Various supported Pt-Pb bimetallic catalysts were prepared and applied for the catalytic conversion of nitrobenzene to p-aminophenol in the environmentally benign pressurized CO2/H2O system.Among the bimetallic cataly...Various supported Pt-Pb bimetallic catalysts were prepared and applied for the catalytic conversion of nitrobenzene to p-aminophenol in the environmentally benign pressurized CO2/H2O system.Among the bimetallic catalysts prepared,Pt-Pb/SiO2 is the best and nitrobenzene could be converted to paminophenol with a selectivity as high as 82% when the reaction was carried out using this catalyst at110 ℃ under 5 MPa CO2 and 0.2 MPa H2.展开更多
文摘Various supported Pt-Pb bimetallic catalysts were prepared and applied for the catalytic conversion of nitrobenzene to p-aminophenol in the environmentally benign pressurized CO2/H2O system.Among the bimetallic catalysts prepared,Pt-Pb/SiO2 is the best and nitrobenzene could be converted to paminophenol with a selectivity as high as 82% when the reaction was carried out using this catalyst at110 ℃ under 5 MPa CO2 and 0.2 MPa H2.