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Catalytic conversion of glucose to small polyols over a binary catalyst of vanadium modified beta zeolite and Ru/C
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作者 joby sebastian Mingyuan Zheng +3 位作者 Xinsheng Li Jifeng Pang Chan Wang Tao Zhang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2019年第7期88-95,共8页
Catalytic conversion of glucose, the most abundant carbohydrate, to chemicals of petroleum origin has great desirability in terms of sustainability and industrial implementation. In this work, we attempted to exploit ... Catalytic conversion of glucose, the most abundant carbohydrate, to chemicals of petroleum origin has great desirability in terms of sustainability and industrial implementation. In this work, we attempted to exploit the vanadium-based catalysts with high retro-aldol condensation(RAC) activity for the synthesis of small polyols from glucose. Vanadium species incorporated or anchored beta zeolites were found to work effectively in synergy with 1 Ru/AC to produce hydroxyacetone(HA) as the major product(34%)in a semi-continuously stirred tank reactor under 5% glucose concentration. Catalyst characterization by UV-vis and Raman spectral analysis revealed vanadium species mainly stayed in the incorporated form(tetrahedral) at 0.5% of loading and in the supported form(octahedral) at higher loadings up to 8%. Pyridine infrared spectra and temperature programmed desorption of NH3 revealed weak Lewis acid sites in dominance. Vanadium species in the catalysts displayed multiple catalytic roles(isomerization and RAC reaction, and synergism with the hydrogenation catalyst) in the synthesis of HA from glucose. Structureactivity correlation pointed out that the catalytic activity of vanadium species is not dependent on it coordination status, nevertheless, the adjacent vanadium atoms could possibly improve the isomerization rate over the RAC rate in favor of high yield of HA. The catalyst system is recyclable to at least five times without any considerable loss in its activity and structural integrity. The results presented here provide a promising route for the sustainable production of HA and polyols from carbohydrates by using a highly selective vanadium catalyst. 展开更多
关键词 VANADIUM GLUCOSE Retro-aldol condensation POLYOLS HYDROXYACETONE
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Preparation and Characterization of ZnSe/EVA Nanocomposites for Photovoltaic Modules
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作者 Jose sebastian Eby Thomas Thachil +4 位作者 Jobin Job Mathen Augustine J. Edakkara Nelson Kuriakose Ginson P. Joseph joby sebastian 《Journal of Minerals and Materials Characterization and Engineering》 2015年第4期215-224,共10页
ZnSe Nanoparticles were synthesized by solvothermal method and the particle was characterized by Transmission Electron Microscopy. The polymer nanocomposite of 2% and 4% ZnSe/EVA was fabricated by direct sonicator met... ZnSe Nanoparticles were synthesized by solvothermal method and the particle was characterized by Transmission Electron Microscopy. The polymer nanocomposite of 2% and 4% ZnSe/EVA was fabricated by direct sonicator method. The nanocomposites were characterized by UV-Vis-NIR and FT-IR spectroscopy. The thermal behaviour of the samples was also investigated and we found that the thermal stability of the composites increased with increasing the filler concentrations. The mechanical properties such as tensile strength, peel strength and refractive index of the samples were also studied and reported for the first. 展开更多
关键词 EVA ZNSE TG-DTA Refractive Index PEEL STRENGTH TENSILE STRENGTH
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