An acrylic modified pumpkin vine-based biochar(p-PVB-PAA) is synthesized by non-thermal plasma-grafting modification of pumpkin vine-based biochar(PVB) for the removal of uranyl from an aqueous solution. Microscopic c...An acrylic modified pumpkin vine-based biochar(p-PVB-PAA) is synthesized by non-thermal plasma-grafting modification of pumpkin vine-based biochar(PVB) for the removal of uranyl from an aqueous solution. Microscopic characterization reveals that compared to PVB the surface of p-PVBPAA has more oxygen-containing functional groups by strong chemical bonding and the specific surface area is increased to 275.3 m^2 g^-1 from 3.8 m^2g^-1. It is found that p-PVB-PAA showed a much higher maximum adsorption capacity for uranyl from aqueous solutions than PVB, which were207.02 mg g^-1 and 67.58 mg g^-1 at pH=5 and 298 K, respectively. Moreover, the adsorption behavior follows a pseudo-second-order kinetics model and the Langmuir adsorption model.Additionally, macroscopic experiments and spectroscopic studies verified that the significantly improved adsorption performance of the p-PVB-PAA is due to surface complexation and electrostatic interactions. Furthermore, the very high removal efficiency and excellent regeneration ability(the percentage of the removal still remained at nearly 90% after five cycles) makes this low-cost, easily obtained, and environmentally friendly material attractive for commercial application.展开更多
基金financially supported by the National High Technology Research and Development Program of China (No. 21677146)National Natural Science Foundation of China (Nos. 21876178, U1607102)the Anhui Provincial Natural Science Foundation (No. 1708085MB31)
文摘An acrylic modified pumpkin vine-based biochar(p-PVB-PAA) is synthesized by non-thermal plasma-grafting modification of pumpkin vine-based biochar(PVB) for the removal of uranyl from an aqueous solution. Microscopic characterization reveals that compared to PVB the surface of p-PVBPAA has more oxygen-containing functional groups by strong chemical bonding and the specific surface area is increased to 275.3 m^2 g^-1 from 3.8 m^2g^-1. It is found that p-PVB-PAA showed a much higher maximum adsorption capacity for uranyl from aqueous solutions than PVB, which were207.02 mg g^-1 and 67.58 mg g^-1 at pH=5 and 298 K, respectively. Moreover, the adsorption behavior follows a pseudo-second-order kinetics model and the Langmuir adsorption model.Additionally, macroscopic experiments and spectroscopic studies verified that the significantly improved adsorption performance of the p-PVB-PAA is due to surface complexation and electrostatic interactions. Furthermore, the very high removal efficiency and excellent regeneration ability(the percentage of the removal still remained at nearly 90% after five cycles) makes this low-cost, easily obtained, and environmentally friendly material attractive for commercial application.
