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一步法烟气浸锰-脱硫的工艺参数及机理 被引量:2
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作者 潘建 朱德庆 +2 位作者 何奥平 john clout 李建 《环境化学》 CAS CSCD 北大核心 2006年第5期607-610,共4页
应用一步法烟气浸锰-脱硫的新工艺,考察烟气流量、烟气SO2浓度、吸收时间、液固比及浸出时间等工艺参数对烟气氧化脱硫效果的影响,并运用溶液化学原理,对SO2及Mn2+在溶液中的组分进行了计算,研究Mn2+液相催化氧化烟气脱硫的机理.在吸收... 应用一步法烟气浸锰-脱硫的新工艺,考察烟气流量、烟气SO2浓度、吸收时间、液固比及浸出时间等工艺参数对烟气氧化脱硫效果的影响,并运用溶液化学原理,对SO2及Mn2+在溶液中的组分进行了计算,研究Mn2+液相催化氧化烟气脱硫的机理.在吸收液pH值5—6时,锰主要以Mn2+形态存在,Mn2+的存在强化了从HSO-3开始发生的SO2氧化反应.采用菱锰矿为原料,能有效地脱除含SO2烟气中的硫,在实现烟气脱硫的同时自动调节溶液的pH值,并可从浸出液中回收高价值的硫酸锰.在最佳的工艺条件下,仅一步吸收过程,取得了锰浸出率85%,含SO2烟气脱硫率70%以上的效果. 展开更多
关键词 烟气 脱硫 浸取 菱镁矿.
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Effect of fluxes on high iron and low silica sintering 被引量:1
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作者 朱德庆 张克诚 +3 位作者 潘建 范晓慧 胡友名 john clout 《Journal of Central South University of Technology》 2003年第3期177-182,共6页
Burnt lime and serpentine were incorporated into the sinter mix to improve high iron and low silica sinte-ring. Optimization of how to use burnt lime including dosage of burnt lime, moisture of sinter mix, hydrating a... Burnt lime and serpentine were incorporated into the sinter mix to improve high iron and low silica sinte-ring. Optimization of how to use burnt lime including dosage of burnt lime, moisture of sinter mix, hydrating andgranulation time was performed. Evaluations of sinter characteristics including sinter mineralogy, reducibility, lowtemperature reduction degradation, softening and melting down properties were carried out. Compared with the re-sults of traditional process in base case, the tumbling index (TI) is increased by 1.53%-2.33% through proportio-ning high ratio of burnt lime or adding serpentine in the sinter mix. It is shown that effective granulation, better per-meability and improved high temperature reactivity in the sinter bed are achieved, resulting in an increase in 3.13 %- 5.10% calcium ferrite occurring in acicular and columnar shape and decrease in glass phase, and with the reduc-ibility index(RI) being increased by 1.65%- 3.25%. 展开更多
关键词 HIGH IRON and low silica SINTERING MINERALOGY permeability burnt lime SERPENTINE
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