期刊文献+
共找到2篇文章
< 1 >
每页显示 20 50 100
丙烯酸酯三嵌段共聚物改性环氧树脂及其性能 被引量:6
1
作者 刘仲良 李洪峰 +3 位作者 顾继友 王德志 曲春艳 杨海冬 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2018年第2期24-31,36,共9页
通过原子转移自由基聚合(ATRP)法合成了硬-软-硬结构的ABA型嵌段共聚物(PMG-PBA-PMG)。采用核磁共振波谱仪、凝胶渗透色谱仪、傅里叶变换红外光谱仪分析确定了嵌段共聚物分子的结构及成分。利用嵌段共聚物改性环氧树脂,研究其热性能、... 通过原子转移自由基聚合(ATRP)法合成了硬-软-硬结构的ABA型嵌段共聚物(PMG-PBA-PMG)。采用核磁共振波谱仪、凝胶渗透色谱仪、傅里叶变换红外光谱仪分析确定了嵌段共聚物分子的结构及成分。利用嵌段共聚物改性环氧树脂,研究其热性能、流变学性能、力学性能、微观形貌、相容性及增韧机制。结果表明,丙烯酸酯三嵌段共聚物用量为10 phr时,共混体系的综合性能达到最佳,确定体系固化工艺为150℃×1 h+180℃×3 h;缺口冲击强度可达7.34 k J/m2,弯曲强度118 MPa,断裂伸长率4.8%,拉伸强度为80 MPa,弹性模量为2931 MPa;共混体系保持较宽的温度加工窗口,可作为复合材料预浸料树脂基体;此外,扫描电镜断面出现大量的锯齿,可有效阻碍裂纹的扩展并吸收大量的断裂能,从而提高环氧树脂的韧性。 展开更多
关键词 丙烯酸酯嵌段共聚物 环氧树脂改性 力学性能 热性能 相容性
下载PDF
Curing Behaviour of MUF Resin in the Presence of Less Desirable Wood Material
2
作者 Jianing Zhao Jun Cao jiyou gu 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2015年第1期106-110,共5页
In order to investigate the effect of different wood species on the curing of MUF resin,DSC spectroscopic analysis and a new procedure are used, an important component in wood composites manufacturing. The MUF resin i... In order to investigate the effect of different wood species on the curing of MUF resin,DSC spectroscopic analysis and a new procedure are used, an important component in wood composites manufacturing. The MUF resin is synthesised with an initial weak acidic condition. The final molar ratios of F /( M+U) and M / U are 1. 37 and 0. 32,respectively. Samples are prepared by mixing MUF resin with wood flours from different wood species. The curing behaviour and transformation of chemical groups are analysed by DSC. The curing activation energy of MUF resin generally decreases when the resin is mixed with wood flours due to the influence of wood extracts. When the heat rate is 5 ℃ / min,the relationship between the peak temperature of the MUF resin and p H values or base buffer capacities is observed. 展开更多
关键词 ADHESIVE reaction of CURING DSC WOOD SPECIES
下载PDF
上一页 1 下一页 到第
使用帮助 返回顶部