Developing fluorescence porous probe for detecting and eliminating Cu^(2+) contamination in water or biosystem is an essential research project that has attracted considerable attention.However,improving the fluoresce...Developing fluorescence porous probe for detecting and eliminating Cu^(2+) contamination in water or biosystem is an essential research project that has attracted considerable attention.However,improving the fluorescence detecting efficiency while enhancing the adsorption capacity of the porous probe is of great challenge.Herein,a bifunctional two-dimensional imine-based porous covalent organic framework(TTP-COF)probe was designed and synthesized from 1,3,5-tris(4-aminophenyl)benzene(TAPB)and 2,4,6-Triformylphloroglucinol(TP)ligand.TTP-COF displayed rapid detection of Cu^(2+)(limit of detection(LOD)=10 nmol·L^(−1) while achieving a high adsorption capacity of 214 mg·g^(−1)(pH=6)at room temperature with high reusability(>5 cycles).The key roles and contributions of highπ-conjugate and delocalized electrons in TABP and functional–OH groups in TP were proved.More importantly,the fluorescence quenching mechanism of TTP-COF was studied by density functional theory theoretical calculations,revealing the crucial role of intramolecular hydrogen bonds among C=N and–OH groups and the blocking of the excited state intramolecular proton transfer process in detecting process of Cu^(2+).展开更多
As one of the promising human–machine interfaces,wearable sensors play an important role in modern society,which advances the development of wearable fields,especially in the promising applications of electronic skin...As one of the promising human–machine interfaces,wearable sensors play an important role in modern society,which advances the development of wearable fields,especially in the promising applications of electronic skin(e-skin),robotics,prosthetics,healthcare.In the last decades,wearable sensors tend to be capable of attractive capabilities such as miniaturization,multifunction,smart integration,wearable properties such as lightweight,flexibility,stretchability,conformability for wider applications.In this work,we developed a stretchable multifunctional sensor based on porous silver nanowire/silicone rubber conductive film(P-AgNW/SR).Its unique structural configuration,i.e.,an assembly of the P-AgNW/SR with good conductivity,stability,resistance response,the insulated silicone rubber layer,provided the feasibility for realizing multiple sensing capabilities.Specifically,porous microstructures of the P-AgNW/SR made the device to be used for pressure sensing,exhibiting outstanding dynamic and static resistive responsive behaviors and having a maximum sensitivity of 9.062%∙N^(−1) in a continuous compressive force range of~16 N.With the merit of the good piezoresistive property of AgNW/SR networks embedded into the surface of micropores of the P-AgNW/SR,the device was verified to be a temperature sensor for detecting temperature changes in the human body and environment.The temperature sensor had good sensitivity of 0.844%∙℃^(−1),high linearity of 0.999 in the range of 25–125℃,remarkable dynamic stability.Besides,the developed sensor was demonstrated to be a single electrode-triboelectric sensor for active sensing,owing to the unique assembly of the conductive PAgNW/SR electrode and the silicone rubber friction layer.Based on the coupling effect of the triboelectrification and electrostatic induction,the generated electrical signals could be used to sense the human motions,according to the quantitative correlation between the human motions and the features in amplitude and waveform of the output signals.Thus,the developed stretchable sensor successfully achieved the integration of two types of passive sensing capabilities,i.e.,pressure and temperature sensing,and one type of active sensing capability,i.e.,triboelectric sensing,demonstrating the feasibility of monitoring multiple variables of the human body and environment.展开更多
基金This study was financially supported by the National Natural Science Foundation of China(Nos.22001156 and 22271178)the Innovation Capability Support Program of Shaanxi(No.2022KJXX-88)the Technology Innovation Leading Program of Shaanxi(No.2020QFY07-05).
文摘Developing fluorescence porous probe for detecting and eliminating Cu^(2+) contamination in water or biosystem is an essential research project that has attracted considerable attention.However,improving the fluorescence detecting efficiency while enhancing the adsorption capacity of the porous probe is of great challenge.Herein,a bifunctional two-dimensional imine-based porous covalent organic framework(TTP-COF)probe was designed and synthesized from 1,3,5-tris(4-aminophenyl)benzene(TAPB)and 2,4,6-Triformylphloroglucinol(TP)ligand.TTP-COF displayed rapid detection of Cu^(2+)(limit of detection(LOD)=10 nmol·L^(−1) while achieving a high adsorption capacity of 214 mg·g^(−1)(pH=6)at room temperature with high reusability(>5 cycles).The key roles and contributions of highπ-conjugate and delocalized electrons in TABP and functional–OH groups in TP were proved.More importantly,the fluorescence quenching mechanism of TTP-COF was studied by density functional theory theoretical calculations,revealing the crucial role of intramolecular hydrogen bonds among C=N and–OH groups and the blocking of the excited state intramolecular proton transfer process in detecting process of Cu^(2+).
基金the National Natural Science Foundation of China(Nos.62074029,61905035,61971108,62004029,and 51905554)the Key Research and Development Program of Sichuan Province(Nos.2022JDTD0020,2022YFG0163,and 2020ZHCG0038)+1 种基金the Sichuan Science and Technology Program(No.2020YJ0015)the Fundamental Research Funds for the Central Universities(No.ZYGX2019Z002).
文摘As one of the promising human–machine interfaces,wearable sensors play an important role in modern society,which advances the development of wearable fields,especially in the promising applications of electronic skin(e-skin),robotics,prosthetics,healthcare.In the last decades,wearable sensors tend to be capable of attractive capabilities such as miniaturization,multifunction,smart integration,wearable properties such as lightweight,flexibility,stretchability,conformability for wider applications.In this work,we developed a stretchable multifunctional sensor based on porous silver nanowire/silicone rubber conductive film(P-AgNW/SR).Its unique structural configuration,i.e.,an assembly of the P-AgNW/SR with good conductivity,stability,resistance response,the insulated silicone rubber layer,provided the feasibility for realizing multiple sensing capabilities.Specifically,porous microstructures of the P-AgNW/SR made the device to be used for pressure sensing,exhibiting outstanding dynamic and static resistive responsive behaviors and having a maximum sensitivity of 9.062%∙N^(−1) in a continuous compressive force range of~16 N.With the merit of the good piezoresistive property of AgNW/SR networks embedded into the surface of micropores of the P-AgNW/SR,the device was verified to be a temperature sensor for detecting temperature changes in the human body and environment.The temperature sensor had good sensitivity of 0.844%∙℃^(−1),high linearity of 0.999 in the range of 25–125℃,remarkable dynamic stability.Besides,the developed sensor was demonstrated to be a single electrode-triboelectric sensor for active sensing,owing to the unique assembly of the conductive PAgNW/SR electrode and the silicone rubber friction layer.Based on the coupling effect of the triboelectrification and electrostatic induction,the generated electrical signals could be used to sense the human motions,according to the quantitative correlation between the human motions and the features in amplitude and waveform of the output signals.Thus,the developed stretchable sensor successfully achieved the integration of two types of passive sensing capabilities,i.e.,pressure and temperature sensing,and one type of active sensing capability,i.e.,triboelectric sensing,demonstrating the feasibility of monitoring multiple variables of the human body and environment.
