Metal organophosphonates have been explored in energy-related fields due to their high chemical and thermal stability as a type of uniformly precursor,but only few of pristine metal organophosphonate are directly used...Metal organophosphonates have been explored in energy-related fields due to their high chemical and thermal stability as a type of uniformly precursor,but only few of pristine metal organophosphonate are directly used for oxygen evolution reaction(OER)catalysts.Here,a mixedvalence iron phosphonate(Fe_(3)-ppat)has been constructed and applied to OER catalysis considered the potential active sites in pillars Fe^(Ⅱ)(-H_(2)O)_(4)(COO)_(2)and inorganic layers Fe^(Ⅲ)(μ_(2)–OH)PO_(3).Specifically,isostructural trimetallic framework Fe_(1.7)Co_(0.3)Ni_(1.0)-ppat possesses a minimum overpotential(291 mV),small Tafel slope(91.65 mV dec^(-1)),and high stability up to 83 h.The enhanced catalytic performance could be mainly ascribed to the synergistic effect of Ni^(Ⅱ)equivalent occupancy in pillars and Co/Fe^(Ⅲ)in layers.展开更多
The discovery of Ξ_(cc)^(++)has inspired new interest in studying doubly heavy baryons.In this study,the weak decays of a doubly charmed baryon B_(cc)to a light baryon B and a charm meson D^(*)(either a pseudoscalar ...The discovery of Ξ_(cc)^(++)has inspired new interest in studying doubly heavy baryons.In this study,the weak decays of a doubly charmed baryon B_(cc)to a light baryon B and a charm meson D^(*)(either a pseudoscalar or a vector one)are calculated.Following our previous work,we calculate the short distance contributions under the factorization hypothesis,whereas the long distance contributions are modeled as the final state interactions,which are calculated with the one particle exchange model.We find that the B_(cc)→BD^(*)decays'branching ratios are obviously larger,as they receive contributions of more polarization states.Among the decays that we investigate,the following have the largest branching fractions:BR(Ξ_(cc)^(++)→∑^(+)D^(*+))∈[0.46%,3.33%]estimated with τΞ_(cc)^(++)=256 fs;BR(Ξ_(cc)^(+)→AD^(*+))∈[0.38%,2.63%]and BR(Ξ_(cc)^(+)→∑^(0)D^(*+))∈[0.45%,3.16%]with τΞ_(cc)^(++)=45 fs;and BR(Ω_(cc)^(+)→Ξ^(0)D^(+))∈[0.27%,1.03%),BR(Ω_(cc)^(+)→∑^(0)D^(*+))∈[0.07%,0.44%],and BR(Ω_(cc)^(+)→∑^(0)D^(*+))∈[0.06%,0.45%] with τ_(Ω_(cc))^(+)=75 fs.By comparing the decay widths of pure color commensurate channels with those of pure bow-tie ones we find that the bow-tie mechanism plays an important role in charm decays.展开更多
基金supported by the National Natural Science Foundation of China(NSFC 21871167)the National Natural Science Fund for Young Scholars of China(NSFC 21201114)+2 种基金the 1331 Engineering of Shanxi ProvinceScientific and Technological Innovation Programs of Higher Education Institutions in Shanxi(2019L0464)Shanxi Province Science Foundation for Youths(201901D211391)。
文摘Metal organophosphonates have been explored in energy-related fields due to their high chemical and thermal stability as a type of uniformly precursor,but only few of pristine metal organophosphonate are directly used for oxygen evolution reaction(OER)catalysts.Here,a mixedvalence iron phosphonate(Fe_(3)-ppat)has been constructed and applied to OER catalysis considered the potential active sites in pillars Fe^(Ⅱ)(-H_(2)O)_(4)(COO)_(2)and inorganic layers Fe^(Ⅲ)(μ_(2)–OH)PO_(3).Specifically,isostructural trimetallic framework Fe_(1.7)Co_(0.3)Ni_(1.0)-ppat possesses a minimum overpotential(291 mV),small Tafel slope(91.65 mV dec^(-1)),and high stability up to 83 h.The enhanced catalytic performance could be mainly ascribed to the synergistic effect of Ni^(Ⅱ)equivalent occupancy in pillars and Co/Fe^(Ⅲ)in layers.
基金National Natural Science Foundation of China(11765012,12075126)。
文摘The discovery of Ξ_(cc)^(++)has inspired new interest in studying doubly heavy baryons.In this study,the weak decays of a doubly charmed baryon B_(cc)to a light baryon B and a charm meson D^(*)(either a pseudoscalar or a vector one)are calculated.Following our previous work,we calculate the short distance contributions under the factorization hypothesis,whereas the long distance contributions are modeled as the final state interactions,which are calculated with the one particle exchange model.We find that the B_(cc)→BD^(*)decays'branching ratios are obviously larger,as they receive contributions of more polarization states.Among the decays that we investigate,the following have the largest branching fractions:BR(Ξ_(cc)^(++)→∑^(+)D^(*+))∈[0.46%,3.33%]estimated with τΞ_(cc)^(++)=256 fs;BR(Ξ_(cc)^(+)→AD^(*+))∈[0.38%,2.63%]and BR(Ξ_(cc)^(+)→∑^(0)D^(*+))∈[0.45%,3.16%]with τΞ_(cc)^(++)=45 fs;and BR(Ω_(cc)^(+)→Ξ^(0)D^(+))∈[0.27%,1.03%),BR(Ω_(cc)^(+)→∑^(0)D^(*+))∈[0.07%,0.44%],and BR(Ω_(cc)^(+)→∑^(0)D^(*+))∈[0.06%,0.45%] with τ_(Ω_(cc))^(+)=75 fs.By comparing the decay widths of pure color commensurate channels with those of pure bow-tie ones we find that the bow-tie mechanism plays an important role in charm decays.
