Preparation of Calcium Cross-linked Nano-Fe3O4 Modified Zeolite Microspheres for Cu^2+ Adsorption from Wastewater

Artificial zeolite was modified by nano-Fe3O4 for development of functional adsorbents.Subsequently,adsorbents such as calcium cross-linked nano-Fe3O4 microspheres (Ca-MS),calcium cross-linked nano-Fe3O4 modified zeolite microspheres (Ca-MZS) and iron cross-linked nano-Fe3O4 modified zeolite microspheres (Fe-MZS) were prepared and compared for their adsorption performance.The effects of adsorbent dosage,solution pH,initial concentration and ion content on the removal of Cu^2+ from wastewater are investigated,and the adsorption kinetics and isotherms for the adsorbent materials were analyzed.The experimental results indicate that for the initial concentration of Cu^2+ of 30 mg/L,the adsorption is noted to be most stable.The optimal initial pH for adsorbing Cu^2+ is observed to be 5.5.At an optimal dosage of Ca-MZS of 900 mg/L,the adsorption capacity is measured to be 28.25 mg/g,along with the removal rate of 72.49%.The addition of Na+ and K+ affects the adsorption of Cu^2+.For the Na^+ and K^+ concentration of 0.2 mmol/L,the Cu^2+ removal rate by Ca-MZS drops to 11.94% and 22.12%,respectively.As compared with the adsorbents such as Natural Zeolite (NZ),Ca-MS and Fe-MZS,Ca-MZS demonstrates the best removal effect in solution,where the removal rate reaches 84.27%,with the maximum adsorption capacity of 28.09 mg/g.The Cu^2+ adsorption kinetics of Ca-MZS is observed to follow the Elovich kinetic model,with the adsorption isotherm data fitting the Freundlich isotherm model by using the non-linear method.

冰形表面激光光带中心线快速提取方法

在风洞结冰模型3D冰形测量中,激光三角测量法相对传统测量方法检测速度快、精确度高,具有极高研究价值。然而由于冰体对激光透射严重,影响激光中心线提取精度从而影响测量精度。针对此问题,提出一种冰形表面激光光带中心线快速提取方法。该算法具体实现步骤为:首先,采用基于三维块匹配去噪算法对图像进行降噪,并对图像进行视觉显著性计算,分割出光带区域;其次,求取梯度图并转换至频域空间,根据图像频谱特征求取能量中心区域;最后,对区域采用灰度重心法求取中心线亚像素级位置。采用冰箱冻结的半径已知圆柱冰块评估该算法,测得算法处理时效为28.57FPS,使用该算法的冰形轮廓重建精度达到0.017mm。实验证明算法满足冰形在线测量技术要求,为开展结冰实验中结冰生长过程在线三维检测技术奠定技术基础。

纳米四氧化三铁沸石微球吸附废水中铅离子研究

采用纳米Fe_3O_4对人造沸石(NZ)进行改性,研究了吸附剂投加量、废水pH、不同交联剂、离子含量等对改性磁性沸石微球去除废水中Pb^(2+)性能的影响,分析了改性沸石的吸附动力学和吸附等温线。结果表明,在Pb^(2+)溶液pH=3,吸附剂投加量为0.6 g/L条件下,钙交联纳米Fe_3O_4改性沸石微球(Ca-MZS)对溶液中Pb^(2+)的去除率达93.4%,最大吸附量为77.1 mg/g,较NZ的最大吸附量8.02 mg/g有明显提高。Ca-MZS比铁交联纳米Fe_3O_4改性沸石微球(Fe-MZS)的最大吸附量高2.57 mg/g。Ca-MZS对Pb^(2+)的吸附过程符合准2级动力学模型和Freundlich模型。Pb^(2+)溶液分别加入Na^+、K^+时,Ca-MZS对Pb^(2+)去除率分别下降了9.3个、16.1个百分点。