Strongly Coupled Ag/Sn-SnO_(2)Nanosheets Toward CO_(2)Electroreduction to Pure HCOOH Solutions at Ampere‑Level Current

Electrocatalytic reduction of CO_(2) converts intermittent renewable electricity into value-added liquid products with an enticing prospect,but its practical application is hampered due to the lack of high-performance electrocatalysts.Herein,we elaborately design and develop strongly coupled nanosheets composed of Ag nanoparticles and Sn-SnO_(2) grains,designated as Ag/Sn-SnO_(2) nanosheets(NSs),which possess optimized electronic structure,high electrical conductivity,and more accessible sites.As a result,such a catalyst exhibits unprecedented catalytic performance toward CO_(2)-to-formate conversion with near-unity faradaic efficiency(≥90%),ultrahigh partial current density(2,000 mA cm^(−2)),and superior long-term stability(200 mA cm^(−2),200 h),surpassing the reported catalysts of CO_(2) electroreduction to formate.Additionally,in situ attenuated total reflection-infrared spectra combined with theoretical calculations revealed that electron-enriched Sn sites on Ag/Sn-SnO_(2)NSs not only promote the formation of*OCHO and alleviate the energy barriers of*OCHO to*HCOOH,but also impede the desorption of H*.Notably,the Ag/Sn-SnO_(2)NSs as the cathode in a membrane electrode assembly with porous solid electrolyte layer reactor can continuously produce~0.12 M pure HCOOH solution at 100 mA cm^(−2)over 200 h.This work may inspire further development of advanced electrocatalysts and innovative device systems for promoting practical application of producing liquid fuels from CO_(2).

352-Gbit/s single line rate THz wired transmission based on PS-4096QAM employing hollow-core fiber

We successfully demonstrate 32-Gbaud Probabilistically Shaped 4096-ary Quadrature Amplitude Modulation(PS-4096QAM)TeraHertz(THz)signal wired transmission at 325 GHz over the 1-m Hollow-Core Fiber(HCF)in a photon-assisted THz-wave communication system.By employing advanced Digital Signal Processing(DSP)and the PS technique,the 352-Gbit/s line rate(288-Gbit/s net rate)delivery with a net Spectral Efficiency(SE)of 9 bit/s/Hz is realized in the experiment,satisfying the 0.86-Normalized Generalized Mutual Information(NGMI)Low-Density Parity-Check(LDPC)threshold.

Cognitive Radio Spectrum Allocation Strategy Based on Improved Genetic Algorithm

With the rapid development of wireless communication industry, shortage situation of spectrum resource is increasingly significant. It has become an important topic to study cognitive radio spectrum allocation algorithm that is of higher spectrum utilization ratio, less system power consumption and better algorithm efficiency. Analyzes spectrum allocation models based on genetic algorithm, and then puts forward new improved genetic algorithm. The algorithm adopts niche crowding operation to avoid individual inbreeding. It adaptively adjusts crossover and mutation probability to keep them always in the appropriate state. It provides more equal individual competition opportunity by hierarchical measures, which can effectively avert premature convergence to local optimal solution. It obviously improves the district's total transfer rate on the premise that it has met the requirements of minimum user transfer rate and limitations of maximum total power and maximum bit error rate. Simulation results prove the effectiveness of the proposed algorithm.

Spectrum Sensing in Multi-user Cognitive Radio Networks

Spectrum sensing is studied for multi-user cognitive radio networks in this paper. An improved spectrum sensing method----energy-cooperative detection method is developed, which combines the double threshold energy detecting method with the “OR” fusion decision rule. The simulation is done for both AWGN channel and Rayleigh channel, and the advantages of the improved method are verified.

4.096 Tbit/s multidimensional multiplexing signals transmission over 1000 km few mode fiber

We experimentally transmit eight wavelength-division-multiplexing(WDM)channels,16 quadratic-amplitude-modulation(QAM)signals at 32-GBaud,over 1000 km few mode fiber(FMF).In this experiment,we use WDM,mode division multiplexing,and polarization multiplexing for signal transmission.Through the multiple-input-multiple-output(MIMO)equalization algorithms,we achieve the total line transmission rate of 4.096 Tbit/s.The results prove that the bit error rates(BERs)for the16QAM signals after 1000 km FMF transmission are below the soft-decision forward-error-correction(SD-FEC)threshold of2.4×10^(-2),and the net rate reaches 3.413 Tbit/s.Our proposed system provides a reference for the future development of high-capacity communication.

