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低热膨胀系数超支化共聚聚酰亚胺的构建及性能
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作者 雷永林 舒远杰 +1 位作者 彭金华 唐友建 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2018年第2期81-87,共7页
以2,3,3',4'-联苯四甲酸二酐、3,3',4,4'-联苯四羧酸二酐、对二氨基二苯醚、对苯二胺和合成三胺单体为原料,合成了含有超支化链段的新型共聚聚酰亚胺。研究表明,与线型低热膨胀系数聚酰亚胺(HB-Co-PIS-0)相比,超支化链... 以2,3,3',4'-联苯四甲酸二酐、3,3',4,4'-联苯四羧酸二酐、对二氨基二苯醚、对苯二胺和合成三胺单体为原料,合成了含有超支化链段的新型共聚聚酰亚胺。研究表明,与线型低热膨胀系数聚酰亚胺(HB-Co-PIS-0)相比,超支化链段引入后,其显著的优点是溶解性变好,引入超支化链段5%时,聚酰亚胺可在极性大的溶剂二甲基甲酰胺和甲基吡咯烷酮中溶解,在四氢呋喃等极性小的溶剂中回流微溶。另外,其聚酰亚胺酸黏度降低,热膨胀系数值维持较低的数值,无序结构增多,玻璃化温度和热分解温度降低,拉伸强度增大,断裂伸长率减小。并且,超支化链段引入,使原线型低热膨胀系数聚酰亚胺微突起的致密表面变为更多纳米突起的粗糙疏松表面,水接触角从原来72°增加到76°(3%超支化)和85°(5%超支化)。 展开更多
关键词 低热膨胀系数 超支化 聚酰亚胺 共聚 溶解性
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Effect of cerium alloying on microstructure,texture and mechanical properties of magnesium during cold-rolling process 被引量:1
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作者 Zhen Zhang Huanhuan Chen +9 位作者 Shiju Cao jinhua peng peng Guo Chang Long Shan Wang Chang Chen Yong Wu Ji'an Huang Xiaodong Du Haigen Wei 《Journal of Rare Earths》 SCIE EI CAS CSCD 2024年第5期1001-1008,I0007,共9页
Hot-extrusion and cold-rolling were conducted on Mg-Ce binary alloys to explore the effect of cerium(Ce)on microstructure,texture and mechanical properties of Mg alloys.The addition of Ce results in significant grain ... Hot-extrusion and cold-rolling were conducted on Mg-Ce binary alloys to explore the effect of cerium(Ce)on microstructure,texture and mechanical properties of Mg alloys.The addition of Ce results in significant grain refinement both in as-cast and hot-extruded samples.The basal texture is also weakened after extrusion and an inclined basal texture is formed with Ce addition.The strength and elongation of the Mg-Ce alloys are improved simultaneously due to such grain refinement and texture weakening effect.After cold-rolling,plenty of twins are found in the pure Mg and AZ31 plates while grains in the Mg-0.3Ce plate deform more uniformly without lamellar twin structure.Furthermore,Mg-0.3Ce alloys own strong and continuous strain hardening because Ce atoms and Mg-Ce precipitated phases serve as obstacles for dislocation slip. 展开更多
关键词 Mg-Ce alloys Hot extrusion COLD-ROLLING Rare earths
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