A simple, mild, efficient Mn(salen)-catalyzed oxidation system of secondaty alcohols,in which the ionic liquid [bmim]PF_6 acts as a powerful additive, has been described. The reactionproceeded with higher efficiency. ...A simple, mild, efficient Mn(salen)-catalyzed oxidation system of secondaty alcohols,in which the ionic liquid [bmim]PF_6 acts as a powerful additive, has been described. The reactionproceeded with higher efficiency. The catalyst was more easier to recycle in ionic liquid[bmim]PF_6 with a well-proportioned CH_2C1_2 than in the single CH_2Cl_2 or ionic liquid.展开更多
文摘A simple, mild, efficient Mn(salen)-catalyzed oxidation system of secondaty alcohols,in which the ionic liquid [bmim]PF_6 acts as a powerful additive, has been described. The reactionproceeded with higher efficiency. The catalyst was more easier to recycle in ionic liquid[bmim]PF_6 with a well-proportioned CH_2C1_2 than in the single CH_2Cl_2 or ionic liquid.