related to the granodiorite-porphyry. However, the characteristics and the source of the ore-forming fluid a...The Baoshan Cu–Pb–Zn deposit, located in the central part of the Qin–Hang belt in South China, is closely related to the granodiorite-porphyry. However, the characteristics and the source of the ore-forming fluid are still ubiquitous. According to the crosscutting relationships between veinlets and their mineral assemblages, three stages of hydrothermal mineralization in this deposit were previously distinguished. In this contribution, two different colored fluorites from the major sulfide mineralization stage are recognized:(1) green fluorites coexisting with Pb–Zn ores;and(2) violet fluorites coexisting with pyrite ores. Y/Ho ratios verify the green fluorites and violet fluorites were co-genetic. The fluorites display elevated(La/Yb)Nratios, which decrease from 1201 to 5710 for green fluorites to 689–1568 for violet fluorites, indicating that they precipitated at the early hydrothermal sulfide stage,and Pb–Zn ores crystallized earlier than pyrite ores. The similar Tb/La ratios of the fluorites also indicate that they precipitated at an early stage within a short time. From the green fluorites to violet fluorites, the total rare earth element(ΣREE)concentrationsdecreasefrom1052–1680 ppm to 148–350 ppm, indicating that the green fluorites precipitated from a more acidic fluid. The Eu/Eu*ratios increase from 0.17 to 0.30 for green fluorites to0.29–0.48 for violet fluorites, and the Ce/Ce* ratios decrease from 1.08–1.13 to 0.93–1.11, suggesting a gradual increase in oxygen fugacity(fO_(2)) and pH value of the mineralization fluid. Though the fluorites display similar REE patterns to the granodiorite-porphyry and limestone,the ΣREE concentrations of the fluorites are significantly higher than those of limestone and the granodiorite-porphyry, suggesting that an important undetected non-magmatic source is involved to provide sufficient REE for fluorites. The most plausible mechanism is fluid mixing between magma fluid and an undetected non-magmatic fluid.展开更多
This paper establishes a diagnostic model for assessing the rationality of size structure of urban agglomerations(UAs) in China. The model is designed to determine from a three-dimensional index including size distrib...This paper establishes a diagnostic model for assessing the rationality of size structure of urban agglomerations(UAs) in China. The model is designed to determine from a three-dimensional index including size distribution index(SDI), size compactness index(SCI), and size efficiency index(SEI). The spatio-temporal pattern of size structure involving the studied 19 UAs and its implications are explored. The results indicate that size structure of China's UAs advanced from a low rationality development stage to a moderate rationality development stage in 1995-2015.Among them, the SDI and SEI were reasonably high, and the SCI was relatively low. Spatially, the high rationality UAs were distributed across eastern China, while the low rationality UAs were located in western China. UAs with positive size structure possessed typically a dual-or multicenter urban structure, while UAs with negative size structure usually presented as a single-center structure. The evolutionary trajectories of rationality of size structure of UAs can be summarized as four different stages. Our findings suggest that, in addition to consolidating the status of national-level UAs, the development of regional-level UAs should be promoted. Also, the fostering focus and direction should be oriented toward an UA with dual-or multicenter spatial structure.展开更多
基金financially supported by the National Natural Science Foundation of China(No.42102079)the Natural Science Foundation of Sichuan Province(No.22NSFSC2765)+1 种基金State Key Laboratory of Ore Deposit Geochemistry Key Laboratory Open Project Fund(No.201804)the Southwest University of Science and Technology Doctoral Fund(No.16zx7132)。
文摘The Baoshan Cu–Pb–Zn deposit, located in the central part of the Qin–Hang belt in South China, is closely related to the granodiorite-porphyry. However, the characteristics and the source of the ore-forming fluid are still ubiquitous. According to the crosscutting relationships between veinlets and their mineral assemblages, three stages of hydrothermal mineralization in this deposit were previously distinguished. In this contribution, two different colored fluorites from the major sulfide mineralization stage are recognized:(1) green fluorites coexisting with Pb–Zn ores;and(2) violet fluorites coexisting with pyrite ores. Y/Ho ratios verify the green fluorites and violet fluorites were co-genetic. The fluorites display elevated(La/Yb)Nratios, which decrease from 1201 to 5710 for green fluorites to 689–1568 for violet fluorites, indicating that they precipitated at the early hydrothermal sulfide stage,and Pb–Zn ores crystallized earlier than pyrite ores. The similar Tb/La ratios of the fluorites also indicate that they precipitated at an early stage within a short time. From the green fluorites to violet fluorites, the total rare earth element(ΣREE)concentrationsdecreasefrom1052–1680 ppm to 148–350 ppm, indicating that the green fluorites precipitated from a more acidic fluid. The Eu/Eu*ratios increase from 0.17 to 0.30 for green fluorites to0.29–0.48 for violet fluorites, and the Ce/Ce* ratios decrease from 1.08–1.13 to 0.93–1.11, suggesting a gradual increase in oxygen fugacity(fO_(2)) and pH value of the mineralization fluid. Though the fluorites display similar REE patterns to the granodiorite-porphyry and limestone,the ΣREE concentrations of the fluorites are significantly higher than those of limestone and the granodiorite-porphyry, suggesting that an important undetected non-magmatic source is involved to provide sufficient REE for fluorites. The most plausible mechanism is fluid mixing between magma fluid and an undetected non-magmatic fluid.
基金supported by the National Social Science Foundation of China [Grant number:17CJY015]the Stragegic Priority Research Program of the Chinese Academy of Sciences [Grant number:XDA19040501]+1 种基金the Fundamental Research Funds for the Central Universities[Grant number:2018RW01]Beijing Natural Science Foundation [Grant number:9184035]
文摘This paper establishes a diagnostic model for assessing the rationality of size structure of urban agglomerations(UAs) in China. The model is designed to determine from a three-dimensional index including size distribution index(SDI), size compactness index(SCI), and size efficiency index(SEI). The spatio-temporal pattern of size structure involving the studied 19 UAs and its implications are explored. The results indicate that size structure of China's UAs advanced from a low rationality development stage to a moderate rationality development stage in 1995-2015.Among them, the SDI and SEI were reasonably high, and the SCI was relatively low. Spatially, the high rationality UAs were distributed across eastern China, while the low rationality UAs were located in western China. UAs with positive size structure possessed typically a dual-or multicenter urban structure, while UAs with negative size structure usually presented as a single-center structure. The evolutionary trajectories of rationality of size structure of UAs can be summarized as four different stages. Our findings suggest that, in addition to consolidating the status of national-level UAs, the development of regional-level UAs should be promoted. Also, the fostering focus and direction should be oriented toward an UA with dual-or multicenter spatial structure.