Graphene oxide(GO) channels exhibit unique mass transport behaviors due to their flexibility, controllable thinness and extraordinary physicochemical properties, enabling them to be widely used for adsorption and memb...Graphene oxide(GO) channels exhibit unique mass transport behaviors due to their flexibility, controllable thinness and extraordinary physicochemical properties, enabling them to be widely used for adsorption and membrane separation. Nevertheless, the adsorption behavior of nanosized contaminants within the channels of GO membrane has not been fully discussed. In this study, we fabricated a GO membrane(PGn, where n represents the deposition cycles of GO) with multi channels via the crosslinking of GO and multibranched poly(ethyleneimine)(PEI). Phenol was used as molecular probe to determine the correlations between dynamic adsorption behavior and structural parameters of the multilevel GO/PEI membrane. PG8 shows higher adsorption capacities and affinity, which is predominantly attributed to the multichannel structure providing a large specific surface for phenol adsorption, enhancing the accessibility of active sites for phenol molecules and the transport of phenol. Density functional theory calculations demonstrate that the adsorption mechanism of phenol within GO channel is energetically oriented by hydrogen bonds, which is dominated by oxygen-containing groups compared to amino groups. Particularly, the interfaces which facilitate strong π-π interaction and hydrogen bonds maybe the most active regions. Moreover, the as-prepared PG8 membrane showed outstanding performance for other contaminants such as methyl orange and Cr(VI). It is anticipated that this study will have implications for design of GO-related environmental materials with enhanced efficiency.展开更多
Dipentaerythritol(DPER),4,40-diphenylmethanediisocyanate(MDI)and melamine(MEL)are used as raw materials to microencapsulate ammonium polyphosphate(MAPP)in situ polymerization.The MAPP is characterized by Fourier trans...Dipentaerythritol(DPER),4,40-diphenylmethanediisocyanate(MDI)and melamine(MEL)are used as raw materials to microencapsulate ammonium polyphosphate(MAPP)in situ polymerization.The MAPP is characterized by Fourier transform infrared(FT-IR),scanning electron microscopy(SEM),transmission electron microscopy(TEM)and thermal gravimetric analysis(TGA).The results show that the coating operation can effectively improve water resistance of ammonium polyphosphate(APP),and MAPP has higher residual rate than that of APP after combustion.The flame retardant action of MAPP and APP in polypropylene(PP)is investigated by the limited oxygen index(LOI),vertical burning test(UL-94),TGA,SEM,and cone calorimeter test(CCT).The LOI value of the PP/MAPP composite at the same loading is higher than that of PP/APP composite.UL 94 ratings of PP/MAPP composites are raised to V-0 at 20 wt%loading.The results of CCT also show that MAPP is more efficient than APP.The morphological structures observed by digital photos and SEM demonstrated that MAPP could be promoted to form the continuous and compact intumescent char layer.The flame retardant mechanism of PP/MAPP is also discussed.展开更多
Multicolor emissive carbon dots(M-CDs)have tremendous potential applications in manifold fields of bioimaging,biomedicine and light-emitting devices.Until now,it is still difficult to produce fluorescence tunable CDs ...Multicolor emissive carbon dots(M-CDs)have tremendous potential applications in manifold fields of bioimaging,biomedicine and light-emitting devices.Until now,it is still difficult to produce fluorescence tunable CDs with high quantum yield across the entire visible spectra.In this work,a type of M-CDs with concentration-tunable fluorescence and solvent-affected aggregation states was synthesized by solvothermal treatment of citric acid(CA)and 1-(2-pyridylazo)-2-naphthol(PAN)and the formation mechanism was monitored by different