Tuning the electrochemical behaviors of N-doped LiMn_(x)Fe_(1–x)PO_(4)/C via cation engineering with metal-organic framework-templated strategy

LiFePO_(4),as a prevailing cathode material for lithium-ion batteries(LIBs),still encounters issues such as intrinsic poor electronic conductivity,inferior Li-ion diffusion kinetic,and two-phase transformation mechanism involving substantial structural rearrangements,resulting in unsatisfactory rate performance.Carbon coating,cation doping,and morphological control have been widely employed to reconcile these issues.Inspired by these,we propose a synthetic route with metal–organic frameworks(MOFs)as self-sacrificial templates to simultaneously realize shape modulation,Mn doping,and N-doped carbon coating for enhanced electrochemical performances.The as-synthesized Li MnxFe1–xPO4/C(x=0,0.25,and0.5)deliver tunable electrochemical behaviors induced by the MOF templates,among which LiMn_(0.25)Fe_(0.75)PO_(4)/C outperforms its counterparts in cyclability(164.7 mA h g^(-1)after 200 cycles at 0.5 C)and rate capability(116.3 mA h g^(-1)at 10 C).Meanwhile,the ex-situ XRD reveals a dominant single-phase solid solution mechanism of LiMn_(0.25)Fe_(0.75)PO_(4)/C during delithiation,contrary to the pristine LiFePO_(4),without major structural reconstruction,which helps to explain the superior rate performance.Furthermore,the density functional theory(DFT)calculations verify the effects of Mn doping and embody the superiority of LiMn_(0.25)Fe_(0.75)PO_(4)/C as a LIB cathode,which well supports the experimental observations.This work provides insightful guidance for the design of tunable MOF-derived mixed transitionmetal systems for advanced LIBs.

A challenge to the concept of slip-lines in extrusion tectonics

Wide-open V-shaped conjugate strike-slip faults in Asia are typically related to extrusion tectonics. However, the tectonic model based on the slip-line theory of plasticity has some critical problems associated with it. The conjugate sets of slip-lines in plane deformation, according to the theory of plasticity should be normal to each another but, in reality, the angles between the conjugate strike-slip faults, which are regarded as slip-lines in extrusion tectonics in the eastern Mediterranean, Tibet-middle Asia, China and the Indochina Peninsular regions, are always more than 90° （on average -110°） in the direction of contraction. Another problem is that the slip-line theory fails to explain how, in some cases, e.g., in the Anatolian area in the eastern Mediterranean, the extrusion rate is much higher than the indent rate. The two major problems are easy to solve in terms of the Maximum-Effective-Moment （MEM） Criterion that predicts that orientations of the shear zones are theoretically at an angle of 54.7° and practically at angles of 55°± 10° with the σ1- or contractional direction. The orientations of the strike-slip faults that accommodate extrusion tectonics are, therefore, fundamentally controlled by the MEM Criterion. When extrusion is along the MEM-orientations, the extruding rate is normally higher than the indenting rate.

Structural features and deformational ages of the northern Dabashan thrust belt

A large-scale pop-up structure occurs at the front of the northern Dabashan thrust belt （NDTB）, bound by the NNE-dipping Chengkou fault to the south, and the SSW-dipping Gaoqiao fault to the north. The pop-up structure shows different features along its strike as a direct reflection of the intensity of tectonic＂ activity. To the northwest, the structure is characterized by a two-directional thrust system forming a positive flower-like structure. In contrast, the southeastern part is composed of the vertical Chengkou fault and a series of N-directed backthrusts, showing a semi-flower-like structure. We present results from Ar-Ar dating of syntectonic microthermal metamorphic sericite which show that the Chengkou fault experienced intense deformation during the mid-Mesozoic Yanshanian epoch （about 143.3 Ma）, causing rapid uplift and thrusting of the northern Dabashan thrust belt. During the propagation of this thrust, a series of backthrusts formed because of the obstruction from the frontier of Dabashan thrust belt, leading to the development of the pop-up structure.

