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环氧大豆油对聚苯乙烯-乙烯/丁烯-苯乙烯结构与性能的影响 被引量:2
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作者 张湘汉 朱君秋 +4 位作者 冀峰 郭江彬 梁红文 张爱民 罗水源 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2021年第6期94-98,108,共6页
系统研究了环保型增塑剂环氧大豆油(ESO)对聚苯乙烯-乙烯/丁烯-苯乙烯(SEBS)进行改性后的结构与性能。红外光谱结果表明,9 phr环氧大豆油添加到SEBS中,会在1750 cm^(-1)处出现新的特征吸收峰,但不会改变SEBS的链结构;小角X射线散射结果... 系统研究了环保型增塑剂环氧大豆油(ESO)对聚苯乙烯-乙烯/丁烯-苯乙烯(SEBS)进行改性后的结构与性能。红外光谱结果表明,9 phr环氧大豆油添加到SEBS中,会在1750 cm^(-1)处出现新的特征吸收峰,但不会改变SEBS的链结构;小角X射线散射结果表明,环氧大豆油与SEBS相互作用会影响聚集态结构,体现在SEBS相间距由56.07 nm增加到59.25 nm,微相尺寸分布增宽,导致SEBS改性后的黏度显著降低,体现在200℃时黏度由19186.8 Pa·s降低到8111.5 Pa·s;同时起始分解温度从389℃降低到354℃,玻璃化转变温度从-29.6℃降低到-34.4℃,SEBS热稳定性降低,分子链柔性增加,结晶度降低,拉伸强度从22.4 MPa降低到20.6 MPa。 展开更多
关键词 环氧大豆油 聚苯乙烯-乙烯/丁烯-苯乙烯 聚集态结构 流变性能 热性能 力学性能
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基于超临界二氧化碳釜压发泡技术制备生物可降解聚丁二酸对苯二甲酸丁二醇共聚酯发泡颗粒 被引量:1
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作者 冀峰 张艳 +4 位作者 龚炜华 于庆雨 朱君秋 郭江彬 罗水源 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2022年第4期66-72,共7页
文中首次使用超临界二氧化碳釜压发泡技术制备了生物可降解聚丁二酸对苯二甲酸丁二醇共聚酯(PBST)发泡颗粒。核磁共振分析结果表明,PBST中丁二酸的摩尔分数是55%;差示扫描量热分析结果表明,PBST的玻璃化转变温度和熔点分别是-16℃和118... 文中首次使用超临界二氧化碳釜压发泡技术制备了生物可降解聚丁二酸对苯二甲酸丁二醇共聚酯(PBST)发泡颗粒。核磁共振分析结果表明,PBST中丁二酸的摩尔分数是55%;差示扫描量热分析结果表明,PBST的玻璃化转变温度和熔点分别是-16℃和118℃;热重分析结果表明,PBST的分解温度是312℃。研究了渗透温度、渗透时间和渗透压力对PBST发泡颗粒密度和发泡倍率的影响。结果表明,当渗透温度从60℃上升到80℃,PBST发泡颗粒的密度逐渐降低、发泡倍率逐渐增大。PBST发泡颗粒放置1 d后,密度增加,发泡倍率降低。继续延长放置时间至7 d,密度和发泡倍率均保持不变;当渗透时间从1 h延长到2 h,PBST发泡颗粒的密度逐渐降低,发泡倍率逐渐增加。当渗透时间从2 h延长到3 h,PBST发泡颗粒的密度和发泡倍率保持不变;当渗透压力从10 MPa增加到12 MPa,PBST发泡颗粒的密度逐渐降低,发泡倍率逐渐增加;当渗透压力从12 MPa增加到14 MPa时,PBST发泡颗粒的密度和发泡倍率保持不变;PBST发泡颗粒的最佳渗透温度是70℃、渗透时间是2 h、渗透压力是12 MPa。扫描电镜结果显示,PBST发泡颗粒的平均泡孔在10μm左右。 展开更多
关键词 超临界二氧化碳 釜压发泡 生物可降解共聚酯 聚丁二酸对苯二甲酸丁二醇共聚酯 发泡颗粒
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Carbon dots enhanced gelatin/chitosan bio-nanocomposite packaging film for perishable foods 被引量:2
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作者 Bofei Fu Qiaoling Liu +7 位作者 Minghuan Liu Xiaofang Chen Hetong Lin Zongping Zheng junqiu zhu Congjie Dai Xiaochen Dong Da-Peng Yang 《Chinese Chemical Letters》 SCIE CAS CSCD 2022年第10期4577-4582,共6页
Carbon dots(CDs)with intriguing fluorescent property,good biocompatibility,high stability,easy interaction with substrates,are burgeoning carbon nanoparticles with large potential in various applications.Incorporating... Carbon dots(CDs)with intriguing fluorescent property,good biocompatibility,high stability,easy interaction with substrates,are burgeoning carbon nanoparticles with large potential in various applications.Incorporating CDs into the polymer matrix is becoming a popular strategy to endow the complex with new functions.Herein,the green-synthesized CDs was integrated into the mixture of gelatin(derived from waste fish scale)and chitosan,and a multifunctional bio-nanocomposite(defined as Gelatin/Chitosan/CDs)film was developed,which showed the excellent antibacterial,antioxidant,pH-sensitivity,UV shielding,and blue-emission properties.The effects of different concentrations of CDs on the physical,mechanical,structural,and functional activity of bio-nanocomposite film were tested.Compared with the Gelatin/Chitosan film,the Gelatin/Chitosan/CDs film with an optimum addition of 20%CDs showed the enhanced antibacterial,antioxidant as well as UV shielding activities.More importantly,it was used as an effective packaging material for fish meat preservation,reducing the loss of nutritional quality consumption,extending the shelf life of food.Besides,the bio-nanocomposite films also possessed the anti-counterfeiting and pH-responsive properties due to the strong fluorescent emission of CDs,and had the great potential in developing the intelligent packaging materials.Our work shed new light on the new application of CDs and the synthesis of bio-nanocomposite film in food industry. 展开更多
关键词 Carbon dots Bio-nanocomposite GELATIN UV shielding Intelligent packaging
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Recent advances in glinty appearance rendering
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作者 junqiu zhu Sizhe Zhao +3 位作者 Yanning Xu Xiangxu Meng Lu Wang Ling-Qi Yan 《Computational Visual Media》 SCIE EI CSCD 2022年第4期535-552,共18页
The interaction between light and materials is key to physically-based realistic rendering.However,it is also complex to analyze,especially when the materials contain a large number of details and thus exhibit"gl... The interaction between light and materials is key to physically-based realistic rendering.However,it is also complex to analyze,especially when the materials contain a large number of details and thus exhibit"glinty"visual effects.Recent methods of producing glinty appearance are expected to be important in next-generation computer graphics.We provide here a comprehensive survey on recent glinty appearance rendering.We start with a definition of glinty appearance based on microfacet theory,and then summarize research works in terms of representation and practical rendering.We have implemented typical methods using our unified platform and compare them in terms of visual effects,rendering speed,and memory consumption.Finally,we briefly discuss limitations and future research directions.We hope our analysis,implementations,and comparisons will provide insight for readers hoping to choose suitable methods for applications,or carry out research. 展开更多
关键词 glinty appearance Monte Carlo methods RENDERING
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