(1-x)(K0.47sNa0.475Li0.os)(Nb0.sTa0.2)O3-xBiCoO3 (KNLNT-BC) lead-free piezoelectric ceramics were prepared by the conventional solid-state sintering method. Effects of the BC content on the phase structure, mi...(1-x)(K0.47sNa0.475Li0.os)(Nb0.sTa0.2)O3-xBiCoO3 (KNLNT-BC) lead-free piezoelectric ceramics were prepared by the conventional solid-state sintering method. Effects of the BC content on the phase structure, microstructure and electrical properties of KNLNT-BC ceramics were investigated. XRD patterns reveal that all the ceramic samples are in the pure perovskite-type structure, and the phase structure changes from the tetragonal to pseudo-cubic phase with the increase of the BC content. After the substitution of BC, the grain size is significantly reduced and relaxer behaviors are induced. By adding a small amount of BC to KNLNT ceramics, piezoelectric properties are improved, while further addition of BC makes the piezoelectric properties deteriorate markedly. The optimized electrical properties atx= 0.005 are as follows: d33 = 194 pC/N, kp = 0.44.展开更多
文摘(1-x)(K0.47sNa0.475Li0.os)(Nb0.sTa0.2)O3-xBiCoO3 (KNLNT-BC) lead-free piezoelectric ceramics were prepared by the conventional solid-state sintering method. Effects of the BC content on the phase structure, microstructure and electrical properties of KNLNT-BC ceramics were investigated. XRD patterns reveal that all the ceramic samples are in the pure perovskite-type structure, and the phase structure changes from the tetragonal to pseudo-cubic phase with the increase of the BC content. After the substitution of BC, the grain size is significantly reduced and relaxer behaviors are induced. By adding a small amount of BC to KNLNT ceramics, piezoelectric properties are improved, while further addition of BC makes the piezoelectric properties deteriorate markedly. The optimized electrical properties atx= 0.005 are as follows: d33 = 194 pC/N, kp = 0.44.