Northward subduction-related orogenesis of the southern Altaids:Constraints from structural and metamorphic analysis of the HP/UHP accretionary complex in Chinese southwestern Tianshan,NW China

The Chinese Tianshan belt of the southern Altaids has undergone a complicated geological evolution. Different theories have been proposed to explain its evolution and these are still hotly debated. The major subduction polarity and the way of accretion are the main problems. Southward, northward subduction and multiple subduction models have been proposed. This study focuses on the structural geology of two of the main faults in the region, the South Tianshan Fault and the Nikolaev Line. The dip direction in the Muzhaerte valley is southward and lineations all point towards the NW. Two shear sense motions have been observed within both of these fault zones, a sinistral one, and a dextral one, the latter with an age of 236-251 Ma. Structural analyses on the fault zones show that subduction has been northward rather than southward. The two shear sense directions indicate that the Yili block was first dragged along towards the east due to the cloclkwise rotation of the Tarim block. After the Tarim block stopped rotating, the Yili block still kept going eastward, inducing the dextral shear senses within the fault zones.

Simulation of Substrate Temperature Distribution in Diamond Films Growth on WC-Co Tools Using HFCVD Method

The substrate temperature is an important factor for diamond films fabricated by hot filament chemical vapor deposition (HFCVD), which affects the grain size and quality of diamond films. In order to deposit polycrystalline diamond films with good quality on the cutting tool, the substrate temperature distribution needs to be further studied. Thus three-dimensional finite element simulations are used to investigate the temperature field with different arrangements of filaments which have profound influences on substrate temperature distribution. Based on the simulation results, the optimum parameters of distance away from drill points and gap between filaments are founded. Subsequently, experiments of depositing diamond films on WC-Co drills are conducted with the optimum values gained from the simulation results. Then, the as-fabricated diamond films are investigated by scanning electron microscopy (SEM) and Raman spectroscopy. The results indicate that the surface of drill are covered with a layer of continuous diamond films, which validate that the simulated deposition parameters are conducive and provide a new method to adjust the substrate temperature distribution in the CVD reactor for depositing diamond films.

挤压构造带变形样式的热年代学诊断

构造运动是控制地应力场与塑造地貌形态的内源动力,受多重因素影响,在不同地区展现出不同的变形样式与岩石剥露路径.基岩热年代学数据常被用于量化岩石剥露与冷却过程,进而间接限定脆性与脆韧性构造变形的时限和样式,但相关数据具有多解性,需要综合分析地质、地球物理等其他证据.本研究旨在以新构造变形与热年代学研究丰富的新特提斯构造带之喜马拉雅、阿尔卑斯、东喀尔巴阡、龙门山及四川盆地西南部5个地区为例,探究前缘逆冲-腹地正断构造、厚皮构造、前展式薄皮构造、乱序式薄皮构造等背景下,热年代学年龄与岩石剥露的空间展布规律,以期为其他地区的相关研究提供参考.切过喜马拉雅-雅鲁藏布江缝合带的热年代学年龄廊带图显示,主边界逆冲带与腹地正断层之间,热年代学年龄最小,剥蚀量最大,吸收了该地区的地壳缩短和中下地壳物质中新世以来的快速剥露.与喜马拉雅冲断带不同,阿尔卑斯造山带年轻的热年代学年龄和显著的岩石剥露主要分布在宽约80 km的造山带内部地区,记录了造山楔的双向逆冲推覆.东喀尔巴阡冲断带,重置的磷灰石(UTh)/He年龄向前陆盆地方向逐渐变小,但冲断带前缘磷灰石裂变径迹年龄未重置,指示前缘变形时代晚、剥蚀量小,记录了前展式冲断变形.龙门山冲断带热年代学年龄分布受3条逆断层控制,腹地断层上盘年龄最小,剥露深度最大,指示多条断层乱序式逆断活动.对四川盆地西南部褶皱带的分析显示,紧闭背斜区的热年代学年龄普遍相对年轻,且与地层时代负相关,记录了褶皱变形的发育过程和剥蚀幅度.上述结果表明,热年代学年龄的空间展布是限定挤压性新构造活跃区岩石剥露与扩展过程、甄别地壳变形样式的有力工具,是探讨构造-气候相互作用关系的重要基础.

