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聚乙烯塑料/铬渣共热解还原Cr(Ⅵ)的实验研究 被引量:6
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作者 张大磊 李公伟 +2 位作者 李卫华 孔海南 孙英杰 《中国环境科学》 EI CAS CSSCI CSCD 北大核心 2017年第5期1852-1857,共6页
在分析聚乙烯热解特性的基础上,研究热解时间、热解温度及聚乙烯与铬渣质量比对Cr(VI)还原的影响,并运用XANES和EXAFS光谱研究铬元素的形态变化,并对反应机制进行分析.结果表明,(1)聚乙烯在热解过程中可以有效将Cr(VI)还原,还原率随着... 在分析聚乙烯热解特性的基础上,研究热解时间、热解温度及聚乙烯与铬渣质量比对Cr(VI)还原的影响,并运用XANES和EXAFS光谱研究铬元素的形态变化,并对反应机制进行分析.结果表明,(1)聚乙烯在热解过程中可以有效将Cr(VI)还原,还原率随着温度的升高而升高,当热解温度达到550℃,还原率为99.93%;随着PE投加量增大,Cr(VI)还原率逐渐上升,当质量比超过0.05时趋于稳定;Cr(VI)还原伴随塑料热解反应进行,6min后趋于稳定;最优反应条件为热解温度550℃、热解时间6min、PE/铬渣质量比0.05.(2)使用XAS铬形态分析过程中以Cr2O3作为Cr(Ⅲ)的参考物较CrCl_3更为合理,铬渣中Cr(VI)还原产物为无定型Cr_2O_3;(3)由于PE主要由C、H两种元素组成,不含O元素,相比生物质还原剂,可以更高效还原Cr(VI);(4)Cr(VI)与挥发份充分接触反应条件下,Cr(VI)可持续还原. 展开更多
关键词 聚乙烯 铬渣 X射线吸收光谱 热解
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A New Soil Infiltration Technology for Decentralized Sewage Treatment:Two-Stage Anaerobic Tank and Soil Trench System 被引量:14
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作者 YE Chun HU Zhan-Bo +2 位作者 kong hai-nan WANG Xin-Ze HE Sheng-Bing 《Pedosphere》 SCIE CAS CSCD 2008年第3期401-408,共8页
The low removal effciency of total nitrogen(TN) is one of the main disadvantages of traditional single stage subsurface infiltration system,which combines an anaerobic tank and a soil filter field.In this study,a full... The low removal effciency of total nitrogen(TN) is one of the main disadvantages of traditional single stage subsurface infiltration system,which combines an anaerobic tank and a soil filter field.In this study,a full-scale,two-stage anaerobic tank and soil trench system was designed and operated to evaluate the feasibility and performances in treating sewage from a school campus for over a one-year monitoring period.The raw sewage was prepared and fed into the first anaerobic tank and second tank by 60% and 40%,respectively.This novel process could decrease chemical oxygen demand with the dichromate method by 89%-96%,suspended solids by 91%-97%,and total phosphorus by 91%-97%.The denitrification was satisfactory in the second stage soil trench,so the removals of TN as well as ammonia nitrogen(NH+4-N) reached 68%-75% and 96%-99%,respectively.It appeared that the removal effciency of TN in this two-stage anaerobic tank and soil trench system was more effective than that in the single stage soil infiltration system.The effuent met the discharge standard for the sewage treatment plant(GB18918-2002) of China. 展开更多
关键词 分散处理 氮除去技术 土壤 地下水
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Zeolite powder addition to improve the performance of submerged gravitation-filtration membrane bioreactor 被引量:8
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作者 HE Sheng-bing XUE Gang kong hai-nan 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第2期242-247,共6页
In this study, the effect of zeolite powder addition on submerged membrane bioreactor (SMBR) on membrane permeability, and the removals for COD, NH3-N, TN were investigated. Through the parallel operation of control... In this study, the effect of zeolite powder addition on submerged membrane bioreactor (SMBR) on membrane permeability, and the removals for COD, NH3-N, TN were investigated. Through the parallel operation of control and test systems, it was found that the zeolite powder addition could alleviate the ultra-filtration membrane fouling and enhance the membrane permeability. On the basis of experimental investigations, a concept of "protection coating layer" was proposed to illustrate the phenomenon of UF membrane fouling. In addition, the removal for COD in test system was more stable, a little higher compared to the control system. Due to the combination of nitrification and ion exchange, a more excellent removal for NH3-N in test system was obtained regardless of influent NH3-N loading rate. It was also found that a mean 25% higher TN removal took place in the test system, and ion exchange and simultaneous nitrification and de-nitrification were analyzed to be main factors. During the stable operation period, the SOURs of test zeolite powder added sludge and control activated sludge were measured to be 75 mgO2/(gMLVSS, h) and 24 mgO2/(gMLVSS, h) respectively, it meant that the zeolite powder addition could enhance the microorganism activity significantly. 展开更多
关键词 submerged gravitation-filtration membrane bioreactor PERFORMANCE zeolite powder membrane fouling microorganism activity
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Removal of PCDD/Fs and PCBs from sediment by oxygen free Pyrolysis 被引量:6
