Conventional oven drying (COD) and supercritical drying (SCD) methods wereapplied to the preparation of Mn-substituted hexaaluminate (BaMnAl_(11)O_(19-α)) catalysts. Theeffect of drying methods on phase composition, ...Conventional oven drying (COD) and supercritical drying (SCD) methods wereapplied to the preparation of Mn-substituted hexaaluminate (BaMnAl_(11)O_(19-α)) catalysts. Theeffect of drying methods on phase composition, specific surface area, pore structure, reductionbehavior of Mn^(3+) ions, and combustion activity of the samples was investigated. The homogenousmixing of the components in the sol-gel process could be maintained by SCD, and the hexaaluminatephase was almost the only phase of the resulting materials after calcination. H_2-TPR revealed thatthe Mn^(3+) ions in the sample obtained by SCD were easier to be reduced than that by COD. Moreover,the samples obtained by SCD have higher surface area, narrower pore size distribution, and highercombustion activity than those obtained by COD.展开更多
文摘Conventional oven drying (COD) and supercritical drying (SCD) methods wereapplied to the preparation of Mn-substituted hexaaluminate (BaMnAl_(11)O_(19-α)) catalysts. Theeffect of drying methods on phase composition, specific surface area, pore structure, reductionbehavior of Mn^(3+) ions, and combustion activity of the samples was investigated. The homogenousmixing of the components in the sol-gel process could be maintained by SCD, and the hexaaluminatephase was almost the only phase of the resulting materials after calcination. H_2-TPR revealed thatthe Mn^(3+) ions in the sample obtained by SCD were easier to be reduced than that by COD. Moreover,the samples obtained by SCD have higher surface area, narrower pore size distribution, and highercombustion activity than those obtained by COD.