reaction time and raw material ratio.The fluorescence spectra of M-CDs in organic solvents can range from 350 to 750 nm by adjusting the concentration.M-CDs possess different aggregation states in water and organic solvents,accompanied by different fluorescence emission,which is attributed to the different surface states of various component CDs in M-CDs.Moreover,the obtained products can be uniformly dispersed into polymethylmethacrylate(PMMA)solutions as well as epoxy resins to fabricate transparent CDs/PMMA films and CDs/epoxy composites,which can effectively prevent the aggregation and produce multicolor and white light-emitting diodes(WLED).In addition,the prepared WLED with Commission Internationale de L’Eclairage(CIE)of(0.29,0.31)by using M-CDs/epoxy resin as packages,demonstrating the M-CDs exhibit potential applications for light-emitting devices.展开更多
In this study, biologically inspired silk fibroin grafted polyacrylonitrile(SF-g-PAN) filtration membrane was prepared using ZnCl_2 aqueous solution as solvent, avoiding the use of organic solvents. Phase inversion oc...In this study, biologically inspired silk fibroin grafted polyacrylonitrile(SF-g-PAN) filtration membrane was prepared using ZnCl_2 aqueous solution as solvent, avoiding the use of organic solvents. Phase inversion occurred when Zn^(2+)and Cl-ions gradually diffused into water, creating a well-connected ion channel network and the SF-g-PAN filtration membrane was obtained. The membranes were observed by SEM and 3D ultra-depth microscope. The hydrophilic property, pore size distribution and dye rejection of the membrane were investigated. Results showed that the membrane has no finger hole formation because ZnCl_2 aqueous solution has a lower curing rate parameter compared with organic solvents. SF-gPAN membrane possessed good anti-fouling properties and pH sensitivity. The pore size distribution of the SF-g-PAN membrane was 0.25–1.04 nm. The rejection of direct yellow 27(Mw = 662.6) and amaranth(Mw = 604.5) was 96.51% and 30.63%, with the flux of 72.32 L m^(-2) h^(-1) and 73.83 L m^(-2) h^(-1) respectively at0.1 MPa. The SF-g-PAN membrane has a wide range of applications prospect in fine separation, dye desalination, waste water treatment and biomedical fields.展开更多
基金supported by the National Natural Science Foundation of China(22078269 and 51708406).
文摘Graphene oxide(GO) channels exhibit unique mass transport behaviors due to their flexibility, controllable thinness and extraordinary physicochemical properties, enabling them to be widely used for adsorption and membrane separation. Nevertheless, the adsorption behavior of nanosized contaminants within the channels of GO membrane has not been fully discussed. In this study, we fabricated a GO membrane(PGn, where n represents the deposition cycles of GO) with multi channels via the crosslinking of GO and multibranched poly(ethyleneimine)(PEI). Phenol was used as molecular probe to determine the correlations between dynamic adsorption behavior and structural parameters of the multilevel GO/PEI membrane. PG8 shows higher adsorption capacities and affinity, which is predominantly attributed to the multichannel structure providing a large specific surface for phenol adsorption, enhancing the accessibility of active sites for phenol molecules and the transport of phenol. Density functional theory calculations demonstrate that the adsorption mechanism of phenol within GO channel is energetically oriented by hydrogen bonds, which is dominated by oxygen-containing groups compared to amino groups. Particularly, the interfaces which facilitate strong π-π interaction and hydrogen bonds maybe the most active regions. Moreover, the as-prepared PG8 membrane showed outstanding performance for other contaminants such as methyl orange and Cr(VI). It is anticipated that this study will have implications for design of GO-related environmental materials with enhanced efficiency.
