Half-Heusler(HH)合金由于其本身具有较为优异的力学性能和高温热稳定性,已成为目前最具有应用前景的中高温热电材料之一。然而,其本身较高的本征晶格热导率阻碍了热电性能的进一步提升。本文以P型Zr Co Sb0.85Sn0.15合金为研究对象,基...Half-Heusler(HH)合金由于其本身具有较为优异的力学性能和高温热稳定性,已成为目前最具有应用前景的中高温热电材料之一。然而,其本身较高的本征晶格热导率阻碍了热电性能的进一步提升。本文以P型Zr Co Sb0.85Sn0.15合金为研究对象,基于同构合金化具有优异P型热电性能的(Nb0.8Ta0.2)0.8Ti0.2Fe Sb,通过磁悬浮熔炼和放电等离子烧结设计并制备出一种(Zr Co Sb0.85Sn0.15)1-x[(Nb0.8Ta0.2)0.8Ti0.2Fe Sb]x(x=0,0.2,0.3,0.4,0.5)高熵HH合金。微观组织分析表明,同构合金化这一策略引入了大量多尺度多衬度的第二相,这将有效增强对声子的散射。其中,当同构合金化含量为0.3时,晶格热导率在923 K时从Zr Co Sb0.85Sn0.15的4.72 W·m-1·K-1降至3.07 W·m-1·K-1,降低了35%。然而,由于多位点合金化元素间存在较为复杂的掺杂效果,使其电导率和塞贝克系数同时降低,最终导致热电优值存在一定的降低。本研究工作表明,高熵合金设计思想是一种降低HH热电合金晶格热导率的有力措施。展开更多
The mold filling and solidification process of a marine propeller hub were simulated using ProCAST. Three casting processes–gravity casting, centrifugal casting and low pressure casting–were compared in order to get...The mold filling and solidification process of a marine propeller hub were simulated using ProCAST. Three casting processes–gravity casting, centrifugal casting and low pressure casting–were compared in order to get the best process. The heat transfer coefficient of the casting/mold interface was determined using a reverse method. The simulated results of velocity, temperature and shrinkage porosity distribution were discussed in detail for the three casting processes. A smooth filling was found in all three casting processes, especially the low pressure casting exhibiting a better filling performance than the other two, but the solidification processes were different. The casting did not experience the sequential solidification, and the feeding paths were blocked, leading to shrinkage porosity defects in the riser and the bottom of the casting in gravity casting and in the upper zone of the casting in low pressure casting. While, the sequential solidification was well controlled in the solidification process of centrifugal casting, and majority of the shrinkage porosity defects can only be observed in the riser. It could be concluded that the centrifugal casting process is the most suitable casting process for the production of propeller hub body. The casting experiments verified the simulation results, and a defect-free propeller hub was obtained by centrifugal casting with a rotational speed of 150 r·min-1.展开更多
In order to overcome the zigzag grids generated by conventional finite difference method on complicated casting boundaries in the simulation of casting process, the generation program for 2-D boundary-fitted coordinat...In order to overcome the zigzag grids generated by conventional finite difference method on complicated casting boundaries in the simulation of casting process, the generation program for 2-D boundary-fitted coordinate grid has been developed by solving a set of partial differential equations (PDE) numerically. The STL format files were treated as input data for 2-D physical regions. The equipartition method for boundary points was used to improve the self-adaptability of grid according to the characteristic of the STL format files. The program was demonstrated through some examples. The comparison between the conventional finite difference method and the proposed method shows that this program is effective and flexible for generation of boundary-fitted grid in any arbitrary 2-D complex domain, and the grid is in accordance with the variety of boundary curvature finely. The program also provides two types of boundary-fitted grids for double-connected region, O-type and C-type. The limitation of the step-like boundary with the rectangle grid could be avoided effectively. Therefore, the computational accuracy and efficiency would be improved and the computational time would be saved significantly by the application of boundary-fitted grids.展开更多
文摘Half-Heusler(HH)合金由于其本身具有较为优异的力学性能和高温热稳定性,已成为目前最具有应用前景的中高温热电材料之一。然而,其本身较高的本征晶格热导率阻碍了热电性能的进一步提升。本文以P型Zr Co Sb0.85Sn0.15合金为研究对象,基于同构合金化具有优异P型热电性能的(Nb0.8Ta0.2)0.8Ti0.2Fe Sb,通过磁悬浮熔炼和放电等离子烧结设计并制备出一种(Zr Co Sb0.85Sn0.15)1-x[(Nb0.8Ta0.2)0.8Ti0.2Fe Sb]x(x=0,0.2,0.3,0.4,0.5)高熵HH合金。微观组织分析表明,同构合金化这一策略引入了大量多尺度多衬度的第二相,这将有效增强对声子的散射。其中,当同构合金化含量为0.3时,晶格热导率在923 K时从Zr Co Sb0.85Sn0.15的4.72 W·m-1·K-1降至3.07 W·m-1·K-1,降低了35%。然而,由于多位点合金化元素间存在较为复杂的掺杂效果,使其电导率和塞贝克系数同时降低,最终导致热电优值存在一定的降低。本研究工作表明,高熵合金设计思想是一种降低HH热电合金晶格热导率的有力措施。
基金financially supported by the National Natural Science Foundation of China(Nos.51274054,U1332115,51271042,and 51375070)the Key Grant Project of Chinese Ministry of Education,China(No.313011)the Science and Technology Planning Project of Dalian(2013A16GX110)
文摘The mold filling and solidification process of a marine propeller hub were simulated using ProCAST. Three casting processes–gravity casting, centrifugal casting and low pressure casting–were compared in order to get the best process. The heat transfer coefficient of the casting/mold interface was determined using a reverse method. The simulated results of velocity, temperature and shrinkage porosity distribution were discussed in detail for the three casting processes. A smooth filling was found in all three casting processes, especially the low pressure casting exhibiting a better filling performance than the other two, but the solidification processes were different. The casting did not experience the sequential solidification, and the feeding paths were blocked, leading to shrinkage porosity defects in the riser and the bottom of the casting in gravity casting and in the upper zone of the casting in low pressure casting. While, the sequential solidification was well controlled in the solidification process of centrifugal casting, and majority of the shrinkage porosity defects can only be observed in the riser. It could be concluded that the centrifugal casting process is the most suitable casting process for the production of propeller hub body. The casting experiments verified the simulation results, and a defect-free propeller hub was obtained by centrifugal casting with a rotational speed of 150 r·min-1.
基金supported by State Key Laboratory of Materials Processing and Die&Mould Technology,Huazhong University of Science and Technology(09-04)National Natural Science Foundation of China(No.50775050)
文摘In order to overcome the zigzag grids generated by conventional finite difference method on complicated casting boundaries in the simulation of casting process, the generation program for 2-D boundary-fitted coordinate grid has been developed by solving a set of partial differential equations (PDE) numerically. The STL format files were treated as input data for 2-D physical regions. The equipartition method for boundary points was used to improve the self-adaptability of grid according to the characteristic of the STL format files. The program was demonstrated through some examples. The comparison between the conventional finite difference method and the proposed method shows that this program is effective and flexible for generation of boundary-fitted grid in any arbitrary 2-D complex domain, and the grid is in accordance with the variety of boundary curvature finely. The program also provides two types of boundary-fitted grids for double-connected region, O-type and C-type. The limitation of the step-like boundary with the rectangle grid could be avoided effectively. Therefore, the computational accuracy and efficiency would be improved and the computational time would be saved significantly by the application of boundary-fitted grids.
