Impact of effective stress on permeability for carbonate fractured-vuggy rocks

To gain insight into the flow mechanisms and stress sensitivity for fractured-vuggy reservoirs,several core models with different structural characteristics were designed and fabricated to investigate the impact of effective stress on permeability for carbonate fractured-vuggy rocks(CFVR).It shows that the permeability performance curves under different pore and confining pressures(i.e.altered stress conditions)for the fractured core models and the vuggy core models have similar change patterns.The ranges of permeability variation are significantly wider at high pore pressures,indicating that permeability reduction is the most significant during the early stage of development for fractured-vuggy reservoirs.Since each obtained effective stress coefficient for permeability(ESCP)varies with the changes in confining pressure and pore pressure,the effective stresses for permeability of four representative CFVR show obvious nonlinear characteristics,and the variation ranges of ESCP are all between 0 and 1.Meanwhile,a comprehensive ESCP mathematical model considering triple media,including matrix pores,fractures,and dissolved vugs,was proposed.It is proved theoretically that the ESCP of CFVR generally varies between 0 and 1.Additionally,the regression results showed that the power model ranked highest among the four empirical models mainly applied in stress sensitivity characterization,followed by the logarithmic model,exponential model,and binomial model.The concept of“permeability decline rate”was introduced to better evaluate the stress sensitivity performance for CFVR,in which the one-fracture rock is the strongest,followed by the fracture-vug rock and two-horizontalfracture rock;the through-hole rock is the weakest.In general,this study provides a theoretical basis to guide the design of development and adjustment programs for carbonate fractured-vuggy reservoirs.

Experimental Study on Gas Flow Uniformity in a Diesel Particulate Filter Carrier

A Diesel Particulate Filter(DPF)is a critical device for diesel engine exhaust products treatment.When using active-regeneration purification methods,on the one hand,a spatially irregular gas flow can produce relatively high local temperatures,potentially resulting in damage to the carrier;On the other hand,the internal temperature field can also undergo significant changes contributing to increase this risk.This study explores the gas flow uniformity in a DPF carrier and the related temperature behavior under drop-to-idle(DTI)condition by means of bench tests.It is shown that the considered silicon carbide carrier exhibits good flow uniformity,with a temperature deviation of no more than 2%with respect to the same radius measurement point at the outlet during the regeneration stage.In the DTI test,the temperature is relatively high within r/2 near the outlet end,where the maximum temperature peak occurs,and the maximum radial temperature gradient is located between r/2 and the edge.Both these quantities grow as the soot load increases,thereby making the risk of carrier burnout greater.Finally,it is shown that the soot load limit of the silicon carbide DPF can be extended to 11 g/L,which reduces the frequency of active regeneration by approximately 40%compared to a cordierite DPF.

Ecological Networks of Allometric Growth,Feeding Behavior and Gut Microbiota in Chinese Alligator Hatchlings

Chinese alligator hatchlings in captivity are fragile and have a high mortality rate within first year.The body mass gain of reptile animals is closely related to their feeding behavior and gut microbiota.This study analyzed the intrinsic factors influencing the allometric growth of Chinese alligator hatchlings based on their body mass gain,feeding behavior,and gut microbiota.This information would enhance the health management of Chinese alligator hatchlings.There was a significant correlation between the total distance moved,the average number of conspecifics nearby,and body mass gain.Chinese alligator hatchlings with a greater growth rate showed greater activity and more independent behavior during feeding than those with a lower growth rate.Moreover,after feeding started,some functions of the gut microbiota showed significant relationships with growth rate and feeding activity.Chinese alligator hatchlings with a greater growth rate showed greater levels of heme biosynthesis than those with a lower growth rate,and feeding activity was inhibited by long-chain fatty acid biosynthesis.These results elucidate the relationships between health,feeding behavior,and the gut microbiota of Chinese alligator hatchlings.Understanding the intrinsic factors of their health and feeding behavior can improve the health management of Chinese alligator hatchlings in captivity for conservation.

