Suppression and mitigation of inter-ELM high-frequency Alfvén-like mode by resonant magnetic perturbation in EAST

Suppression and mitigation of a high-frequency Alfvén-like mode(HFAM)between type-I edge localized modes(ELMs)during ELM mitigation by resonant magnetic perturbation(RMP)is observed for the first time in the EAST tokamak.This mode is located near the edge pedestal region.The modeling result of the Alfvén continuum shows that the HFAM is located near the elipical Alfvén eigenmode(EAE)gap.During the application of n=1 RMP for ELM mitigation,the HFAM can be fully suppressed when the RMP amplitude exceeds a threshold,below which the HFAM is mitigated.The suppression is caused by a reduction of pedestal height induced by RMP.In the case using n=3 RMP,the mode is localized toroidally at specific phase depending on the phase of applied RMP,i.e.locked in the three-dimensional equilibrium formed by RMP.The dominant toroidal mode number of HFAM is around n=-6 and it reduces to-3 during the application of n=3 RMP,which indicates the existence of possible nonlinear coupling between the HFAM and RMP.Here the negative mode number denotes that the mode rotates in electron diamagnetic drift direction.The observation reported here improves the understanding of pedestal dynamics and its stability in RMP ELM control.

Synthesis and energy transfer of model conjugate of phycobilisome rods

The conjugate of R-phycoerythrin (R-PE) and C-phycocyanin (C-PC) was synthesized through a heterobifunctional coupling reagent, N-succinimidyl 3-(2-pyridyldithio) propionate. The molar ratio of R-PE to C-PC was determined by absorption spectra, and the result was 2:1. The energy transfer phenomena were observed from steady-state fluorescence spectra. The calculated result showed that the energy transfer efficiency from R-PE to C-PC was 88%. The energy transfer kinetics was determined by picosecond time-resolved fluorescence spectra. The time constant of energy transfer from R-PE to C-PC was 80 ps, which was much longer than that in the rood of native phycobilisomes.

Transition-Metal-Free Catalyzed Dehydrative Coupling of Quinoline and Isoquinoline N-Oxides with Propargylic Alcohols

A novel,green,and transition-metal-free protocol for the facile modification of quinoline and isoquinoline derivatives is introduced,starting from readily available and environmentally benign quinoline and isoquinoline N-oxides with propargylic alcohols in the presence of Na_(2)S_(2)O_(8) or K_(2)S_(2)O_(8) at 100℃.The one-pot transformation features the advantages of good functional group compatibility,short reaction time,operational simplicity,and highly efficient reaction system.This protocol,which produces water as the only byproduct,provides efficient and atom-economical access to a class of fascinating quinoline and isoquinoline products in satisfactory yields.The method is effective on the gram scale,thus highlighting the inherent practicality of this methodology.