Combining material big data with artificial intelligence constitutes the fourth paradigm of material research.However,the sluggish development of highthroughput(HT)experimentation has resulted in a lack of experimenta...Combining material big data with artificial intelligence constitutes the fourth paradigm of material research.However,the sluggish development of highthroughput(HT)experimentation has resulted in a lack of experimentally verified and validated material data,which has become the bottleneck of data-driven material research.Wet-chemical synthesis has the benefits of low equipment cost and scalability,but traditional wet-chemical techniques are time-consuming and ineffective at disclosing the interrelationships between synthesis,compositions,structures,and performance.Constructing a HT workflow in wet-chemical synthesis is crucial to achieving the preparation of multidimensional materials and establishing the composition-structure-synthesis-performance relationships of functional materials for diverse applications.In this review,the most recent development in HT wet-chemical synthesis techniques for material research are analyzed in depth.Additionally,the application of HT wet-chemical synthesis in the fabrication of advanced hydrogels and catalysts is demonstrated through illustrative instances.Finally,this review suggests possible paths for enhancing the efficiency of HT experimentation and data acquisition in order to facilitate more effective material discovery.展开更多
Flexible piezoresistive pressure sensor with high sensitivity over a broad linearity range have been attracting tremendous attention for its applications in health monitoring,artificial intelligence,and human-machine ...Flexible piezoresistive pressure sensor with high sensitivity over a broad linearity range have been attracting tremendous attention for its applications in health monitoring,artificial intelligence,and human-machine interfaces.Herein,we report a hierarchical insitu filling porous piezoresistive sensor(HPPS)by direct ink writing(DIW)printing and curing of carbon nanofibers(CNFs)/polydimethylsiloxane(PDMS)emulsion.Hierarchical geometry significantly increases the contact area,distributes stress to multilayered lattice and internal porous structure,resulting in a broad sensing range.Moreover,unlike conventional hollow porous structure,the CNFs networks in-situ filling porous structure generates more contact sites and conductive pathways during compression,thereby achieving high sensitivity and linearity over entire sensing range.Therefore,the optimized HPPS achieves high sensitivity(4.7 kPa^(−1))and linearity(coefficient of determination,R^(2)=0.998)over a broad range(0.03-1000 kPa),together with remarkable response time and repeatability.Furthermore,the applications in diverse pressure scenarios and healthcare monitoring are demonstrated.展开更多
The development of stretchable electronics could enhance novel interface structures to solve the stretchability-conductivity dilemma,which remains a major challenge.Herein,we report a nano-liquid metal(LM)-based highl...The development of stretchable electronics could enhance novel interface structures to solve the stretchability-conductivity dilemma,which remains a major challenge.Herein,we report a nano-liquid metal(LM)-based highly robust stretchable electrode(NHSE)with a self-adaptable interface that mimics water-tonet interaction.Based on the in situ assembly of electrospun elastic nanofiber scaffolds and electrosprayed LM nanoparticles,the NHSE exhibits an extremely low sheet resistance of 52 mΩsq^(-1).It is not only insensitive to a large degree of mechanical stretching(i.e.,350%electrical resistance change upon 570%elongation)but also immune to cyclic deformation(i.e.,5%electrical resistance increases after 330000 stretching cycles with 100%elongation).These key properties are far superior to those of the state-of-the-art reports.Its robustness and stability are verified under diverse circumstances,including long-term exposure to air(420 days),cyclic submersion(30000 times),and resilience against mechanical damages.The combination of conductivity,stretchability,and durability makes the NHSE a promising conductor/electrode solution for flexible/stretchable electronics for applications such as wearable on-body physiological signal detection,human-machine interaction,and heating e-skin.展开更多
基金supported by Ningbo Municipal 3315 Talent Scheme by Ningbo Science and Technology BureauZhejiang Provincial Natural Science Foundation of China(LQ23F010016 and LR19F010001)。
基金the funding support from National Key R&D Program of China(grant no.2022YFB3807700)Department of Science and Technology of Guangdong Province(no.2017ZT07Z479),Shenzhen Fundamental Research Funding(no.JCYJ20220530113802006)the Major Science,and Technology Infrastructure Project of Shenzhen Material Genome Big-Science Facilities Platform.
文摘Combining material big data with artificial intelligence constitutes the fourth paradigm of material research.However,the sluggish development of highthroughput(HT)experimentation has resulted in a lack of experimentally verified and validated material data,which has become the bottleneck of data-driven material research.Wet-chemical synthesis has the benefits of low equipment cost and scalability,but traditional wet-chemical techniques are time-consuming and ineffective at disclosing the interrelationships between synthesis,compositions,structures,and performance.Constructing a HT workflow in wet-chemical synthesis is crucial to achieving the preparation of multidimensional materials and establishing the composition-structure-synthesis-performance relationships of functional materials for diverse applications.In this review,the most recent development in HT wet-chemical synthesis techniques for material research are analyzed in depth.Additionally,the application of HT wet-chemical synthesis in the fabrication of advanced hydrogels and catalysts is demonstrated through illustrative instances.Finally,this review suggests possible paths for enhancing the efficiency of HT experimentation and data acquisition in order to facilitate more effective material discovery.
基金supported by Ningbo Municipal 3315 Talent Scheme by Ningbo Science and Technology Bureau,the Zhejiang Provincial Natural Science Foundation of China (Grant LR19F010001).
文摘Flexible piezoresistive pressure sensor with high sensitivity over a broad linearity range have been attracting tremendous attention for its applications in health monitoring,artificial intelligence,and human-machine interfaces.Herein,we report a hierarchical insitu filling porous piezoresistive sensor(HPPS)by direct ink writing(DIW)printing and curing of carbon nanofibers(CNFs)/polydimethylsiloxane(PDMS)emulsion.Hierarchical geometry significantly increases the contact area,distributes stress to multilayered lattice and internal porous structure,resulting in a broad sensing range.Moreover,unlike conventional hollow porous structure,the CNFs networks in-situ filling porous structure generates more contact sites and conductive pathways during compression,thereby achieving high sensitivity and linearity over entire sensing range.Therefore,the optimized HPPS achieves high sensitivity(4.7 kPa^(−1))and linearity(coefficient of determination,R^(2)=0.998)over a broad range(0.03-1000 kPa),together with remarkable response time and repeatability.Furthermore,the applications in diverse pressure scenarios and healthcare monitoring are demonstrated.
文摘The development of stretchable electronics could enhance novel interface structures to solve the stretchability-conductivity dilemma,which remains a major challenge.Herein,we report a nano-liquid metal(LM)-based highly robust stretchable electrode(NHSE)with a self-adaptable interface that mimics water-tonet interaction.Based on the in situ assembly of electrospun elastic nanofiber scaffolds and electrosprayed LM nanoparticles,the NHSE exhibits an extremely low sheet resistance of 52 mΩsq^(-1).It is not only insensitive to a large degree of mechanical stretching(i.e.,350%electrical resistance change upon 570%elongation)but also immune to cyclic deformation(i.e.,5%electrical resistance increases after 330000 stretching cycles with 100%elongation).These key properties are far superior to those of the state-of-the-art reports.Its robustness and stability are verified under diverse circumstances,including long-term exposure to air(420 days),cyclic submersion(30000 times),and resilience against mechanical damages.The combination of conductivity,stretchability,and durability makes the NHSE a promising conductor/electrode solution for flexible/stretchable electronics for applications such as wearable on-body physiological signal detection,human-machine interaction,and heating e-skin.