WT-FCTGN:A wavelet-enhanced fully connected time-gated neural network for complex noisy traffic flow modeling

Accurate forecasting of traffic flow provides a powerful traffic decision-making basis for an intelligent transportation system. However, the traffic data's complexity and fluctuation, as well as the noise produced during collecting information and summarizing original data of traffic flow, cause large errors in the traffic flow forecasting results. This article suggests a solution to the above mentioned issues and proposes a fully connected time-gated neural network based on wavelet reconstruction(WT-FCTGN). To eliminate the potential noise and strengthen the potential traffic trend in the data, we adopt the methods of wavelet reconstruction and periodic data introduction to preprocess the data. The model introduces fully connected time-series blocks to model all the information including time sequence information and fluctuation information in the flow of traffic, and establishes the time gate block to comprehend the periodic characteristics of the flow of traffic and predict its flow. The performance of the WT-FCTGN model is validated on the public Pe MS data set. The experimental results show that the WT-FCTGN model has higher accuracy, and its mean absolute error(MAE), mean absolute percentage error(MAPE) and root mean square error(RMSE) are obviously lower than those of the other algorithms. The robust experimental results prove that the WT-FCTGN model has good anti-noise ability.

Analysis of the Influence of Geometrical Parameters on the Performance of a Proton Exchange Membrane Fuel Cell

A suitable channel structure can lead to efficient gas distribution and significantly improve the power density of fuel cells.In this study,the influence of two channel design parameters is investigated,namely,the ratio of the channel width to the bipolar plate ridge width(i.e.,the channel ridge ratio)and the channel depth.The impact of these parameters is evaluated with respect to the flow pattern,the gas composition distribution,the temperature field and the fuel cell output capability.The results show that a decrease in the channel ridge ratio and an increase in the channel depth can effectively make the distributions of velocity,temperature and concentration more uniform in each channel and improve the output capability of the fuel cell.An increase in the channel ridge ratio and depth obviously reduces the flow resistance and improves the flow characteristics.

An organic visible-photocatalytic-adsorbence mechanism to high-efficient removal of heavy metal antimony ions

Purification of emerging heavy metal antimony contaminated water based on advanced ingenious strategies.An activated modified coconut shell charcoal(CSC)was synthesized and evaluated as a substrate-supported loaded organic photovoltaic material,PM6:PYIT:PM6-b-PYIT,to prepare a surprisingly highly efficient,stable,environmentally friendly,and recyclable organic photocatalyst(CSC–N–P.P.P),which showed excellent effects on the simultaneous removal of Sb(Ⅲ)and Sb(Ⅴ).The removal efficiency of CSC-N-P.P.P on Sb(Ⅲ)and Sb(Ⅴ)reached an amazing 99.9%in quite a short duration of 15 min.At the same time,under ppb level and indoor visible light(~1 W m^(2)),it can be treated to meet the drinking water standards set by the European Union and the U.S.National Environmental Protection Agency in 5 min,and even after 25 cycles of recycling,the efficiency is still maintained at about 80%,in addition to the removal of As(Ⅲ),Cd(Ⅱ),Cr(Ⅵ),and Pb(Ⅱ)can also be realized.The catalyst not only solves the problems of low reuse rate,difficult structure adjustment and high energy consumption of traditional photocatalysts but also has strong applicability and practical significance.The pioneering approach provides a much-needed solution strategy for removing highly toxic heavy metal antimony pollution from the environment.

Research on ECMS Based on Segmented Path Braking Energy Recovery in a Fuel Cell Vehicle

Proton exchange membrane fuel cells are widely regarded as having the potential to replace internal combustion engines in vehicles.Since fuel cells cannot recover energy and have a slow dynamic response,they need to be used with different power sources.Developing efficient energy management strategies to achieve excellent fuel economy is the goal of research.This paper proposes an adaptive equivalent fuel minimum consumption strategy(AECMS)to solve the problem of the poor economy of the whole vehicle caused by the wrong selection of equivalent factors(EF)in traditional ECMS.In this method,the kinematics interval is used to update the equivalent factor by considering the penalty term of energy recovery on SOC changes.Finally,the optimized equivalent factor is substituted into the optimization objective function to achieve efficient energy regulation.Simulation results under the New European Driving Cycle show that compared with the traditional ECMS based on fixed SOC benchmarks,the proposed method improves fuel economy by 1.7%while ensuring vehicle power and increases SOC by 30%.

Antioxidant Activity of Ethyl Acetate Extract of Amomum villosum Lour.