Microstructures, Fabrics, and Seismic Properties of Mylonitic Amphibolites: Implications for Strain Localization in a Thickening Anisotropic Middle Crust of the North China Craton

Strain localization processes in the continental crust generate faults and ductile shear zones over a broad range of scales affecting the long-term lithosphere deformation and the mechanical response of faults during the seismic cycle.Seismic anisotropy originated within the continental crust can be applied to deduce the kinematics and structures within orogens and is widely attributed to regionally aligned minerals,e.g.,hornblende.However,naturally deformed rocks commonly show various structural layers(e.g.,strain localization layers).It is necessary to reveal how both varying amphibole contents and fabrics in the structural layers of strain localization impact seismic property and its interpretations in terms of deformation.We present microstructures,petrofabrics,and calculate seismic properties of deformed amphibolite with the microstructures ranging from mylonite to ultramylonite.The transition from mylonite to ultramylonite is accompanied by a slight decrease of amphibole grain size,a disintegration of amphibole and plagioclase aggregates,and amphibole aspect ratio increase(from 1.68 to 2.23),concomitant with the precipitation of feldspar and/or quartz between amphibole grains.The intensities of amphibole crystallographic preferred orientations(CPOs)show a progressively increasing trend from mylonitic layers to homogeneous ultramylonitic layers,as indicated by the JAm index increasing from 1.9–4.0 for the mylonitic layers and 4.0–4.8 for the transition layer,to 5.1–6.9 for the ultramylonitic layers.The CPO patterns are nearly random for plagioclase and quartz.Polycrystalline amphibole aggregates in the amphibolitic mylonite deform by diffusion,mechanical rotation,and weak dislocation creep,and develop CPOs collectively.The polymineralic matrix(such as quartz and plagioclase)of the mylonite and the ultramylonite deform dominantly by dissolution-precipitation,combined with weak dislocation creep.The mean P and S wave velocities are estimated to be 6.3 and 3.5 km/s,respectively,for three layers of the mylonitic amphibolite.The respective maximum P and S anisotropies are 1.5%–6.4%and 1.8%–4.5%for the mylonite layers of the mylonitic amphibolite,and 6.0%–6.9%and 4.5%–5.0%for the transition layers;but for the ultramylonite layers,these values increase significantly to 8.0%–9.1%and 5.1%–6.0%,respectively.Furthermore,increasing strain(strain localization)generates significant variations in the geometry of the seismic anisotropy.This effect,coupled with the geographical orientations of structures in the Hengshan-Wutai-Fuping complex terrains,can generate substantial variations in the orientation and magnitude of seismic anisotropy for the continental crust as measured by the existing North China Geoscience Transect.Thickened amphibolitic layers by extensively folding or thrusting in the middle crust can explain the strong shear wave splitting and the tectonic boundary parallel fast shear wave polarization beneath the Hengshan-Wutai-Fuping complex terrains.Therefore,signals of seismic anisotropy varying with depth in the deforming continent crust need not deduce depth-varying kinematics or/and tectonic decoupling.

Effect of temperature-dependent rock thermal conductivity and specific heat capacity on heat recovery in an enhanced geothermal system

The modeling of heat recovery from an enhanced geothermal system(EGS)requires rock thermal parameters as inputs such as thermal conductivity and specific heat capacity.These parameters may encounter significant variations due to the reduction of rock temperature during heat recovery.In the present study,we investigate the effect of temperature-dependent thermal conductivity and specific heat capacity on the thermal performance of EGS reservoirs.Equations describing the relationships between thermal conductivity/specific heat capacity and temperature from previous experimental studies were incorporated in a field-scale single-fracture EGS model.The modeling results indicate that the increase of thermal conductivity caused by temperature reduction accelerates thermal conduction from rock formations to fracture fluid,and thus improves thermal performance.The decrease of specific heat capacity due to temperature reduction,on the contrary,impairs the thermal performance but the impact is smaller than that of the increase of thermal conductivity.Due to the opposite effects of thermal conductivity increase and specific heat capacity decrease,the overall effect of temperature-dependent thermal parameters is relatively small.Assuming constant thermal parameters measured at room temperature appears to be able to provide acceptable predictions of EGS thermal performance.

