In the present work, the effect of oxides on the alkylation of benzene with 1-dodecene was comprehensively investigated over MCM-49 n-heptanol, n-heptaldehyde and n-heptanoic acid were selected as the model oxides her...In the present work, the effect of oxides on the alkylation of benzene with 1-dodecene was comprehensively investigated over MCM-49 n-heptanol, n-heptaldehyde and n-heptanoic acid were selected as the model oxides herein, and obvious decrease of lifetime could be caused by only trace amount of oxides added in the feedstocks. However, the deactivated catalysts were difficult to be regenerated by extraction with hot benzene. Additionally, coke-burning was also proved to be incapable to regenerate the deactivated catalysts mainly for the dealumination during calcination. Further characterizations complementary with DFT calculations were conducted to demonstrate that the deactivation was mainly due to the firm adsorption of oxides on the acid sites.展开更多
In this paper,a fault-tolerant control method for an input-series output-parallel modular grid-tied pulse-width modulation(PWM)current source inverter is proposed to address the most commonly seen single symmetrical g...In this paper,a fault-tolerant control method for an input-series output-parallel modular grid-tied pulse-width modulation(PWM)current source inverter is proposed to address the most commonly seen single symmetrical gate-commutated thyristor(SGCT)open-circuit fault problems.This method actively offsets the neutral point of the current space vector to ensure a sinusoidal output of the grid current,and it can achieve the upper limit power of the inverter under the condition of a single SGCT open-circuit fault.In addition,an active damping control method based on grid harmonic current feedback is proposed after analyzing the influence of the transformer ferromagnetic resonance caused by the neutral point offset on the power quality of the grid current.It has been demonstrated that the proposed method effectively suppresses the resonance caused by the transformer and the modified modulation,improving the grid current’s power quality.展开更多
文摘In the present work, the effect of oxides on the alkylation of benzene with 1-dodecene was comprehensively investigated over MCM-49 n-heptanol, n-heptaldehyde and n-heptanoic acid were selected as the model oxides herein, and obvious decrease of lifetime could be caused by only trace amount of oxides added in the feedstocks. However, the deactivated catalysts were difficult to be regenerated by extraction with hot benzene. Additionally, coke-burning was also proved to be incapable to regenerate the deactivated catalysts mainly for the dealumination during calcination. Further characterizations complementary with DFT calculations were conducted to demonstrate that the deactivation was mainly due to the firm adsorption of oxides on the acid sites.
文摘In this paper,a fault-tolerant control method for an input-series output-parallel modular grid-tied pulse-width modulation(PWM)current source inverter is proposed to address the most commonly seen single symmetrical gate-commutated thyristor(SGCT)open-circuit fault problems.This method actively offsets the neutral point of the current space vector to ensure a sinusoidal output of the grid current,and it can achieve the upper limit power of the inverter under the condition of a single SGCT open-circuit fault.In addition,an active damping control method based on grid harmonic current feedback is proposed after analyzing the influence of the transformer ferromagnetic resonance caused by the neutral point offset on the power quality of the grid current.It has been demonstrated that the proposed method effectively suppresses the resonance caused by the transformer and the modified modulation,improving the grid current’s power quality.