基金Supported by the Natural Science Foundation of Hebei Province(B2016209059)
文摘Dipentaerythritol(DPER),4,40-diphenylmethanediisocyanate(MDI)and melamine(MEL)are used as raw materials to microencapsulate ammonium polyphosphate(MAPP)in situ polymerization.The MAPP is characterized by Fourier transform infrared(FT-IR),scanning electron microscopy(SEM),transmission electron microscopy(TEM)and thermal gravimetric analysis(TGA).The results show that the coating operation can effectively improve water resistance of ammonium polyphosphate(APP),and MAPP has higher residual rate than that of APP after combustion.The flame retardant action of MAPP and APP in polypropylene(PP)is investigated by the limited oxygen index(LOI),vertical burning test(UL-94),TGA,SEM,and cone calorimeter test(CCT).The LOI value of the PP/MAPP composite at the same loading is higher than that of PP/APP composite.UL 94 ratings of PP/MAPP composites are raised to V-0 at 20 wt%loading.The results of CCT also show that MAPP is more efficient than APP.The morphological structures observed by digital photos and SEM demonstrated that MAPP could be promoted to form the continuous and compact intumescent char layer.The flame retardant mechanism of PP/MAPP is also discussed.
基金supported by the National Natural Science Foundation of China(Nos.51678409,51638011 and 51578375)Tianjin Research Program of Application Foundation and Advanced Technology(Nos.18JCYBJC87500 and 15ZCZDSF00880)+1 种基金State Key Laboratory of Separation Membranes and Membrane Processes(No.Z1-201507)the Program for Innovative Research Team in University of Tianjin(No.TD13-5042).
文摘Multicolor emissive carbon dots(M-CDs)have tremendous potential applications in manifold fields of bioimaging,biomedicine and light-emitting devices.Until now,it is still difficult to produce fluorescence tunable CDs with high quantum yield across the entire visible spectra.In this work,a type of M-CDs with concentration-tunable fluorescence and solvent-affected aggregation states was synthesized by solvothermal treatment of citric acid(CA)and 1-(2-pyridylazo)-2-naphthol(PAN)and the formation mechanism was monitored by different reaction time and raw material ratio.The fluorescence spectra of M-CDs in organic solvents can range from 350 to 750 nm by adjusting the concentration.M-CDs possess different aggregation states in water and organic solvents,accompanied by different fluorescence emission,which is attributed to the different surface states of various component CDs in M-CDs.Moreover,the obtained products can be uniformly dispersed into polymethylmethacrylate(PMMA)solutions as well as epoxy resins to fabricate transparent CDs/PMMA films and CDs/epoxy composites,which can effectively prevent the aggregation and produce multicolor and white light-emitting diodes(WLED).In addition,the prepared WLED with Commission Internationale de L’Eclairage(CIE)of(0.29,0.31)by using M-CDs/epoxy resin as packages,demonstrating the M-CDs exhibit potential applications for light-emitting devices.
基金supported by the National Natural Science Foundation of China (Nos. 51678409, 145 708407, 21476172)Tianjin Science Technology Research Funds of China (Nos. 16JCZDJC37500, 15JCZDJC38300)+1 种基金Program for Innovative Research Team in University of Tianjin (No. TD13-5042)Science Foundation for the Youth Teachers of Peking Union Medical College (No. 2014ZLGC0754)
文摘In this study, biologically inspired silk fibroin grafted polyacrylonitrile(SF-g-PAN) filtration membrane was prepared using ZnCl_2 aqueous solution as solvent, avoiding the use of organic solvents. Phase inversion occurred when Zn^(2+)and Cl-ions gradually diffused into water, creating a well-connected ion channel network and the SF-g-PAN filtration membrane was obtained. The membranes were observed by SEM and 3D ultra-depth microscope. The hydrophilic property, pore size distribution and dye rejection of the membrane were investigated. Results showed that the membrane has no finger hole formation because ZnCl_2 aqueous solution has a lower curing rate parameter compared with organic solvents. SF-gPAN membrane possessed good anti-fouling properties and pH sensitivity. The pore size distribution of the SF-g-PAN membrane was 0.25–1.04 nm. The rejection of direct yellow 27(Mw = 662.6) and amaranth(Mw = 604.5) was 96.51% and 30.63%, with the flux of 72.32 L m^(-2) h^(-1) and 73.83 L m^(-2) h^(-1) respectively at0.1 MPa. The SF-g-PAN membrane has a wide range of applications prospect in fine separation, dye desalination, waste water treatment and biomedical fields.