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作者 HU Zhan-bo Saman Wijesekara R.G. +4 位作者 Ronald R. Navarro WU De-yi ZHANG Da-lei Masatoshi Matsumura kong hai-nan 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2006年第5期989-994,共6页
Few studies have dealt on the evaluation of volatilization and decomposition reactions of dioxins from sediment by oxygen free pyrolysis. In this study, the performance of pyrolysis on the removal of dioxins from sedi... Few studies have dealt on the evaluation of volatilization and decomposition reactions of dioxins from sediment by oxygen free pyrolysis. In this study, the performance of pyrolysis on the removal of dioxins from sediment was investigated. Dioxin concentrations of the raw sediment and the solid residues after pyrolysis were analyzed at different conditions. Results showed a removal efficiency of 99.9999% for total dioxins at 800℃ and retention time of 30 min. All the polychlorinated dibenzo-furans (PCDFs) have been removed and were not formed in the solid residues at the retention time range of 30-90 min at 800℃. Close to 100% removal of polychlorinated dibenzo-p-dioxins (PCDDs) was also achieved. Only trace PCDDs were detected in the solid yields at a retention time of 60 min. The highest removal efficiency of polychlorinated biphenyls (PCBs) was more than 99.9994% at a retention time of 30 min. During cooling period following pyrolysis, however, the concentration of total dioxins in solid residues increased 130 times as compared to that of the raw sediment under air atmosphere. This confirmed that some complex reactions do occur to form PCDD/Fs and PCBs from 800 to 400℃ in the presence of oxygen. Oxygen-free atmosphere therefore can prevent formation of dioxin during thermal process thus generating clean solid residues. 展开更多
关键词 DIOXINS PYROLYSIS oxygen free SEDIMENT PCBS
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Distribution characteristics of ammonia-oxidizing bacteria in the Typha latifolia constructed wetlands using fluorescent in situ hybridization(FISH) 被引量:1
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作者 YAN Li Ryuhei Inamori +4 位作者 GUI Ping XU Kai-qin kong hai-nan Masatoshi Matsurnura Yuhei Inamori 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2005年第6期993-997,共5页
A molecular biology method, fluorescent in situ hybridization(FISH), in which the pre-treatment was improved in allusion to the media of the constructed wetlands(CW), e.g. the soil and the grit, was used to invest... A molecular biology method, fluorescent in situ hybridization(FISH), in which the pre-treatment was improved in allusion to the media of the constructed wetlands(CW), e.g. the soil and the grit, was used to investigate the vertical distribution characteristics of ammonia-oxidizing bacteria(AOB) quantity and the relation with oxidation-reduction potential(ORP) in the Typha latifolia constructed wetlands under three different Ioadings in summer from May to September. Results showed that the quantity of the AOB decreased in the Typha latifolia CW with the increase of vertical depth. However, the AOB quantity was 2-4 times the quantity of the control in the root area. Additionally, ORP in the rhizosphere was found to be higher than other areas, which showed that Typha latifolia CW was in an aerobic state in summer when using simulated non-point sewage at the rural area of Taihu Lake in China and small town combined sewage. 展开更多
关键词 constructed wetland(CW) fluorescent in situ hybridization(FISH) ammonia-oxidizing bacteria (AOB) Typha/atifo/ia(cattail)
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居民饮用水安全研究进展 被引量:11
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作者 关玥 孔海南 +3 位作者 张树栋 李晓迪 刘华 林燕 《环境工程》 CAS CSCD 北大核心 2018年第4期18-22,共5页
饮用水安全对社会发展和居民健康都起着重要作用,如何保障居民饮用水安全成为目前面临的重大社会和环境问题之一。饮用水安全面临着从水源地输水到用户过程中的"三重污染"问题,即水源地污染、水处理工艺落后和管网污染。综述... 饮用水安全对社会发展和居民健康都起着重要作用,如何保障居民饮用水安全成为目前面临的重大社会和环境问题之一。饮用水安全面临着从水源地输水到用户过程中的"三重污染"问题,即水源地污染、水处理工艺落后和管网污染。综述国内饮用水安全存在的问题以及改善的现状等方面的内容,探讨和分析了为改善饮用水现状使用的一种饮用水供水方式即管道直饮水的应用情况,为饮用水的安全供应提供参考。 展开更多
关键词 水源地污染 处理工艺污染 管网污染 管道直饮水
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应用改良型水质综合指数法评价饮用水水质 被引量:7
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作者 周蓓 关玥 +2 位作者 赵亚芳 孔海南 林燕 《环境工程》 CAS CSCD 北大核心 2020年第8期244-248,共5页
应用1套改良型水质综合指数法对3种不同类型的饮用水水质进行评价。将选取的26项检测指标按照卫生学意义分为5大类,并对各分类指标赋权。选用内梅罗法和最差因子判别法与五色等级分级法结合对2017年4—8月的3种类型饮用水进行水质评价。... 应用1套改良型水质综合指数法对3种不同类型的饮用水水质进行评价。将选取的26项检测指标按照卫生学意义分为5大类,并对各分类指标赋权。选用内梅罗法和最差因子判别法与五色等级分级法结合对2017年4—8月的3种类型饮用水进行水质评价。除7月和8月的管网水水质为2级(水质综合指数>0.5,蓝色)以外,其余月份的出水水质均达到1级(绿色)评价标准。不同类型饮用水中对水质综合指数影响最大的水质分类指标均是有机污染指标。2种不同类型的净水机出水水质均优于管网末梢水,但需注意个别指标的污染。 展开更多
关键词 改良型水质综合指数 饮用水评价 五色等级分级法 管网末梢水
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