地质学科未来5~10年发展战略:趋势与对策

当代地球科学的内涵和外延已经拓展到涵盖整个固体地球内部及外部层圈形成演化及与资源能源富集、生态环境变迁、地球宜居性和社会可持续发展相关的地球系统科学问题.随着人类社会经济高速发展,与地球相关的资源能源、气候环境、地质灾害等问题日益突出.为了适应新时代地球科学发展形势,在地球系统科学理论框架下,准确分析我国地球科学未来5~10年的发展趋势、明确战略目标和优先发展领域,不仅能够大力促进和强化我国地球科学的发展、赶超世界领先水平、早日实现从地质大国到地质强国的转变,而且对于保障国家矿产能源安全、助推国家经济建设和人类社会可持续发展具有重大意义.

Rapid denudation of the Himalayan orogen in the Nyalam area,southern Tibet, since the Pliocene and implications for tectonics–climate coupling

The Himalayan orogen characterized by very high variability in tectonic and climatic processes,and is thus regarded as a natural laboratory for investigating the coupling of tectonics and climate,as well as the influence of this coupling on geomorphological processes.This study uses apatite fission track(AFT)dating of samples from a45-km-long section crossing the Great Himalaya Crystalline Complex(GHC)in the Nyalam area,southern Tibet,to constrain the timing and rate of late Cenozoic denudation.The AFT ages can be divided into two groups:(1)15–6 Ma,to the north of Nyalam town,for which the bestfit line of elevation-age has a gentle slope of 0.05,and for which a denudation rate of 0.27 mm/a is calculated;and(2)3–1 Ma,south of Nyalam town,for which the best-fit line has a steep slope of 0.64,and for which a denudation rate of 1.32 mm/a is calculated.The whole AFT ages has a positive correlation with sample elevation(i.e.,older ages are found at higher elevations),and the geographical location of the point of inflexion of the two fitted lines corresponds closely to the junction of Poqu River near Nyalam town.By integrating the AFT data with thermotectonic modeling,it can be inferred that the GHC has experienced two different periods of denudation:(1)slow denudation during middle to late Miocene(15–6 Ma)is recorded in the northern part of the GHC;and(2)rapid denudation from the Pliocene to the Pleistocene(3–1 Ma)is recorded in the southern part of the GHC.An abrupt change in denudation rate occurred between the two periods,with the Pliocene–Pleistocene denudation rate being five times higher than that during the Miocene.This abrupt change in denudation rate during Pliocene pervaded the Himalayan orogen,and was roughly synchronous with a marked change in global climate at 4–3 Ma,and intensification of the Asian monsoon.Importantly,the later period of rapid denudation in the study region closely coupled to the mean annual precipitation,while there is no clear evidence for large-scale faulting activity and associated uplift during this period.Therefore,climate(precipitation)is inferred to be the main cause of the rapid denudation of the Himalayan orogen since the Pliocene.

Impact analysis of human factors on power system operation reliability

Along with the improvement of electrical equipment reliability,people’s unsafe behaviors and human errors have become one of main sources of risks in power systems.However,there is no comprehensive study on human factors and human reliability analysis in power systems.In allusion to this situation,this paper attempts to analyze the impact of human factors on power system reliability.First,this paper introduces current situation of human factors in power systems and the latest research progress in this field.Several analysis methods are proposed according to specified situations,and these methods are verified by some power system practical cases.On this base,this paper illustrates how human factors affect power system operation reliability from 2 typical aspects:imperfect maintenance caused by human errors,and impact of human factors on emergency dispatch operation and power system cascading failure.Finally,based on information decision and action in crew(IDAC),a novel dispatcher training evaluation simulation system(DTESS)is established,which can incorporate all influencing factors.Once fully developed,DTESS can be used to simulate dispatchers’response when encountering an initial event,and improve power system dispatching reliability.

