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磺酰腙的高效快速合成及其抗菌性能初探——推荐一个医学本科院校化学创新实验
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作者 唐敬杰 谢露影 +8 位作者 刘嘉昱 石尚玉 孙欣雨 林家阳 杨琦堃 于传昂 王泽诚 王盈盈 解增洋 《大学化学》 CAS 2024年第3期316-326,共11页
在有机化学实验教学过程中,实验内容通常是完成某一化合物的合成或提取,缺少对目标化合物的结构鉴定和性质检验。为了提高有机化学实验教学质量,培养学生的科研素养和创新能力。以商业易得的醛、酮和对甲苯磺酰肼为反应原料,于室温无溶... 在有机化学实验教学过程中,实验内容通常是完成某一化合物的合成或提取,缺少对目标化合物的结构鉴定和性质检验。为了提高有机化学实验教学质量,培养学生的科研素养和创新能力。以商业易得的醛、酮和对甲苯磺酰肼为反应原料,于室温无溶剂条件下,利用研磨方法在1 min内高效快速合成磺酰腙,并对产物进行结构表征和性质研究。产物应用于抗菌实验研究时,化合物3i和3h对大肠杆菌有最好的抑制效果。实验涉及合成、TLC检测和柱色谱层析等操作,可以锻炼学生在有机化合物合成、纯化及结构鉴定等方面的操作技能。要求学生独立查阅文献,熟练掌握Origin、ChemDraw和MestRec等软件的使用,可以提升学生分析问题并解决问题的能力。改进的实验以提高学生综合素质为宗旨,适用于有机化学基础实验教学。 展开更多
关键词 无溶剂条件 磺酰腙 研磨方式 抗菌性能
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Reservoir accumulation conditions and key exploration&development technologies for Keshen gas field in Tarim Basin 被引量:3
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作者 Haijun Yang Yong Li +10 位作者 Yangang tang Ganglin Lei Xiongwei Sun Peng Zhou Lu Zhou Anming Xu jingjie tang Wenhui Zhu Jiangwei Shang Weili Chen Mei Li 《Petroleum Research》 2019年第4期295-313,共19页
The Keshen gas field is located in the central part of Kuqa foreland thrust belt in Tarim Basin,and is another large gas field discovered in Kuqa depression after Kela 2 gas field.Since the breakthrough in 2008,a numb... The Keshen gas field is located in the central part of Kuqa foreland thrust belt in Tarim Basin,and is another large gas field discovered in Kuqa depression after Kela 2 gas field.Since the breakthrough in 2008,a number of large and medium scale gas reservoirs including Keshen 2,Keshen 5 and Keshen 8 have been discovered,that are characterized by ultra depth,ultra-high pressure,ultra-low porosity,ultra-low permeability,high temperature and high pressure.With natural gas geological reserves of nearly trillion cubic meters and production capacity of nearly 5.5 billion cubic meters,the Keshen gas field is the main natural gas producing area in Tarim Oilfield.The Keshen gas field is located in a series of thrusting imbrication structures in the Kelasu structural belt of Kuqa foreland thrust belt.The salt roof structure,plastic rheology of salt beds and pre-salt faulted anticlinal structure constitute the large wedge-shaped thrust body.The thick delta sandstone of the Cretaceous Bashijike Formation is widely distributed,and it forms the superior reservoir-caprock combination with overlying Paleogene thick gypsum-salt bed.The deep Jurassic-Triassic oil and gas migrate vertically along fault system formed in Late Himalaya,break through the thick Cretaceous mudstone and move laterally along the fracture system of the pre-salt reservoirs,to form anticline and fault anticline high pressure reservoir groups.Through near ten years of studies,the three-dimensional seismic acquisition and processing technology for complex mountainous areas,extrusion salt-related structural modeling technology and fractured low-porosity sandstone reservoir evaluation technology have been established,which lay a foundation for realization of oil and gas exploration objectives.Logging acquisition and evaluation technology for high temperature,high pressure,ultra-deep and low-porosity sandstone gas reservoirs,and efficient development technology for fractured tight sandstone gas reservoirs have been developed,which provide a technical support for efficient exploration&development and rapid production of the Keshen gas field. 展开更多
关键词 Oil and gas accumulation Three-dimensional mountainous seismic EXPLORATION Ultra-deep high temperature and high pressure gas reservoirs High efficiency exploration and DEVELOPMENT Keshen gas field Tarim Basin
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