Wearable electronics on fibers or fabrics assembled with electronic functions provide a platform for sensors,displays,circuitry,and computation.These new conceptual devices are human-friendly and programmable,which ma...Wearable electronics on fibers or fabrics assembled with electronic functions provide a platform for sensors,displays,circuitry,and computation.These new conceptual devices are human-friendly and programmable,which makes them indis-pensable for modern electronics.Their unique properties such as being adaptable in daily life,as well as being lightweight and flexible,have enabled many promising applications in robotics,healthcare,and the Internet of Things(IoT).Transistors,one of the fundamental blocks in electronic systems,allow for signal processing and computing.Therefore,study leading to integration of transistors with fabrics has become intensive.Here,several aspects of fiber-based transistors are addressed,including materials,system structures,and their functional devices such as sensory,logical circuitry,memory devices as well as neuromorphic computation.Recently reported advances in development and challenges to realizing fully integrated electronic textile(e-textile)systems are also discussed.展开更多
InSb is a narrow-bandgap semiconductor with a zinc blende structure and has been wildly applied in photodetectors, infrared thermal imaging, and Hall devices. The facts of decent band structure, ultrahigh electron mob...InSb is a narrow-bandgap semiconductor with a zinc blende structure and has been wildly applied in photodetectors, infrared thermal imaging, and Hall devices. The facts of decent band structure, ultrahigh electron mobility,and nontoxic nature indicate that InSb may be a potential mid-temperature thermoelectric material. The critical challenges of InSb, such as high thermal conductivity and small Seebeck coefficient, have induced its ultrahigh lattice thermal conductivity, and thus low ZT values. In view of this, we have developed a competitive strategy typified by the cost-efficient nanocompositing of z wt% QSe_(2)(Q = Sn, W). Specifically, the Q_(In)^(+) and Se_(Sb)^(+) point defects were introduced in the In Sb system by nanocompositing the vested two-dimensional layered QSe_(2). In addition, the enlarged valence band maximum of intrinsic WSe_(2)acted as ladders can scatter a fair number of hole carriers, resulting in the relatively enhanced Seebeck coefficient of high temperature. Moreover, the disorderly distributed nanosheets/particles, and dislocations acting as obstacles can effectively delay the heat flow diffusion, inducing the strong scattering of thermal phonons. Consequently, an enhanced power factor of ~33.3 μW cm^(-1)K^(-2) and ZT value of~0.82 at 733 K have been achieved in the 3% WSe_(2)sample,companied with the engineering output power density ω_(max)~233 μW cm^(-1) and thermoelectric conversion efficiency η~5.2%. This artificially designed approach indicated by suited nanocompositing can integrate several engineering strategies such as point defects, nanoengineering, and energy filtering into one, providing a reference to optimize the thermoelectric performance of other thermoelectric systems.展开更多
基金This work was supported by the Singapore Ministry of Education Academic Research Fund Tier 2(Nos.MOE2019-T2-2-127 and MOE-T2EP50120-0002),A*STAR under AME IRG(No.A2083c0062)the Singapore Ministry of Education Academic Research Fund Tier 1(Nos.RG90/19 and RG73/19)the Singapore National Research Foundation Competitive Research Program(No.NRF-CRP18-2017-02)。
文摘Wearable electronics on fibers or fabrics assembled with electronic functions provide a platform for sensors,displays,circuitry,and computation.These new conceptual devices are human-friendly and programmable,which makes them indis-pensable for modern electronics.Their unique properties such as being adaptable in daily life,as well as being lightweight and flexible,have enabled many promising applications in robotics,healthcare,and the Internet of Things(IoT).Transistors,one of the fundamental blocks in electronic systems,allow for signal processing and computing.Therefore,study leading to integration of transistors with fabrics has become intensive.Here,several aspects of fiber-based transistors are addressed,including materials,system structures,and their functional devices such as sensory,logical circuitry,memory devices as well as neuromorphic computation.Recently reported advances in development and challenges to realizing fully integrated electronic textile(e-textile)systems are also discussed.
基金supported by the National Natural Science Foundation of China (92163211 and 51872102)Foshan (Southern China) Institute for New Materials (2021AYF25005)+3 种基金Singapore Ministry of Education Academic Research Fund Tier 2 (MOE2019-T2-2-127 and MOET2EP50120-0002)the A*STAR under AME IRG (A2083c0062)Singapore Ministry of Education Academic Research Fund Tier 1 (RG90/19 and RG73/ 19)Singapore National Research Foundation Competitive Research Program (NRF-CRP18-2017-02)。
文摘InSb is a narrow-bandgap semiconductor with a zinc blende structure and has been wildly applied in photodetectors, infrared thermal imaging, and Hall devices. The facts of decent band structure, ultrahigh electron mobility,and nontoxic nature indicate that InSb may be a potential mid-temperature thermoelectric material. The critical challenges of InSb, such as high thermal conductivity and small Seebeck coefficient, have induced its ultrahigh lattice thermal conductivity, and thus low ZT values. In view of this, we have developed a competitive strategy typified by the cost-efficient nanocompositing of z wt% QSe_(2)(Q = Sn, W). Specifically, the Q_(In)^(+) and Se_(Sb)^(+) point defects were introduced in the In Sb system by nanocompositing the vested two-dimensional layered QSe_(2). In addition, the enlarged valence band maximum of intrinsic WSe_(2)acted as ladders can scatter a fair number of hole carriers, resulting in the relatively enhanced Seebeck coefficient of high temperature. Moreover, the disorderly distributed nanosheets/particles, and dislocations acting as obstacles can effectively delay the heat flow diffusion, inducing the strong scattering of thermal phonons. Consequently, an enhanced power factor of ~33.3 μW cm^(-1)K^(-2) and ZT value of~0.82 at 733 K have been achieved in the 3% WSe_(2)sample,companied with the engineering output power density ω_(max)~233 μW cm^(-1) and thermoelectric conversion efficiency η~5.2%. This artificially designed approach indicated by suited nanocompositing can integrate several engineering strategies such as point defects, nanoengineering, and energy filtering into one, providing a reference to optimize the thermoelectric performance of other thermoelectric systems.