Cenozoic tectonic evolution of regional fault systems in the SE Tibetan Plateau

The SE Tibetan Plateau,tectonically situated in the eastern India-Eurasia oblique convergence zone,has experienced multiple stages of deformation since the Cenozoic.Three major tectonic boundaries—the Ailaoshan-Red River,ChongshanLincang-Inthanon,and Gaoligong-Mogok shear zones—delineate the first-order tectonic framework in this region.The most striking structural features in the block interiors are a series of NW-and NE-trending fault systems,such as the Dayingjiang,Longlin-Ruili,Nantinghe,Red River,Weixi-Qiaohou,and Lancang-Genma faults,which have conjugate geometric relationships.In this study,we review these structures’geometric and kinematic characteristics and deformation histories.A synthesis of existing geological observations,geomorphological analyses,and chronological data reveals three major Cenozoic tectonothermal events,including crustal shortening,strike-slip shearing,and kinematic reversal.The boundary structures controlled the tectonic extrusion of plateau material during the early Oligocene-early Miocene.In the mid-late Miocene,NW-and NE-trending fault systems mostly experienced diachronous slip-sense inversions.The onset and spatial trend of regional kinematic reversal are constrained by existing chronologic data.Together with geophysical and geodetic observations,the activity and geodynamic drivers of the major fault systems and regional deformation styles are explored,revealing that the SE Tibetan Plateau underwent a transition from discrete(lateral block extrusion)to diffuse deformation in the mid-late Miocene.The intracontinental crustal deformation and its coupling with dynamic processes at depth during the plateau growth are discussed in the context of the IndiaEurasia convergence.

A statistical-based online cross-system fault detection method for building chillers

Practical applications of data-driven fault detection(FD)are limited by their portability.The costs of model training and validation are extremely high when each system requires a model retrained on its own fault and fault-free data.Therefore,this paper proposes a statistical-based online cross-system FD method to address the problem of model portability.The proposed FD model can be cross-utilized between building chillers with various specifications while it only needs to update the original fault detection model by the normal operation data of the new chiller system,thus saving huge fault experimental costs for the fault detection of new chiller.First,a theoretical basis for the proposed cross-system fault detection method is presented.Then,experiments were conducted on three building chillers with different specifications.Both fault and fault-free data were collected from the three chillers.The development and validation of the proposed cross-system fault detection method are then conducted.Results show that the cross-system fault detection models perform well when used with different chillers.For instance,when the fault detection model of system#1 was cross-utilized to system#2,the detection accuracies of refrigerant leakage,refrigerant overcharge,and reduced evaporator water flow were 99.73%,90.17%,and 96.94%,respectively.Compared with original models,the detection accuracies were improved by 33.78%,84.07%,and 65.56%,respectively.Therefore,the proposed cross-system fault detection method has potential for online application to practical engineering FD.

Syn-deformation P-T paths of Xiaoqinling metamorphic core complex

The \%P_T\% paths of the Xiaoqinling metamorphic core complex (XMCC) have been investigated with the Gibbs method by researching the compositional changing of zoned epidotes which formed during syn_deformation metamorphism. These \%P_T\% paths indicate that the XMCC had experienced the following thermodynamics processes: firstly, near isobaric falling slightly in temperature in lower crust; secondly, fast decompression and rising in temperature during extensional uplifting to middle crust level; and finally, isobaric falling in temperature in middle crust. The upwelling and emplacement of the deep magma may be a major factor during the uplifting processes of the metamorphic core complex.

Mechanism of inversion metallogeny of quartz vein type gold deposits in the Xiaoqinling region

There are a lot of important gold_bearing quartz veins in the Xiaoqinling metamorphic core complex. The quartz veins are strictly controlled by shear zones. Stress analysis indicates that the metallizing process of the Xiaoqinling gold deposits of quartz vein type can be divided into two stages. At the first stage, the shear zones were formed in an extensional environment, and the temperature was higher and the buried depth was greater; at the second stage, the brittle thrusts were superimposed in ductile shear zones after the tectonic stress field turned from the extension to compression. The ore_bearing fluids were concentrated in these weak positions, and the gold deposits of quartz vein type were developed.