In this paper,the non-polluting,non-toxic,and eco-friendly material-MnO_(2)electrodes were deposited on three-dimensional porous nickel(Ni)foam by linear sweep voltammetry,and the entire electrodeposition process did ...In this paper,the non-polluting,non-toxic,and eco-friendly material-MnO_(2)electrodes were deposited on three-dimensional porous nickel(Ni)foam by linear sweep voltammetry,and the entire electrodeposition process did not require sintering of the material,which was fast and convenient while avoiding unnecessary energy consump-tion and thus was environmentally friendly.Scanning electron microscopy(SEM)and transmission electron microscopy were used to examine the surface and microscopic characteristics of each sample(TEM).Chronoam-perometry(CA),cyclic voltammetry(CV),galvanostatic charge/discharge(GCD),and electrochemical impedance spectroscopy(EIS)were then used to determine the electrochemical characteristics of the manufactured samples.The result suggests that the MnO_(2)-sv80 electrode sample at a scan rate of 80 mV/s^(−1)has excellent performance for the supercapacitor electrode.The specific capacitance was as high as 531.4 F g^(−1)at a current density of 1 A g^(−1)and remained at 223.2 F g^(−1)at an ultra-high current density of 20 A g^(−1),with capacitance retention of 42%.展开更多
基金sponsored by the National Natural Science Foundation of China(NSFC)Nos.11675029,51708015supported by Sichuan Science and Technology Program(2021JDRC0020,2022JDRC0080).
文摘In this paper,the non-polluting,non-toxic,and eco-friendly material-MnO_(2)electrodes were deposited on three-dimensional porous nickel(Ni)foam by linear sweep voltammetry,and the entire electrodeposition process did not require sintering of the material,which was fast and convenient while avoiding unnecessary energy consump-tion and thus was environmentally friendly.Scanning electron microscopy(SEM)and transmission electron microscopy were used to examine the surface and microscopic characteristics of each sample(TEM).Chronoam-perometry(CA),cyclic voltammetry(CV),galvanostatic charge/discharge(GCD),and electrochemical impedance spectroscopy(EIS)were then used to determine the electrochemical characteristics of the manufactured samples.The result suggests that the MnO_(2)-sv80 electrode sample at a scan rate of 80 mV/s^(−1)has excellent performance for the supercapacitor electrode.The specific capacitance was as high as 531.4 F g^(−1)at a current density of 1 A g^(−1)and remained at 223.2 F g^(−1)at an ultra-high current density of 20 A g^(−1),with capacitance retention of 42%.
