Kathon(CMI-MI),a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one(CMI)and 2-methyl-4-isothiazolin-3-one(MI),was extensively used in industry as a nonoxidizing biocide or disinfectant.However,it would show adverse eff...Kathon(CMI-MI),a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one(CMI)and 2-methyl-4-isothiazolin-3-one(MI),was extensively used in industry as a nonoxidizing biocide or disinfectant.However,it would show adverse effects on aquatic life when it is discharged into surface water.In this study,the removal performance,parameter influence,degradation products and enhancement of subsequent biodegradation of CMI-MI in UV/H_(2)O_(2)system were systematically investigated.The degradation rate of CMI-MI could reach 90%under UV irradiation for 20 min when the dosage of H_(2)O_(2)was 0.3 mmol·L^(–1).The DOC(dissolved organic carbon)mineralization rate of CMI-MI could reach 35%under certain conditions([H_(2)O_(2)]=0.3 mmol·L^(–1),UV irradiation for 40 min).kobs was inversely proportional to the concentration of CMI-MI and proportional to the concentration of H_(2)O_(2).The degradation rate of CMIMI was almost unchanged in the pH range from 4 to 10.Except the presence of CO_(3)^(2-)inhibited the removal rate of CMI-MI,SO_(4)^(2-),Cl^(-),NO_(3)^(-),and NH_(4)^(+) did not interfere with the degradation of CMI-MI in the system.It was found that UV/H_(2)O_(2)system had lower energy consumption and more economic advantage compared with UV/PS system by comparing the EEO(electric energy per order)values under the same conditions.Two main organic products were identified,namely HCOOH and CH_(3)NH_(2).There’s also the formation of Cl^(-)and SO_(4)^(2-).After UV and UV/H_(2)O_(2)photolysis,the biochemical properties of CMI-MI solution were obviously improved,especially the UV/H_(2)O_(2)treatment effect was better,indicating that UV/H_(2)O_(2)technology is expected to combine with biotechnology to remove CMI-MI effectively and environmentally friendly from wastewater.展开更多
We developed a hybrid structure photodetector combining one-dimensional(1D)inorganic GaAs nanowires and two-dimensional(2D)organic perovskite materials,which can achieve various performance enhancements using a relati...We developed a hybrid structure photodetector combining one-dimensional(1D)inorganic GaAs nanowires and two-dimensional(2D)organic perovskite materials,which can achieve various performance enhancements using a relatively simple structure.Via the optical absorption enhancement of perovskite and the type-II energy band structure formed by the heterostructure,the responsivity and detectivity of the photodetector from ultraviolet(UV)to visible(Vis)wavelengths are significantly enhanced,reaching 75 A/W and 1.49×10^(11)Jones,respectively.The response time of the photodetector was significantly decreased by 3 orders,from 785 ms to 0.5 ms,and the dark current was further reduced to 237 fA.A photodetector was prepared with enhanced responsivity and ultrafast response time in the multiband region from the UV to Vis wavelength.To the best of our knowledge,this is the first time to combine inorganicⅢ-ⅤGaAs nanomaterials with organic perovskite materials,which verifies the effective combination of inorganic and organic materials in a mixed dimension.The excellent photoelectric performance of the perovskite/GaAs-nanowire hybrid structure photodetector makes it a potential candidate material for a wide range of photoelectric applications such as multiband photodetection.展开更多
基金support of experimental Instrument Platform of Shandong Taihe Water Treatment Technology Co.,LTD.
文摘Kathon(CMI-MI),a mixture of 5-chloro-2-methyl-4-isothiazolin-3-one(CMI)and 2-methyl-4-isothiazolin-3-one(MI),was extensively used in industry as a nonoxidizing biocide or disinfectant.However,it would show adverse effects on aquatic life when it is discharged into surface water.In this study,the removal performance,parameter influence,degradation products and enhancement of subsequent biodegradation of CMI-MI in UV/H_(2)O_(2)system were systematically investigated.The degradation rate of CMI-MI could reach 90%under UV irradiation for 20 min when the dosage of H_(2)O_(2)was 0.3 mmol·L^(–1).The DOC(dissolved organic carbon)mineralization rate of CMI-MI could reach 35%under certain conditions([H_(2)O_(2)]=0.3 mmol·L^(–1),UV irradiation for 40 min).kobs was inversely proportional to the concentration of CMI-MI and proportional to the concentration of H_(2)O_(2).The degradation rate of CMIMI was almost unchanged in the pH range from 4 to 10.Except the presence of CO_(3)^(2-)inhibited the removal rate of CMI-MI,SO_(4)^(2-),Cl^(-),NO_(3)^(-),and NH_(4)^(+) did not interfere with the degradation of CMI-MI in the system.It was found that UV/H_(2)O_(2)system had lower energy consumption and more economic advantage compared with UV/PS system by comparing the EEO(electric energy per order)values under the same conditions.Two main organic products were identified,namely HCOOH and CH_(3)NH_(2).There’s also the formation of Cl^(-)and SO_(4)^(2-).After UV and UV/H_(2)O_(2)photolysis,the biochemical properties of CMI-MI solution were obviously improved,especially the UV/H_(2)O_(2)treatment effect was better,indicating that UV/H_(2)O_(2)technology is expected to combine with biotechnology to remove CMI-MI effectively and environmentally friendly from wastewater.
基金National Natural Science Foundation of China(11804335,12074045,61904017,62027820)OpenFoundation of Key Laboratory of Laser Technology+2 种基金China North Industries Group Corporation Limited(KLLDT202105)Youth Foundation of ChangchunUniversity of Science and Technology(XQNJJ-2018-18)“111”Project of China(D17017)。
文摘We developed a hybrid structure photodetector combining one-dimensional(1D)inorganic GaAs nanowires and two-dimensional(2D)organic perovskite materials,which can achieve various performance enhancements using a relatively simple structure.Via the optical absorption enhancement of perovskite and the type-II energy band structure formed by the heterostructure,the responsivity and detectivity of the photodetector from ultraviolet(UV)to visible(Vis)wavelengths are significantly enhanced,reaching 75 A/W and 1.49×10^(11)Jones,respectively.The response time of the photodetector was significantly decreased by 3 orders,from 785 ms to 0.5 ms,and the dark current was further reduced to 237 fA.A photodetector was prepared with enhanced responsivity and ultrafast response time in the multiband region from the UV to Vis wavelength.To the best of our knowledge,this is the first time to combine inorganicⅢ-ⅤGaAs nanomaterials with organic perovskite materials,which verifies the effective combination of inorganic and organic materials in a mixed dimension.The excellent photoelectric performance of the perovskite/GaAs-nanowire hybrid structure photodetector makes it a potential candidate material for a wide range of photoelectric applications such as multiband photodetection.