We herein report our studies into the effects of microwave irradiation on the solvent-free esterification of L-leucine with alcohols. In the absence of solvent, microwave irradiation accelerated the reaction compared ...We herein report our studies into the effects of microwave irradiation on the solvent-free esterification of L-leucine with alcohols. In the absence of solvent, microwave irradiation accelerated the reaction compared to conventional oil bath heating. Measurement of the dielectric properties under the reaction conditions revealed that the high dielectric loss factor of the reaction mixture containing L-leucine, n-butanol, and a p-toluene sulfonic acid catalyst could be attributed to the acceleration of the reaction. The depth of microwave penetration into the reaction mixture as derived from the in-situ measurement of the dielectric properties was ~13 mm, which suggested that a thinner reaction vessel was favorable for the esterification of L-leucine. In addition to the batch reaction using a desktop microwave reactor, two types of flow reaction were also performed using a desktop tubular reactor and a semi-bench-scale tubular reactor. These flow reactions also exhibited high performances, thus allowing the scale-up of this reaction system for industrial use.展开更多
We studied human perceptions on the management of bamboo-tree gardens in two villages with contrasting agroecological conditions in the upper Citarum basin. We undertook interviews to reveal perceptions on the tenure,...We studied human perceptions on the management of bamboo-tree gardens in two villages with contrasting agroecological conditions in the upper Citarum basin. We undertook interviews to reveal perceptions on the tenure, function, and management strategies of multi-layered agroforest. Owners in a village located lower in the basin perceived the gardens more positively than those in an upland village, where market pressures were felt more keenly and for a longer period. There was not always a direct correlation between perceptions and behavior with respect to bamboo-tree garden management. However, we concluded that an understanding of human perceptions could provide valuable insight to the process of formulating strategies that might be effective in minimizing the conversion of bamboo-tree gardens to more intensive and less ecologically diverse agricultural systems. Specifically, since the villagers retained a strong cultural perception of the heritage value of the bamboo-tree gardens, they would likely be responsive to conservation efforts that increased the economic value of the gardens and reduced the opportunity cost of not converting them to production that is more intensive or other land uses.展开更多
文摘We herein report our studies into the effects of microwave irradiation on the solvent-free esterification of L-leucine with alcohols. In the absence of solvent, microwave irradiation accelerated the reaction compared to conventional oil bath heating. Measurement of the dielectric properties under the reaction conditions revealed that the high dielectric loss factor of the reaction mixture containing L-leucine, n-butanol, and a p-toluene sulfonic acid catalyst could be attributed to the acceleration of the reaction. The depth of microwave penetration into the reaction mixture as derived from the in-situ measurement of the dielectric properties was ~13 mm, which suggested that a thinner reaction vessel was favorable for the esterification of L-leucine. In addition to the batch reaction using a desktop microwave reactor, two types of flow reaction were also performed using a desktop tubular reactor and a semi-bench-scale tubular reactor. These flow reactions also exhibited high performances, thus allowing the scale-up of this reaction system for industrial use.
文摘We studied human perceptions on the management of bamboo-tree gardens in two villages with contrasting agroecological conditions in the upper Citarum basin. We undertook interviews to reveal perceptions on the tenure, function, and management strategies of multi-layered agroforest. Owners in a village located lower in the basin perceived the gardens more positively than those in an upland village, where market pressures were felt more keenly and for a longer period. There was not always a direct correlation between perceptions and behavior with respect to bamboo-tree garden management. However, we concluded that an understanding of human perceptions could provide valuable insight to the process of formulating strategies that might be effective in minimizing the conversion of bamboo-tree gardens to more intensive and less ecologically diverse agricultural systems. Specifically, since the villagers retained a strong cultural perception of the heritage value of the bamboo-tree gardens, they would likely be responsive to conservation efforts that increased the economic value of the gardens and reduced the opportunity cost of not converting them to production that is more intensive or other land uses.
