A high performance preoxidized poly(acrylonitrile)(O-PAN)nanofiber membrane with excellent solvent resistance,thermal stability and flexibility was fabricated by the preoxidation of electrospun PAN nanofiber membrane....A high performance preoxidized poly(acrylonitrile)(O-PAN)nanofiber membrane with excellent solvent resistance,thermal stability and flexibility was fabricated by the preoxidation of electrospun PAN nanofiber membrane.The performance of resultant O-PAN nanofiber membrane was optimized by altering the PAN concentration and preoxidation temperature.The results showed that the O-PAN nanofiber membrane which made from PAN concentration of 14%(mass)and preoxidation temperature of 250.0℃ have a more optimal comprehensive performance.In the long-term separation test of SiO2 particle(1 μm)in DMAc suspension,the permeate flux of O-PAN nanofiber membrane stabilized at 227.91 L·m^(-2)·h^(-1)(25℃,0.05 MPa)while the SiO2 rejection above 99.6%,which showed excellent solvent resistance and separation performance.In order to further explore the application of the O-PAN nanofiber membrane,the OPAN nanofiber membrane was treated with fluoride and used in oil/water separation process.The O-PAN nanofiber membrane after hydrophobic treatment showed excellent hydrophobicity and good oil/water separation performance with the permeate flux about 969.59 L·m^(-2)·h^(-1)while the separation efficiency above 96.1%.The O-PAN nanofiber membrane exhibited a potential application prospect in harsh environment separation.展开更多
With the rapid development of wireless communication technology,the Internet of Things is playing an increasingly important role in our everyday.The amount of data generated by sensor devices is increasing as a large ...With the rapid development of wireless communication technology,the Internet of Things is playing an increasingly important role in our everyday.The amount of data generated by sensor devices is increasing as a large number of connectable devices are deployed in many fields,including the medical,agricultural,and industrial areas.Uploading data to the cloud solves the problem of data overhead but results in privacy issues.Therefore,the question of how to manage the privacy of uploading data and make it available to be interconnected between devices is a crucial issue.In this paper,we propose a scheme that supports real-time authentication with conjunctive keyword detection(RA-CKD),this scheme can realize the interconnection of encrypted data between devices while ensuring some measure of privacy for both encrypted data and detection tokens.Through authentication technology,connected devices can both authenticate each other’s identity and prevent malicious adversaries from interfering with device interconnection.Finally,we prove that our scheme can resist inside keyword guessing attack through rigorous security reduction.The experiment shows that the efficiency of RA-CKD is good enough to be practical.展开更多
基金supported by the Science and Technology Plans of Tianjin(18PTSYJC00170)the Young Elite Scientists Sponsorship Program by China Association for Science and Technology(YESS20160168)The Analytical&Testing Center of Tiangong University was appreciated.
文摘A high performance preoxidized poly(acrylonitrile)(O-PAN)nanofiber membrane with excellent solvent resistance,thermal stability and flexibility was fabricated by the preoxidation of electrospun PAN nanofiber membrane.The performance of resultant O-PAN nanofiber membrane was optimized by altering the PAN concentration and preoxidation temperature.The results showed that the O-PAN nanofiber membrane which made from PAN concentration of 14%(mass)and preoxidation temperature of 250.0℃ have a more optimal comprehensive performance.In the long-term separation test of SiO2 particle(1 μm)in DMAc suspension,the permeate flux of O-PAN nanofiber membrane stabilized at 227.91 L·m^(-2)·h^(-1)(25℃,0.05 MPa)while the SiO2 rejection above 99.6%,which showed excellent solvent resistance and separation performance.In order to further explore the application of the O-PAN nanofiber membrane,the OPAN nanofiber membrane was treated with fluoride and used in oil/water separation process.The O-PAN nanofiber membrane after hydrophobic treatment showed excellent hydrophobicity and good oil/water separation performance with the permeate flux about 969.59 L·m^(-2)·h^(-1)while the separation efficiency above 96.1%.The O-PAN nanofiber membrane exhibited a potential application prospect in harsh environment separation.
基金This work is supported by the National Natural Science Foundation of China(No.62072240)the National Key Research and Development Program of China(No.2020YFB1804604).
文摘With the rapid development of wireless communication technology,the Internet of Things is playing an increasingly important role in our everyday.The amount of data generated by sensor devices is increasing as a large number of connectable devices are deployed in many fields,including the medical,agricultural,and industrial areas.Uploading data to the cloud solves the problem of data overhead but results in privacy issues.Therefore,the question of how to manage the privacy of uploading data and make it available to be interconnected between devices is a crucial issue.In this paper,we propose a scheme that supports real-time authentication with conjunctive keyword detection(RA-CKD),this scheme can realize the interconnection of encrypted data between devices while ensuring some measure of privacy for both encrypted data and detection tokens.Through authentication technology,connected devices can both authenticate each other’s identity and prevent malicious adversaries from interfering with device interconnection.Finally,we prove that our scheme can resist inside keyword guessing attack through rigorous security reduction.The experiment shows that the efficiency of RA-CKD is good enough to be practical.