For the first time,this paper demonstrates a synergistic effect from the combination of a gliding arc discharge plasma with a photocatalyst TiO_(2) for CO_(2) dissociation.The effects of adding a tray downstream the d...For the first time,this paper demonstrates a synergistic effect from the combination of a gliding arc discharge plasma with a photocatalyst TiO_(2) for CO_(2) dissociation.The effects of adding a tray downstream the discharge and the combination of the catalyst with plasma have been investigated.Two different combination modes of plasma catalysis,i.e.,in-plasma catalysis and post-plasma catalysis,have been evaluated with the emphasis on the analysis of potential mechanisms.The results show that modifying the gliding arc reactor by the addition of a tray can enhance the fraction of gas treated by plasma,thus improv-ing the reaction performance.An exceptional synergistic effect of combining the gliding arc discharge with TiO_(2) for CO_(2) activation forms in the in-plasma catalysis mode.The presence of TiO_(2) significantly enhances the CO_(2) conversion by 138% and the energy efficiency by 133%at a flow rate of 2 L/min.The plasma activation effect,which produces energetic electrons that can create the electron-hole pairs on the catalyst surface,is believed to be the major contributor to the generation of the plasma catalysis synergy.This mechanism has been further evidenced by the negligible influence of the post-plasma catalysis on the reaction performance.展开更多
基金support from the National Natural Science Foundation of China(No.51706204)National Key Technologies R&D Program(No.YS2018YFE010498)the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 823745.XT and NW thank the financial support from the State Key Laboratory of Electrical Insulation and Power Equipment at Xi’an Jiaotong University(No.EIPE19207).
文摘For the first time,this paper demonstrates a synergistic effect from the combination of a gliding arc discharge plasma with a photocatalyst TiO_(2) for CO_(2) dissociation.The effects of adding a tray downstream the discharge and the combination of the catalyst with plasma have been investigated.Two different combination modes of plasma catalysis,i.e.,in-plasma catalysis and post-plasma catalysis,have been evaluated with the emphasis on the analysis of potential mechanisms.The results show that modifying the gliding arc reactor by the addition of a tray can enhance the fraction of gas treated by plasma,thus improv-ing the reaction performance.An exceptional synergistic effect of combining the gliding arc discharge with TiO_(2) for CO_(2) activation forms in the in-plasma catalysis mode.The presence of TiO_(2) significantly enhances the CO_(2) conversion by 138% and the energy efficiency by 133%at a flow rate of 2 L/min.The plasma activation effect,which produces energetic electrons that can create the electron-hole pairs on the catalyst surface,is believed to be the major contributor to the generation of the plasma catalysis synergy.This mechanism has been further evidenced by the negligible influence of the post-plasma catalysis on the reaction performance.
