Photosynthetic organisms harness solar radiation to produce energy-rich compounds from water and atmospheric CO_(2)via exquisite supramolecular assemblies,which offers a design principle for highly efficient artificia...Photosynthetic organisms harness solar radiation to produce energy-rich compounds from water and atmospheric CO_(2)via exquisite supramolecular assemblies,which offers a design principle for highly efficient artificial photocatalytic systems.As an emerging research field,significant effort has been devoted to self-assembled supramolecular materials for photocatalytic H_(2)production and CO_(2)reduction.In this review,we introduce the basic concepts of supramolecular photocatalytic materials.After that,we will discuss recent advances in the preparation of supramolecular photocatalytic materials from zero-dimension to three-dimension which include molecular assemblies,micelles,hybrid nanoparticles,nanofibers,nanosheets,microcrystals,lipid bilayers,supramolecular organic frameworks,supramolecular metal-organic frameworks,gels,and host-guest metal-organic frameworks,etc.Furthermore,we show the recent progress in the photocatalytic properties of supramolecular photocatalytic materials,i.e.photocatalytic proton reduction,water splitting,CO_(2)to HCOOH,CO_(2)to CO,CO_(2)to CH4 conversions,etc.Finally,we provide our perspective for the future research,with a focus on the development of new structures and highly efficient photocatalysis.展开更多
Porous organic polymers(POPs)have become an emerging class of advanced porous organic materials owing to their structural diversity and tailored functions in solid state and organic media.Creating water-soluble and re...Porous organic polymers(POPs)have become an emerging class of advanced porous organic materials owing to their structural diversity and tailored functions in solid state and organic media.Creating water-soluble and related water-dispersible POPs is still very challenging in the research area of porous organic materials.Their porosity-based functions with diverse topological architectures in aqueous media offer promising platforms in bio-related fields.This review highlights recent progress on water soluble or dispersible POPs for biomedical applications including bioimaging and biosensing,nanocarriers for drug delivery and tumor targeting,phototherapeutics,protein and gene delivery,biomacromolecule encapsulation and discrimination,and anti-microbial activity.展开更多
基金We thank the National Natural Science Foundation of China(Nos:21921003,21890732 and 21890730)for financial support of this workJ T acknowledges the funding support from Shanghai Institute of Organic Chemistry and Shanghai Branch,CAS+1 种基金Shanghai Rising-Star Program(22QA1411200)the National Natural Science Foundation of China(No:22271306).
文摘Photosynthetic organisms harness solar radiation to produce energy-rich compounds from water and atmospheric CO_(2)via exquisite supramolecular assemblies,which offers a design principle for highly efficient artificial photocatalytic systems.As an emerging research field,significant effort has been devoted to self-assembled supramolecular materials for photocatalytic H_(2)production and CO_(2)reduction.In this review,we introduce the basic concepts of supramolecular photocatalytic materials.After that,we will discuss recent advances in the preparation of supramolecular photocatalytic materials from zero-dimension to three-dimension which include molecular assemblies,micelles,hybrid nanoparticles,nanofibers,nanosheets,microcrystals,lipid bilayers,supramolecular organic frameworks,supramolecular metal-organic frameworks,gels,and host-guest metal-organic frameworks,etc.Furthermore,we show the recent progress in the photocatalytic properties of supramolecular photocatalytic materials,i.e.photocatalytic proton reduction,water splitting,CO_(2)to HCOOH,CO_(2)to CO,CO_(2)to CH4 conversions,etc.Finally,we provide our perspective for the future research,with a focus on the development of new structures and highly efficient photocatalysis.
基金National Natural Science Foundation of China,Grant/Award Numbers:21890730,21890732,21921003。
文摘Porous organic polymers(POPs)have become an emerging class of advanced porous organic materials owing to their structural diversity and tailored functions in solid state and organic media.Creating water-soluble and related water-dispersible POPs is still very challenging in the research area of porous organic materials.Their porosity-based functions with diverse topological architectures in aqueous media offer promising platforms in bio-related fields.This review highlights recent progress on water soluble or dispersible POPs for biomedical applications including bioimaging and biosensing,nanocarriers for drug delivery and tumor targeting,phototherapeutics,protein and gene delivery,biomacromolecule encapsulation and discrimination,and anti-microbial activity.