[Objectives]To study the antioxidant activity of the ethyl acetate extract of Amomum villosum Lour.[Methods]The removal rate of chelated iron ions,hydroxyl radicals,superoxide anion free radicals and DPPH free radicals by the ethyl acetate extract of A.villosum Lour.was determined by UV spectrophotometer.[Results]0.5000μg/mL ethyl acetate extract of A.villosum Lour.had the strongest ability to chelate with ferrous ions and to remove hydroxyl radicals,superoxide anion free radicals and DPPH free radicals.The ability to chelate with ferrous ions was 95.14%,and the removal rate of the above free radicals was 86.217%,81.44%,and 85.16%.[Conclusions]The ethyl acetate extract of A.villosum Lour.had a strong antioxidant effect,and its antioxidant capacity was related to the sample concentration,which provides a theoretical basis for its application in the development of antioxidant skin care products.

Influence of Diesel Engine Intake Throttle and Late Post Injection Process on the Rise of Temperature in the Diesel Oxidation Catalyst

In order to effectively implement DPF(Diesel Particulate Filters)regeneration control,thermal management of exhaust products before and inside Diesel Oxidation Catalyst(DOC)is necessary.In the present study,the Influence of the intake throttle valve and late post injection process on temperature rise inside DOC is analyzed through engine bench tests.The steady experiment results show that adjustment of the intake throttle valve can effectively increase exhaust temperature before DOC;in particular,with intake throttle valve opening at 20%,temperature before DOC can be increased by about 170℃ with respect to the full opening.An increase in the late post injection quantity can produce a significant rise of the temperature inside DOC,however its impact on the exhaust temperature before DOC is relatively limited.As the late post injection quantity increases,Hydrocarbon(HC)emissions also grow;in the present work it is shown that with a proper injection quantity,a considerable temperature increase inside the DOC can be obtained with relatively low HC emission.More specifically,with the intake throttle valve at 30%and DOC reaching ignition temperature as the late post injection quantity is increased,the exhaust temperature after DOC can be made larger than 550℃,adequate for DPF active regeneration.

CFD Analysis and Optimization of a Diesel Engine Cooling Water Jacket

The STAR-CCM+software is used to investigate the flow inside a cooling water jacket of an in-line six-cylinder diesel engine.The results show that the average flow velocity of the cooling water inside the jacket is 1.669 m/s while the flow velocity distribution is not uniform for each cylinder.Moreover,the fluid velocity in proximity to the cylinder head is too low,thereby affecting the cooling performances of the water jacket.Two corresponding structural optimization schemes are proposed to mitigate this issue and the post-optimization performances of the water jacket are discussed in detail.

色氨酸代谢在炎症性肠病中的研究进展

炎症性肠病(inflammatory bowel disease,IBD)包括溃疡性结肠炎和克罗恩病,其发病机制与肠道菌群紊乱密切相关.肠道菌群紊乱导致的肠道微环境异常影响氨基酸的代谢.色氨酸作为人体必需氨基酸,其代谢产物参与调节免疫、神经元功能和肠道稳态等.IBD疾病的发生与发展伴随色氨酸的缺乏或代谢异常.本综述主要介绍了肠道菌群代谢物色氨酸及其代谢产物与IBD疾病发生与发展之间的关系,并为未来预测IBD疾病活动的诊断方法和治疗IBD的方案提供了新思路.

Identification of Dynamic Active Sites Among Cu Species Derived from MOFs@CuPc for Electrocatalytic Nitrate Reduction Reaction to Ammonia

Direct electrochemical nitrate reduction reaction(NITRR)is a promising strategy to alleviate the unbalanced nitrogen cycle while achieving the electrosynthesis of ammonia.However,the restructuration of the high-activity Cu-based electrocatalysts in the NITRR process has hindered the identification of dynamical active sites and in-depth investigation of the catalytic mechanism.Herein,Cu species(single-atom,clusters,and nanoparticles)with tunable loading supported on N-doped TiO_(2)/C are successfully manufactured with MOFs@CuPc precursors via the pre-anchor and post-pyrolysis strategy.Restructuration behavior among Cu species is co-dependent on the Cu loading and reaction potential,as evidenced by the advanced operando X-ray absorption spectroscopy,and there exists an incompletely reversible transformation of the restructured structure to the initial state.Notably,restructured CuN_(4)&Cu_(4) deliver the high NH_(3) yield of 88.2 mmol h^(−1)g_(cata)^(−1) and FE(~94.3%)at−0.75 V,resulting from the optimal adsorption of NO_(3)^(−) as well as the rapid conversion of^(*)NH_(2)OH to^(*)NH_(2) intermediates originated from the modulation of charge distribution and d-band center for Cu site.This work not only uncovers CuN_(4)&Cu_(4) have the promising NITRR but also identifies the dynamic Cu species active sites that play a critical role in the efficient electrocatalytic reduction in nitrate to ammonia.

