废旧聚氨酯泡沫醇解产物作为再生剂实现废橡胶的力化学再生

近年来,废聚氨酯和废橡胶产量呈上升趋势,其资源化循环利用成为研究热点。文中使用丙二醇作为醇解剂在不同温度下分解聚氨酯泡沫,并利用聚氨酯醇解产物作为再生剂实现了废橡胶的力化学再生。醇解产物下层液(PAPL)含有较多的胺类基团,可与橡胶再生过程中产生的自由基结合,提高橡胶的脱硫程度,从而提高再生胶(RRs)的力学性能。与只填加活化剂的RRs相比,在原有活化剂填加份数的基础上,加入PAPL可缩短RRs的最佳硫化时间,提高交联密度。使用180℃制备的聚氨酯醇解产物下层液,RRs硫化橡胶的综合性能最好,拉伸强度达到15.6MPa,断裂伸长率达到325.5%。该方法实现了废聚氨酯和废橡胶的双重高价值回收,应用前景广阔。

Analysis of technology pathway of China's liquid fuel production with consideration of energy supply security and carbon price

Efforts to provide alternative resources and technologies for producing liquid fuel have recently been intensified.Different levels of dependence on oil imports and carbon prices have a significant impact on the composition of the cost-minimizing portfolio of technologies.Considering such factors,how should China plan its future liquid fuel industry?The model for supporting the technology portfolio and capacity configuration that minimizes the total system cost until 2045 is described in this study.The results obtained for different carbon prices and levels of dependence on oil import indicate that the oil-to-liquid fuel(OTL)will remain dominant in China's liquid fuel industry over the next three decades.If the carbon price is low,the coal-to-liquid fuel(CTL)process is competitive.For a high carbon price,the biomass-to-liquid fuel(BTL)technology expands more rapidly.The results also reveal that developing the BTL and CTL can effectively reduce the oil-import dependency;moreover,a high carbon price can lead to the CTL being replaced with the low-carbon technology(e.g.,BTL).Improvement in energy raw material conversion and application of CO_(2) removal technologies are also effective methods to control carbon emissions for achieving the carbon emission goals and ultimately emission reduction targets.

Levelized costs of the energy chains of new energy vehicles targeted at carbon neutrality in China

The diffusion of new energy vehicles(NEVs),such as battery electric vehicles(BEVs)and fuel cell vehicles(FCVs),is critical to the transportation sector's deep decarbonization.The cost of energy chains is an important factor in the diffusion of NEVs.Although researchers have addressed the technological learning effect of NEVs and the life cycle emissions associated with the diffusion of NEVs,little work has been conducted to analyze the life cycle costs of different energy chains associated with different NEVs in consideration of technological learning potential.Thus,relevant information on investment remains insufficient to promote the deployment of NEVs.This study proposes a systematic framework that includes various(competing or coordinated)energy chains of NEVs formed with different technologies of power generation and transmission,hydrogen production and transportation,power-to-liquid fuel,and fuel transportation.The levelized costs of three typical carbon-neutral energy chains are investigated using the life cycle cost model and considering the technological learning effect.Results show that the current well-to-pump levelized costs of the energy chains in China for BEVs,FCVs,and internal combustion engine vehicles(ICEVs)are approximately 3.60,4.31,and 2.21 yuan/GJ,respectively,and the well-to-wheel levelized costs are 4.50,6.15,and 7.51 yuan/GJ,respectively.These costs primarily include raw material costs and they vary greatly for BEVs and FCVs from resource and consumer costs.In consideration of the technological learning effect,the energy chains'well-to-wheel levelized costs are expected todecrease by 24.82%for BEVs,27.12%for FCVs,and 19.25%for ICEVs by 2060.This work also summarizes policy recommendations on developing energy chains to promote the diffusion of NEVs in China.