1-Ethoxycarbonylalkyldiphenylpolystyrylphosphonium triflates can be easily prepared by quaternizing diphenylpolystyryl phosphine with ethyl 2-trifloxyalkanoates;base treatment of these polymer-supported phosphonium t...1-Ethoxycarbonylalkyldiphenylpolystyrylphosphonium triflates can be easily prepared by quaternizing diphenylpolystyryl phosphine with ethyl 2-trifloxyalkanoates;base treatment of these polymer-supported phosphonium triflates affords 1-ethoxycarbonylalkylidenephosphoranes which are stable and undergo satisfactory Wittig reactions.展开更多
文摘1-Ethoxycarbonylalkyldiphenylpolystyrylphosphonium triflates can be easily prepared by quaternizing diphenylpolystyryl phosphine with ethyl 2-trifloxyalkanoates;base treatment of these polymer-supported phosphonium triflates affords 1-ethoxycarbonylalkylidenephosphoranes which are stable and undergo satisfactory Wittig reactions.