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Evolution of Mount Cameroon volcanism: Geochemistry, mineral chemistry and radiogenic isotopes(Pb, Sr, Nd)
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作者 Emmanuel Wenjeh Wembenyui kenneth d.collerson Jian-xin Zhao 《Geoscience Frontiers》 SCIE CAS CSCD 2020年第6期2157-2168,共12页
Mount Cameroon volcano has erupted several times in the 20 th Century with documented eruptions in 1909,1922,1954,1959,1982,1999 and 2000.Evidence of historic volcanism is represented by several older lava flows and l... Mount Cameroon volcano has erupted several times in the 20 th Century with documented eruptions in 1909,1922,1954,1959,1982,1999 and 2000.Evidence of historic volcanism is represented by several older lava flows and lahar deposits around the flanks of the volcano.This study aims to assess the evolution of Mount Cameroon volcanism through its eruptive history via interpretation of mineralogical,whole rock geochemical and Pb,Sr,Nd isotope data generated from historic and recent lava flows.In this study,samples were collected from the 1959,1982,1999 and 2000 eruptions and from several historic eruption sites with unknown eruption dates.Evaluation of major and trace element data demonstrates that Mount Cameroon is geotectonically associated with within-plate Ocean Island Basalt Settings.More than 90%of the studied historic lavas(n=29)classify as tephrites and basanites whereas the modern lavas(n=38)are predominantly trachybasalts,demonstrating evolution from primitive to evolved lavas over time typically in response to fractional crystallization.Petrographically,the lavas are porphyritic with main mineral phases being olivine,clinopyroxene,plagioclase feldspars and Fe-Ti-Cr oxides.The 1982 lavas are predominantly aphyric and dominated by lath-shaped flow-aligned plagioclase in the groundmass.Olivine chemistry shows variable forsterite compositions from Fo60-89.Clinopyroxenes vary from diopside through augite to titanaugite with chemical composition ranges from Wo45En32Fs7 to Wo51En47Fs17.Plagioclase feldspars vary from labradorite(An567 O)to bytownite(An80-87).For the Fe-Ti-Cr oxides,calculated ulvospinel component shows a wide variation from ulv38-87.CIPW-normative classification on the Di-Ol-Hy-Qz-Ne system shows that all Mount Cameroon lavas are nepheline-normative(Ne ranges from4.20 wt.%to 11.45 wt.%).Radiogenic isotope data demonstrate that Mount Cameroon lavas are HIMU(or high μ=238U/204Pb),characterized by 206Pb/204Pb=20.19-20.46,207Pb/204Pb=15.63-15.69,208Pb/204Pb=40.01-40.30,87Sr/86Sr=0.70322-0.70339(εsr=-21.37 to-18.96)and 143 Nd/144 Nd=0.51276-0.51285(εNd=+2.29 to+4.05).The historic lavas show stronger HIMU signature relative to the modern lavas,suggesting evolution towards less HIMU signatures over time.This study has revealed that Mount Cameroon volcanism has evolved from primitive magmas characterized by stronger HIMU signatures with high 206/204Pb and 208/204Pb isotopes,low SiO2 and high Mg,Ni,Cr content towards lower HIMU signatures with relatively higher SiO2,lower Mg,Cr and Ni compositions.The geochemical and isotopic changes,which account for the evolution of magmatism on Mount Cameroon occur over long periods of time because all the modern lavas erupted within the last 100 years are isotopically homogeneous,with very limited variation in SiO2 compositions. 展开更多
关键词 Mount Cameroon HIMU PETROGENESIS Geochemical evolution Radiogenic isotopes Mineral chemistry
