The epoxy nanocomposites with similar amines （CH3（CH2）17NH2 and CH3（CH2）17N（CH3）301） treated montmorillonite clays have been investigated by wide-angle X-ray scattering, transmission electron microscopy （TEM...The epoxy nanocomposites with similar amines （CH3（CH2）17NH2 and CH3（CH2）17N（CH3）301） treated montmorillonite clays have been investigated by wide-angle X-ray scattering, transmission electron microscopy （TEM）, differential scanning calorimetry （DSC） and thermal gravimetric analysis （TGA）. Different nanocomposite structures, intercalation and exfoliation were formed by the reaction of octadecyltrimethylammonium chloride-exchanged and octadecylamine-exchanged clays with epoxy resin and phenalkamine as the curing agent, respectively. Results showed that the exfoliated nanocomposite can be obtained when octadecylamine with the lower polarity was used as a modifier. However, the intercalated nanocomposite can be obtained when octadecyltrimethylammonium chloride with higher polarity was used as a modifier.展开更多
基金support from the National Key Technology R&D Program(Grant No.2012BAB15B00)State Grid Practical Project-Investigation on the key technologies on developmentapplication of anticorrosive material of power transmission and transformation equipment(Grant No.521820130014)for supporting these studies
文摘The epoxy nanocomposites with similar amines （CH3（CH2）17NH2 and CH3（CH2）17N（CH3）301） treated montmorillonite clays have been investigated by wide-angle X-ray scattering, transmission electron microscopy （TEM）, differential scanning calorimetry （DSC） and thermal gravimetric analysis （TGA）. Different nanocomposite structures, intercalation and exfoliation were formed by the reaction of octadecyltrimethylammonium chloride-exchanged and octadecylamine-exchanged clays with epoxy resin and phenalkamine as the curing agent, respectively. Results showed that the exfoliated nanocomposite can be obtained when octadecylamine with the lower polarity was used as a modifier. However, the intercalated nanocomposite can be obtained when octadecyltrimethylammonium chloride with higher polarity was used as a modifier.