TOC estimation from logging data using principal component analysis

Total organic carbon(TOC)content is one of the most important parameters for characterizing the quality of source rocks and assessing the hydrocarbon-generating potential of shales.The Lucaogou Formation shale reservoirs in the Jimusaer Sag,Junggar Basin,NW China,is characterized by extremely complex lithology and a wide variety of mineral compositions with source rocks mainly consisting of carbonaceous mudstone and dolomitic mudstone.The logging responses of organic matter in the shale reservoirs is quite different from those in conventional reservoirs.Analyses show that the traditional△logR method is not suitable for evaluating the TOC content in the study area.Analysis of the sensitivity characteristics of TOC content to well logs reveals that the TOC content has good correlation with the separation degree of porosity logs.After a dimension reduction processing by the principal component analysis technology,the principal components are determined through correlation analysis of porosity logs.The results show that the TOC values obtained by the new method are in good agreement with that measured by core analysis.The average absolute error of the new method is only 0.555,much less when compared with 1.222 of using traditional△logR method.The proposed method can be used to produce more accurate TOC estimates,thus providing a reliable basis for source rock mapping.

Host Genetic Background Impacts Microbiome Composition in Newborn Alligator

Genetic factors play a key role in determination of the structure of the cloacal flora for newborn Chinese Alligators.We collected the cloacal microbiomes for 24 newborn Chinese Alligators from three different genetic backgrounds for 16S gene amplicon sequencing.The number of cloacal flora for the Chinese Alligators from different groups was comparable but differed structurally.There were variations in proportions of floral compositions at the phylum and family levels;however,the main difference was at the genus level.There were two significant differences in richness and evenness among the three groups.Non-metric multidimensional scaling NMDS analysis revealed that the 24 samples could be clearly divided into three categories based on their genetic backgrounds(stress=0.0244).Thus,we postulated that newborn Chinese Alligators with different genetic backgrounds have different immune strengths,which affects individual responses to environmental microorganisms.In summary,newborn Chinese Alligators from different genetic backgrounds exhibit variations in cloacal microbiome.

Influence of Urea Uneven Injection on the Performances of a Diesel Engine

The influence of heterogeneous flow injection of urea at different velocities and temperatures on NO x conversion efficiency,ammonia storage and ammonia leakage is investigated experimentally.A diesel engine employing a selective catalytic reduction(SCR)technology is considered.It is found that for a fixed injection velocity,the degree of ammonia leakage changes depending on the temperature.The higher the temperature,the faster the catalytic reduction reaction and the smaller the degree of ammonia leakage.The temperature has a great influence on the catalytic reduction reaction rate.At an injection velocity of 10000/h,the average reaction rate at 420℃ is 12 times higher than that at 180℃.The injection velocity has a weak influence on the reaction rate.When the injection velocity changes from 10000/h to 40000/h at the same temperature,the average reaction rate does not change appreciably.However,increasing the space velocity can accelerate the leakage of ammonia,thereby miti-gating the benefits associated with the NO_(x) conversion.

Optimization of a Diesel Injector Nozzle

Multiphase simulations based on the VOF(Volume of Fluid)approach,used in synergy with the cavitation Schnerr-Sauer method and the K-Epsilon turbulence model,have been conducted to study the behavior of an injector nozzle as a function of relevant structural parameters(such as the spray hole diameter and length).The related performances have been optimized in the framework of orthogonal experimental design and range analysis methods.As made evident by the results,as the spray hole diameter increases from 0.10 to 0.20 mm,the outlet massflow rate grows by 243.23%.A small diameter of the spray hole,however,has a beneficial effect in terms of cavitation suppression.Moreover,rounding the spray hole can effectively increase the outlet massflow rate and improve theflow characteristics while mitigating the cavitation phenomenon inside the spray hole.In particular,with the optimized nozzle design,the outlet massflow rate can be increased by 13.33%,while the fuel vapor volume is reduced by 33.53%,thereby,leading to significant improvements in terms offlow characteristics and cavitation control.

