We develop a novel coumarin-all〈yne derivative （NC7-AL）, which can specifically react with Au^3＋ and give a colorimetric and fluorescent ＂turn-on＂ response toward Au3~, Notably, other alkynophilic metal species ...We develop a novel coumarin-all〈yne derivative （NC7-AL）, which can specifically react with Au^3＋ and give a colorimetric and fluorescent ＂turn-on＂ response toward Au3~, Notably, other alkynophilic metal species such as Au^＋, Ag^＋, Pd^2＋, Ni^2＋, Cu^2＋, and Hg^2＋ do not produce an interfering signal. A good linear relationship between emission intensity at 420 nm and Au^3＋ concentration from 0 to 2 equivalent is observed, and the detection limit （3σ/k） is estimated to be ca. 3.58 nmol/L. Harnessing the Au^3＋ .展开更多
基金supported by the National Natural Science Foundation of China (Nos. 21102001, 21271035 and 21372005)Anhui Provincial Natural Science Foundation (No. 1608085MB39)+1 种基金Natural Science Foundation of Education Department of Anhui Province (Nos. KJ2015A047, KJ2014A013)211 Project of Anhui University
文摘We develop a novel coumarin-all〈yne derivative （NC7-AL）, which can specifically react with Au^3＋ and give a colorimetric and fluorescent ＂turn-on＂ response toward Au3~, Notably, other alkynophilic metal species such as Au^＋, Ag^＋, Pd^2＋, Ni^2＋, Cu^2＋, and Hg^2＋ do not produce an interfering signal. A good linear relationship between emission intensity at 420 nm and Au^3＋ concentration from 0 to 2 equivalent is observed, and the detection limit （3σ/k） is estimated to be ca. 3.58 nmol/L. Harnessing the Au^3＋ .
