Al/Hf ratio-dependent mechanisms of microstructure and mechanical property of nearly fully dense Al—Hf reactive material

This study proposed three types of Al—Hf reactive materials with particle size ratios(a),which were almost completely dense(porosity of<5.40%)owing to their preparation using hot-pressing technology.Microstructure characteristics and phase composition were analyzed,and the influence of particle size ratios on dynamic mechanical behavior and damage mechanism were investigated.The prepared sample with a=0.1 exhibited continuous wrapping of the Hf phase by the Al phase.Hf—Hf contact(continuous Hf phase)within the sample gradually increased with increasing a,and a small amount of fine Hf appeared for the sample with a=1.The reactive materials exhibited clear strain-rate sensitivity,with flow stressσ0.05and failure strainεfincreasing approximately linearly with increasing strain rate.ε.It is found that the plastic deformation of the material increased with increasing strain rate.As a increased from 0.1 to 1,the flow stress gradually increased.Impact failure of the material was dominated by ductile fracture with a large Al phase plastic deformation band for lower a,while brittle fracture with crushed Hf particles occurred at higher a.Finally,a constitutive model based on BP neural network was proposed to describe the stress-strain relationships of the materials,with an average relative error of 2.22%.

Study on Spatial Variation of Soil Moisture in Coal Mining Subsidence Area in Mu Us Sandy Land

In order to explore the spatial distribution and variation characteristics of soil moisture in coal mining subsidence area in Mu Us sandy Land,and provide theoretical basis for the restoration of the mining area,experiments based on a linear sampling and classic statistical and geostatistical methods were conducted. Spatial distribution characteristics and variation of soil moisture in the typical 0 to 100 cm dune area in the subsidence area and the non-subsidence area( control) were studied. The results showed that in the typical sand dune location of nonsubsidence area( control),the probability distribution curves of soil moisture changes in all layers along vertical and horizontal directions were all normal distribution,and it was consistent with the temporal and spatial variation characteristics of soil moisture in conventional dunes in Mu Us sandy land. By contrast,two years after the coal mine collapsed,the variations of soil moisture in different layers along vertical and horizontal directions were different,and soil moisture loss was more serious than that of control dune by nearly 10% to 30%,and the standard deviation varied from 0. 54 to 1. 05,increasing by 52. 08% compared with the non-subsidence area( control). The probability of positive and negative deviation greater than 1 was over 50%,and the coefficient of variation varied from 0. 14 to 0. 28,which was 80% higher than that of nonsubsidence area( control). After collapsing,the average level of soil moisture,standard deviation,variance and variation coefficient had greatly changed,and influence of coal mining subsidence on soil moisture was the most in the middle layer( 30-70 cm),and was not obvious in the surface( 0-20 cm) and lower layer( 80-100 cm). In coal mining subsidence area,the dispersion degree of soil moisture in different layers along the vertical and horizontal direction was greatly improved,which increased spatial variation of soil moisture.

克雷伯氏菌属(Klebsiella)细菌比较基因组学分析揭示多复制子抗性质粒介导广泛的抗性基因传播

【目的】研究克雷伯氏菌与多复制子抗性质粒间的关系,分析细菌携带多复制子质粒对抗生素环境的响应机制。【方法】以2018-2020年分离的56株不同来源克雷伯氏菌(Klebsiella sp.)分离株为研究对象,利用微量肉汤稀释法评估其多重耐药表型,对分离菌株进行全基因组测序(WGS),通过细菌全基因组关联分析(BGWAS)技术和比较基因组学方法深入解析多复制子抗性质粒形成的机制。【结果】耐药表型分析发现野生动物来源的菌株具有更广的耐药谱系,总体Klebsiella sp.对氨苄西林表现出很高的耐药率(80.36%),尤其是马来穿山甲来源菌株对头孢类抗生素高度耐受,同时对氯霉素、左氧氟沙星和复方新诺明等药物耐受,基因组分析发现这些菌株携带了抗性质粒和更多的抗生素抗性基因。进一步对69个质粒序列分析,发现有28个质粒为多复制子质粒,主要携带bla_(CTX-M-15)、bla_(CTX-M-14)、bla_(CTX-M-55)、bla_(OXA-1)和bla_(TEM-1)等β-内酰胺酶基因。细菌携带质粒类型分析认为Klebsiella pneumoniae可能是多复制子质粒的重要宿主,质粒骨架与结构分析发现多复制子质粒多由2个或2个以上单个质粒融合而成,携带此类质粒的菌株不仅获得了更广的耐药表型,而且在全球传播扩散分布逐年增加,因此产生对抗生素环境更强的适应性。【结论】多重耐药性细菌呈现的表型与携带的多复制子质粒有关,相比较下多复制子质粒比非多复制子质粒有更强的抗性基因携带能力,或许是细菌在强大的抗生素压力下产生的重要响应机制。本研究对于未来探索细菌抗性基因的传播扩散机制具有重要意义。

Ferroelastic domain identification and toughening mechanism for yttrium tantalate–zirconium oxide

Yttrium tantalate(YTaO_(4))is the next generation of higher service temperature thermal barrier coatings(TBCs)materials due to its smaller volume effect in phase change,lower thermal conductivity and unique ferroelastic domain structure.However,the low fracture toughness limits its application.We first characterized the diffraction patterns of variants,and two variants(M_(1)and M_(2))observed in transmission electron microscopy(TEM)results were determined from four possible variants by mechanical derivation.The role of Zr^(4+)doping in ferroelastic toughening was explained in detail.With the increase of Zr^(4+)doping concentration,the monoclinic angle β and the domain rotation angleαdecrease,respectively.The spontaneous strain component and the principal strain in the main space also have a similar decreasing trend.The decrease of the ferroelastic domain inversion energy barrier is beneficial to the improvement of fracture toughness.Combining the results of Vickers indentation,we found that Zr^(4+)could be enriched at the domain boundary to inhibit the generation of cracks.An appropriate amount of Zr^(4+)is conducive to the improvement of fracture toughness,and the excessive Zr^(4+)will reduce the fracture toughness due to the generation of by-product t-ZrO_(2).So,the optimal composition is Y_(0.44)Ta_(0.44)Zr_(0.12)O_(2) and the best fracture toughness(2.9–3.8MPa m^(1/2))is equivalent to the commercial 8YSZ.This result will promote the application of a new generation of TBCs.