Mission segment division of the whole aeroengine loading spectrum based on flight actions

This paper studies on a division method of the whole aeroengine loading spectrum flight mission segment and rotor speed mission segment,which is based on the actual flight actions and related to the flight operations of aeroengine and is suitable for the variable-speed aeroengines such as turbojet and turbofan.Through the research,the aeroengine loading spectrum operation-related mission segments can be divided,which can provide important data basis for the life research on the structures which are sensitive to flight maneuver(such as the main shaft,large gearbox and installation section),lay a foundation for the simulation,compilation and prediction of the whole aeroengine loading spectrum.Firstly,based on the summary of basic flight actions in actual flight,the division of flight mission segment was realized by programming.Moreover,the aeroengine rotor speed mission segments,associated with flight actions and missions,were divided based on the flight mission segment division results.Besides,the efficiency and accuracy of the mission segment division results were verified by adopting measured loading spectrum data.Finally,the characteristics of speed mission segment division results were compared and analyzed in tables and figures.The comparison results show that the characteristics of similar speed mission segments are similar,while the characteristics of different speed mission segments are different.And the shapes of similar mission segments vary to the change of flight actions and operations,which can reflect the operation-related feature of the segments.

A new insight into the promoting effects of transition metal phosphides in methanol electrooxidation

The construction of highly active catalysts for methanol oxidation reaction(MOR)is central to direct methanol fuel cells.Tremendous progress has been made in transition metal phosphides(TMPs)based catalysts.However,TMPs would be partially damaged and transformed into new substances(e.g.,Pt-M-P composite,where M represents a second transition metal)during Pt deposition process.This would pose a large obstacle to the cognition of the real promoting effects of TMPs in MOR.Herein,Co_(2)P co-catalysts(Pt-P/Co_(2)P@NPC,where NPC stands for N and P co-doped carbon)and Pt-Co-P composite catalysts(Pt-CoP/NPC)were controllably synthesized.Electrocatalysis tests show that the Pt-Co-P/NPC exhibits superior MOR activity as high as 1016 m A/mg_(Pt),significantly exceeding that of Pt-P/Co_(2)P@NPC(345 m A/mg_(Pt)).This result indicates that the promoting effect is ascribed primarily to the resultant Pt-Co-P composite,in sharply contrast to previous viewpoint that Co_(2)P itself improves the activity.Further mechanistic studies reveal that Pt-Co-P/NPC exhibits much stronger electron interaction and thus manifesting a remarkably weaker CO absorption than Pt-P/Co_(2)P@NPC and Pt/C.Moreover,Pt-Co-P is also more capable of producing oxygen-containing adsorbate and thus accelerating the removal of surface-bonded CO^(*),ultimately boosting the MOR performance.

Recent progress on lanthanide complexes/clay minerals hybrid luminescent materials

The unique luminescent performance of lanthanide complexes/clay minerals hybrid materials has been fascinating many researchers for recent decades.It not only retains the excellent luminescent characteristics of lanthanide complexes but also improves the poor stability of the complexes.In this article,we introduce the luminescence mechanism of lanthanide complexes and point out the necessity of their combination with clay minerals.After the analysis of the structure and interlayer environment differences of 1:1-type and 2:1-type clay minerals,the intercalation methods(covalent grafting and ion exchange)appropriate for different clay minerals are summarized with examples.Based on the luminescence characteristics of the hybrid materials,the applications of these materials as luminescent probes in recognition of specific metal cations and molecules,detection of pH value,and temperature are reviewed.Finally,the current problems in the preparation of lanthanide complexes/clay minerals hybrid luminescent materials and shortcomings that need improvement in their performance are analyzed,and the application prospect is forecast.

Construction of rhombic triacontahedron discrete global grid systems

Discrete Global Grid System(DGGS)is a new multi-resolution geospatial data modeling and processing scheme for the digital earth.The icosahedron is commonly regarded as an ideal polyhedron for constructing DGGSs with small distortions;however,the shape of its face is triangular,making it difficult to incorporate the matrix structure used for geospatial data storage and parallel computing.To overcome this limitation,this study utilizes the rhombic triacontahedron(RT)as the basic polyhedron to construct DGGSs.An equal-area projection between the surface of RT and the sphere is developed and used to design a grid-generation algorithm for the aperture 4 hexagonal DGGS based on RT.Compared with the equal-area DGGS based on the icosahedron,the proposed scheme results in smaller angular projection distortions,with the mean and standard deviation decreasing by 41.6%and 30.9%,respectively.The grid cells of the RT DGGS also achieve more optimized geometric characteristics in shape compactness,length deviation,and angle deviation than those in the icosahedron DGGS.Additionally,the cross-surface computation efficiency provides advantages in code conversion to latitude and longitude and proximity queries.Furthermore,the use of RT offers a new and better framework within the context of DGGS research and application.