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温度对不同相对分子质量缓释型聚羧酸保坍剂性能的影响 被引量:2
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作者 刘金芝 李申桐 +3 位作者 张建纲 杨勇 舒鑫 冉千平 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2019年第3期60-65,共6页
将丙烯酸羟丙酯引入保坍剂(PCE)中,合成了4种不同相对分子质量(M_w)的缓释型聚羧酸保坍剂,系统研究了温度对不同M_w保坍剂的分散和分散保持、水解速率及吸附进程的影响。随温度升高,PCE水解速率增大,吸附量增加,但初始流动度减小。低温... 将丙烯酸羟丙酯引入保坍剂(PCE)中,合成了4种不同相对分子质量(M_w)的缓释型聚羧酸保坍剂,系统研究了温度对不同M_w保坍剂的分散和分散保持、水解速率及吸附进程的影响。随温度升高,PCE水解速率增大,吸附量增加,但初始流动度减小。低温(20℃)时,随着M_w减小,吸附速率(K)变小,吸附变慢,浆体溶液中残留的保坍剂分子多,可进一步发挥分散作用,低M_w样品的保坍能力优异。高温(30℃和40℃)时,随着M_w减小,K变大,吸附加快,浆体中残留的分子较少,且高温使水泥水化速度加快,分子更易被水化产物包埋,分散保持性能变差,合适M_w的样品初始分散性能优异,后期保坍能力也优异,温度对水化的影响超过对PCE水解速率增加的分散作用。 展开更多
关键词 相对分子质量 分散和分散保持 水解速率 吸附动力学 温度
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Channel Capacity Optimization Based on Riemannian Trust Region Algorithm in IRS-Aided Communication System
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作者 jinzhi liu Dan Wang +1 位作者 Jiamin Liang Zhiqiang Mei 《China Communications》 SCIE CSCD 2022年第10期21-37,共17页
Intelligent Reflecting Surface (IRS) can offer unprecedented channel capacity gains since it can reconfigure the signal propagation environment. We decide to maximize the channel capacity by jointly optimizing the tra... Intelligent Reflecting Surface (IRS) can offer unprecedented channel capacity gains since it can reconfigure the signal propagation environment. We decide to maximize the channel capacity by jointly optimizing the transmit-power-constrained precoding matrix at the base station and the unit-modulus-constrained phase shift vector at the IRS in IRS-assisted multi-user downlink communication. We first convert the resulting non-convex problem into an equivalent problem, then use the alternate optimization algorithm. While fixing the phase shift vector, we can obtain the optimal precoding matrix directly by adopting standard optimization packages. While fixing the precoding matrix, we propose the Riemannian Trust-Region (RTR) algorithm to solve this optimization problem. And the key of the RTR algorithm is the solution of the trust-region sub-problem. We first adopt the accurate solution based on Newton's (ASNT) method to solve this sub-problem, which can obtain the global solution but cannot guarantee that the solution is optimal since the initial iteration point is difficult to choose. Then, we propose the Improved-Polyline (IPL) method, which can avoid the difficulty of the ASNT method and improve convergence speed and calculation efficiency. The numerical results show that the RTR algorithm has more significant performance gains and faster convergence speed compared with the existing approaches. 展开更多
关键词 intelligent reflecting surface(IRS) MULTI-USER MIMO channel capacity unit modulus constraint Riemannian manifold optimization
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