The damage characteristics of different speed sections of Cu−Cr−Zr alloy rail after simulated launch were studied.The microstructure,morphologies and properties of samples were investigated by using XRD,XPS,EBSD,SEM,h...The damage characteristics of different speed sections of Cu−Cr−Zr alloy rail after simulated launch were studied.The microstructure,morphologies and properties of samples were investigated by using XRD,XPS,EBSD,SEM,hardness test,electrochemical test and DSC techniques.It was found that deposition layers were formed on the surfaces of the simulated launch samples.The thickness and surface roughness of these deposition layers increased with increasing the heat effect,suggesting a launch speed dependent damage degree of the arc ablation.The hardness variation of samples is attributed to the effects of the deposition layer and deformation hardening.The surface deposition layer affects corrosion resistance and crystalline characteristics,leading to changes in subsequent service performances.Additionally,the surface texture and plastic deformation ability of the samples are related to the recrystallization degree and deformation grain amount.展开更多
The anisotropy of the microstructure, thermal expansion behavior, corrosion resistance and magnetic properties of AISI 1045 steel was investigated. The distribution of Fe3C lameUae in the investigation plane parallel ...The anisotropy of the microstructure, thermal expansion behavior, corrosion resistance and magnetic properties of AISI 1045 steel was investigated. The distribution of Fe3C lameUae in the investigation plane parallel to the radial directions of molds was observed to differ from that in the investigation plane perpendicular to the radial directions by transmission electron microscopy. The lattice constants a0 of α-Fe deduced from the XRD patterns of samples prepared using a sand (S)-mold and cut parallel to the radial direction of the mold (S//) and using a metal (M)-mold and cut parallel to the radial direction (M//), the corrosion resistance measured using an electrochemical work- station, and the magnetic permeability obtained by vibrating sample magnetometry also indicated the existence of anisotropy in the tested samples. The anisotropic change of corrosion potential (Eeorr), pitting potential (Epit) and magnetic permeability (μ) of the samples was observed to depend on the orientation factorF200 of α-Fe in the measured samples, which is controlled by the distribution of Fe3C lamellae in the eutectoid structure.展开更多
The mixing enthalpies and structural order in liquid Mg−Si system were investigated via ab-initio molecular dynamics at 1773 K.By calculating the transferred charges and electron density differences,the dominance of S...The mixing enthalpies and structural order in liquid Mg−Si system were investigated via ab-initio molecular dynamics at 1773 K.By calculating the transferred charges and electron density differences,the dominance of Si−Si interactions in the chemical environments around Si was demonstrated,which determined that the mixing enthalpy reached the minimum on Mg-rich side.In terms of Honeycutt and Anderson(HA)bond pairs based on the partial pair correlation functions,the attraction between Si−Si pairs and Mg atoms was revealed,and the evolution of structural order with Si content was characterized as a process of constituting frame structures by Si−Si pairs that dispersed Mg atoms.Focusing on tetrahedral order of local Si-configurations,a correlation between the mixing enthalpy and structural order was uncovered ultimately,which provided a new perspective combining the energetics with geometry to understand the liquid Mg−Si binary system.展开更多
基金the Key Research and Development Program of China(No.2022YFB2404102)the National Natural Science Foundation of China(Nos.51971093,52171158,52101196)+5 种基金the Key Research and Development Program of Shandong Province,China(Nos.2020ZLYS11,2021ZLGX01,2022CXGC020308,2023CXGC010308)the Major Innovation Projects of Shandong Province,China(Nos.2020CXGC010701,2020CXGC010702)the Young Taishan Scholars,China(No.tsqn202211184)the Shandong Provincial Natural Science Foundation,China(No.ZR2022ME137)the Yantai Science and Technology Planning Project,China(No.2021ZDCX001)the Open Project Program of Shandong Marine Aerospace Equipment Technological Innovation Center(Ludong University),China(No.MAETIC2021-11).
文摘The damage characteristics of different speed sections of Cu−Cr−Zr alloy rail after simulated launch were studied.The microstructure,morphologies and properties of samples were investigated by using XRD,XPS,EBSD,SEM,hardness test,electrochemical test and DSC techniques.It was found that deposition layers were formed on the surfaces of the simulated launch samples.The thickness and surface roughness of these deposition layers increased with increasing the heat effect,suggesting a launch speed dependent damage degree of the arc ablation.The hardness variation of samples is attributed to the effects of the deposition layer and deformation hardening.The surface deposition layer affects corrosion resistance and crystalline characteristics,leading to changes in subsequent service performances.Additionally,the surface texture and plastic deformation ability of the samples are related to the recrystallization degree and deformation grain amount.
基金financially supported by the National Natural Science Foundation of China (Nos. 51171091 and 51471099)the Excellent Youth Project of Natural Science Foundation of Shandong (No. JQ201012)the Major State Basic Research Development Program of China (No. 2012CB825702)
文摘The anisotropy of the microstructure, thermal expansion behavior, corrosion resistance and magnetic properties of AISI 1045 steel was investigated. The distribution of Fe3C lameUae in the investigation plane parallel to the radial directions of molds was observed to differ from that in the investigation plane perpendicular to the radial directions by transmission electron microscopy. The lattice constants a0 of α-Fe deduced from the XRD patterns of samples prepared using a sand (S)-mold and cut parallel to the radial direction of the mold (S//) and using a metal (M)-mold and cut parallel to the radial direction (M//), the corrosion resistance measured using an electrochemical work- station, and the magnetic permeability obtained by vibrating sample magnetometry also indicated the existence of anisotropy in the tested samples. The anisotropic change of corrosion potential (Eeorr), pitting potential (Epit) and magnetic permeability (μ) of the samples was observed to depend on the orientation factorF200 of α-Fe in the measured samples, which is controlled by the distribution of Fe3C lamellae in the eutectoid structure.
基金The authors are grateful for the financial supports from the National Key Research and Development Program of China(2016YFB0701202)the National Natural Science Foundation of China(51901117,51801116,51804190,and 11804179)the Shandong Provincial Key Research and Development Plan,China(2019GGX102047).
文摘The mixing enthalpies and structural order in liquid Mg−Si system were investigated via ab-initio molecular dynamics at 1773 K.By calculating the transferred charges and electron density differences,the dominance of Si−Si interactions in the chemical environments around Si was demonstrated,which determined that the mixing enthalpy reached the minimum on Mg-rich side.In terms of Honeycutt and Anderson(HA)bond pairs based on the partial pair correlation functions,the attraction between Si−Si pairs and Mg atoms was revealed,and the evolution of structural order with Si content was characterized as a process of constituting frame structures by Si−Si pairs that dispersed Mg atoms.Focusing on tetrahedral order of local Si-configurations,a correlation between the mixing enthalpy and structural order was uncovered ultimately,which provided a new perspective combining the energetics with geometry to understand the liquid Mg−Si binary system.