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SiO_(2)微球主导下多孔树脂微观结构的精细调控
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作者 赵锦梅 刘飒 +2 位作者 范琼予 王星越 米亚策 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2022年第4期58-65,共8页
以环氧树脂为反应单体、聚乙二醇为不良溶剂、1,4-二氧六环为良溶剂、4,4’-二氨基二环己基甲烷为交联剂,利用反应诱导相分离法制备环氧树脂多孔材料。在制备过程中引入SiO_(2)微球,通过改变SiO_(2)微球的质量分数和润湿性,调控环氧树... 以环氧树脂为反应单体、聚乙二醇为不良溶剂、1,4-二氧六环为良溶剂、4,4’-二氨基二环己基甲烷为交联剂,利用反应诱导相分离法制备环氧树脂多孔材料。在制备过程中引入SiO_(2)微球,通过改变SiO_(2)微球的质量分数和润湿性,调控环氧树脂多孔材料的微观结构。在不引入新组分的情况下,通过酸刻蚀法去除SiO_(2)微球,实现了对环氧树脂多孔材料微观结构的精细调控。利用光学显微镜、扫描电镜和压汞仪探讨了纳米SiO_(2)微球加入前后环氧树脂共混体系的相分离过程及环氧树脂多孔材料的微观结构变化。结果表明,SiO_(2)微球的加入减小了相分离后期相结构的粗化速率;随着SiO_(2)微球质量分数的增加,环氧树脂多孔材料的孔径逐渐减小,结构细化;值得注意的是,对于SiO_(2)微球润湿性的影响,当SiO_(2)微球优先被其中一相润湿时,其对环氧树脂多孔材料微观结构的影响更显著。 展开更多
关键词 反应诱导相分离 环氧树脂多孔材料 SiO_(2)微球
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The Effect of the Soil Water Holding Capacity and Permeability under Different Patterns of Land Use in the Eastern Qilian Mountains
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作者 jinmei zhao Degang ZHANG Changzhong LIU 《Asian Agricultural Research》 2013年第7期63-66,86,共5页
This study investigated the effect of the soil water holding capacity and permeability under different land use patterns in the Tianzhu alpine region of the Eastern Qilian Mountains,and four land use patterns were sel... This study investigated the effect of the soil water holding capacity and permeability under different land use patterns in the Tianzhu alpine region of the Eastern Qilian Mountains,and four land use patterns were selected,namely,natural grassland,rehabilitated land,oats land and perennial grassland. As time went by,different land use patterns imposed significant effects on the water holding capacity power and permeability. The soil bulk density was rehabilitated land(1. 104 g/cm3) > perennial grassland(1.061g/cm3) > oats land(1.011 g/cm3) > natural grassland(0. 781 g/cm3) ; the soil overall porosity was natural grassland(68.196%) > oats land(60.606%) > perennial grassland(58. 93%) > rehabilitated land(57. 5%) ; the natural grassland had the most water holding capacity power and soil steady infiltration rate(681. 966 t/hm 2 and 3. 02 mm/min) ,while the rehabilitated land had the least(575. 005 t/hm 2 and 1. 004 mm/min) . In terms of soil water-holding capacity and permeability,the natural grassland was the best out of these four use patterns while the rehabilitated land was the worst pattern. In other words,both oats land and perennial grassland had better water holding capacity power and permeability than the rehabilitated land. 展开更多
关键词 SOIL WATER HOLDING capacity SOIL PERMEABILITY LAND
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