CFD-Based Optimization of a Diesel Engine Waste Heat Recycle System

A dedicated heat exchanger model is introduced for the optimization of heavy-duty diesel engines.The model is a prerequisite for the execution of CFD simulations,which are used to improve waste heat recovery in these systems.Several optimization methods coupled with different types of working fluids are compared in terms of exergy efficiency and heat exchanger complicity.The three considered optimization methods all lead to significant improvements in the R245fa and R1233zd systems with a comparatively low evaporation temperature.The optimal R245fa system has the highest efficiency increase(77.49%).The cyclopentane system displays the highest efficiency among the optimized ORC(Organic Rankine Cycle)systems,yet achieved by using a much heavier evaporator HEC(Heat Exchanging Core).In contrast,the 96.84%efficiency increase for the optimized R1233zd is achieved with only 68.96%evaporator weight.

Acute acquired concomitant esotropia with congenital paralytic strabismus:A case report

BACKGROUND An unusual case of acute acquired concomitant esotropia(AACE)with congenital paralytic strabismus in the right eye is reported.CASE SUMMARY A 23-year-old woman presented with complaints of binocular diplopia and esotropia of the right eye lasting 4 years and head tilt to the left since 1 year after birth.The Bielschowsky head tilt test showed right hypertropia on a right head tilt.She did not report any other intracranial pathology.A diagnosis of AACE and right congenital paralytic strabismus was made.Then,she underwent medial rectus muscle recession and lateral rectus muscle resection combined with inferior oblique muscle myectomy in the right eye.One day after surgery,the patient reported that she had no diplopia at either distance or near fixation and was found to be orthophoric in the primary position;furthermore,her head posture immediately and markedly improved.CONCLUSION In future clinical work,in cases of AACE combined with other types of strabismus,we can perform conventional single surgery for both at the same time,and the two types of strabismus can be solved simultaneously.

Study of the Effects of Lower Limb Muscle Strengthening Exercises on Hospitalized Pregnant Women on Bed Rest for Prevention of Miscarriage

Objective: Against a background of the two-child policy in China, the objective is to explore the effects of lower limb strengthening exercises on hospitalized pregnant women put on bed rest for prevention of miscarriage. Method: Sixty cases of pregnant women admitted to the Department of Obstetrics in one of the highest ranking hospitals in Guangzhou, China, during the period from November 2018 to December 2019 for the purpose of preventing miscarriage were selected. They were divided into an experimental group and a control group of 30 cases each. The control group was put under routine care while the intervention group conducted lower limb muscle strengthening exercise on top of the routine care. After the intervention, the conditions of lower limbs, the psychological states and the results of pregnancy for the two groups were compared. Results: After the intervention, the scores of the experimental group in anxiety, depression and postpartum depression were lower and leg circumferences were smaller compared to the control group. The difference is statistically significant (P < 0.05). The experimental group had longer gestation than the control group and was able to get out of bed earlier than the control group after delivery, with statistically significant difference (P < 0.05). Conclusion: Lower limb muscle strengthening exercises can effectively improve the physiological and psychological states of pregnant women hospitalized for prevention of miscarriage and promote their postpartum recovery.

钙钛矿型水氧化电催化剂

在全球能源结构“清洁化”转型的背景下,可再生能源的开发与利用能够有效解决能源危机与环境问题,符合我国的可持续发展路线。能源转换与储存技术贯穿着循环能源技术的各个环节,是新型能源框架的核心支撑。水氧化反应是众多能源体系(例如,水裂解反应、二氧化碳还原反应、氮还原反应和金属-空气电池)的重要半反应,但其动力学缓慢,严重限制了设备的能源效率,阻碍了相应技术的广泛应用。因此,亟需开发具有低成本、高活性、强稳定性的水氧化电催化剂以降低反应能垒,进而推动能源转换与存储设备的工业化发展。钙钛矿型材料的晶体结构包容性强,元素组成涵盖广泛,具有丰富而独特的电子特性,易于实现表面化学与电子结构的精准调控,因此被公认为理想的催化材料设计平台。本文综述了钙钛矿型水氧化电催化剂的最新研究进展。首先介绍了钙钛矿型材料的晶体结构和电子特性,归纳了制备钙钛矿型氧化物的代表性的合成策略。通过讨论近期钙钛矿型水氧化电催化剂在酸性和碱性介质中的研究进展,强调了钙钛矿型电催化剂结构与催化性能间的构效关系。最后,我们总结了钙钛矿型水氧化电催化剂在实际应用中面临的挑战与机遇,提出了相应的建议与解决方案,期望能使读者更清晰地认识到该领域的未来发展方向。