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Effect of poly(4-tert-butylstyrene)block length on the microphase structure of poly(ethylene oxide)-b-poly(4-vinylbenzyl chloride)-b-poly(4-tert-butylstyrene)triblock terpolymers
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作者 Kun An Jia Gao +4 位作者 Yihang Chen jingjing nie Yongjin Li Junting Xu Binyang Du 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第6期551-555,共5页
A series of linear poly(ethylene oxide)-b-poly(4-vinylbenzyl chloride)-b-poly(4-tert-butylstyrene)(PEO_(113)-b-PVBC_(130)-b-Pt BS_(x)or E_(113)V_(130)T_(x))triblock terpolymers with various lengths x(=20,33,66,104,215... A series of linear poly(ethylene oxide)-b-poly(4-vinylbenzyl chloride)-b-poly(4-tert-butylstyrene)(PEO_(113)-b-PVBC_(130)-b-Pt BS_(x)or E_(113)V_(130)T_(x))triblock terpolymers with various lengths x(=20,33,66,104,215)of Pt BS block were synthesized via a two-step reversible addition-fragmentation chain transfer(RAFT)polymerization.The E_(113)V_(130)T_(x)triblock terpolymers were non-crystalline because the PVBC and Pt BS blocks strongly hindered the crystallization of PEO block.The effects of Pt BS block length x on the phase structures of E_(113)V_(130)T_(x)triblock terpolymers were investigated by combined techniques of small-angle X-ray scattering(SAXS)and transmission electron microscopy(TEM).It was found that with increasing x from20 to 215,the phase structure of E_(113)V_(130)T_(x)triblock terpolymers became more ordered and changed from disordered structure,hexagonally-packed cylinder(HEX),hexagonally perforated layer(HPL),to lamellar(LAM)phase structures.Temperature-variable SAXS measurements showed that the HEX,HPL and LAM phase structures obtained for E_(113)V_(130)T_(66),E_(113)V_(130)T_(104)and E_(113)V_(130)T_(215)by thermal annealing,respectively,were thermodynamically stable in the temperature range of 30-170℃. 展开更多
关键词 ABC triblock terpolymer Phase structure SAXS HPL Thermodynamically stable
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Vector Dominance with Threshold Searchable Encryption (VDTSE) for the Internet of Things
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作者 jingjing nie Zhenhua Chen 《Computers, Materials & Continua》 SCIE EI 2024年第6期4763-4779,共17页
The Internet of Medical Things(IoMT)is an application of the Internet of Things(IoT)in the medical field.It is a cutting-edge technique that connects medical sensors and their applications to healthcare systems,which ... The Internet of Medical Things(IoMT)is an application of the Internet of Things(IoT)in the medical field.It is a cutting-edge technique that connects medical sensors and their applications to healthcare systems,which is essential in smart healthcare.However,Personal Health Records(PHRs)are normally kept in public cloud servers controlled by IoMT service providers,so privacy and security incidents may be frequent.Fortunately,Searchable Encryption(SE),which can be used to execute queries on encrypted data,can address the issue above.Nevertheless,most existing SE schemes cannot solve the vector dominance threshold problem.In response to this,we present a SE scheme called Vector Dominance with Threshold Searchable Encryption(VDTSE)in this study.We use a Lagrangian polynomial technique and convert the vector dominance threshold problem into a constraint that the number of two equal-length vectors’corresponding bits excluding wildcards is not less than a threshold t.Then,we solve the problem using the proposed technique modified in Hidden Vector Encryption(HVE).This technique makes the trapdoor size linear to the number of attributes and thus much smaller than that of other similar SE schemes.A rigorous experimental analysis of a specific application for privacy-preserving diabetes demonstrates the feasibility of the proposed VDTSE scheme. 展开更多
关键词 Internet of Things(IoT) Internet of Medical Things(IoMT) vector dominance with threshold searchable encryption(VDTSE) threshold comparison electronic healthcare
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