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A prolonged granitoid formation in Saglek Block,Labrador:Zonal growth and crustal reworking of continental crust in the Eoarchean
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作者 Tsuyoshi Komiya Shinji Yamamoto +10 位作者 Shogo Aoki Keiko Koshida Masanori Shimojo Yusuke Sawaki Kazumasa Aoki Shuhei Sakata Takaomi D.Yokoyama Kenshi Maki Akira Ishikawa Takafumi Hirata kenneth d.collerson 《Geoscience Frontiers》 SCIE CAS CSCD 2017年第2期355-385,共31页
The Archean continental crusts account for ca.20% of the present volume,but the thermal history of the Earths' mantle suggests much more continental crusts were formed in the early Archean.Because the Archean contine... The Archean continental crusts account for ca.20% of the present volume,but the thermal history of the Earths' mantle suggests much more continental crusts were formed in the early Archean.Because the Archean continental crust underwent severe metamorphism,it is important to avoid influence by the later thermal events.We carried out a comprehensive geochronological work of Cathodoluminescence(CL) observation and U-Pb dating of zircons from orthogneisses and supracrustal rocks over the Saglek Block to obtain their protolith ages.The zircons were classified into three domains of core,mantle and rims,and the cores were further classified into three groups of inherited,altered and zoned cores based on the zonation on the CL images.We estimated the protolith ages from Pb-Pb ages of the zoned-cores of zircons with low U contents.We made a detailed sketch of a small outcrop in St.John's Harbour South(SJHS) area,and classified the orthogneisses and mafic enclaves into seven generations based on the geologic occurrence.The first and second generations comprise mafic rocks and lack magmatic zircons.We conducted CL imaging and U-Pb dating of zircons from the third,sixth and seventh generation of the orthogneisses to estimate the protolith ages at 3902 L 25,3892 ± 33 and 3897 ± 33 Ma for each,supporting the presence of the over 3.9 Ca Iqaluk Gneiss.The geological occurrence that the mafic rocks occur as enclaves within the 3.9 Ga Iqaluk Gneiss indicates that they are the oldest supracrustal rocks in the world.Our geochronological and geological studies show the Uivak Gneiss is quite varied in lithology and age from 3.6 to 〉3.9 Ga,and tentatively classified into six groups based on their ages.The oldest Uivak Gneiss components including the Iqaluk Gneiss are present around the SJHS area,and the orthogneisses become young as it is away.The lines of evidence of overprinting of younger granitoid on older granitoid in small outcrops and geological-map scale as well as presence of inherited zircons even in the oldest suite suggests that crustal reworking played an important role on erasing the ancient crusts. 展开更多
关键词 Eoarchean Geochronology Uivak Gneiss Iqaluk Gneiss Continental recycling The oldest rocks
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电感耦合等离子体质谱分析在中国古陶瓷研究中的应用 被引量:11
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作者 李宝平 赵建新 +1 位作者 kenneth d.collerson Alan Greig 《科学通报》 EI CAS CSCD 北大核心 2003年第7期659-664,共6页
用电感耦合等离子体质谱法(ICP-MS)测试了宋元时期磁州窑、吉州窑、龙泉务窑瓷胎的39种微量元素, 以探索这种在中国科技考古中尚极少使用的方法的应用前景. 发现微量元素特征明确反映了3个瓷窑不同种类的瓷胎原料及其矿物组成, 可将其... 用电感耦合等离子体质谱法(ICP-MS)测试了宋元时期磁州窑、吉州窑、龙泉务窑瓷胎的39种微量元素, 以探索这种在中国科技考古中尚极少使用的方法的应用前景. 发现微量元素特征明确反映了3个瓷窑不同种类的瓷胎原料及其矿物组成, 可将其产品明确区分. 磁州窑元代与宋金样品之间、龙泉务窑粗细两组瓷器之间的元素特征也明显不同. 磁州窑中优质仿定窑瓷器的元素特征迥异于普通产品, 说明仿定瓷胎使用了特别的原料, 并有可能在使用前进行了高于普通磁州窑瓷器的精细加工. 发现不同瓷窑以及同一瓷窑内不同类型瓷器之间元素特征的差别, 可以用元素地球化学原理进行合理的解释. ICP-MS可测试40多种微量元素, 元素分布范围广泛, 提供的信息量大, 多数元素的分析误差在2%以下, 可有效运用于中国古陶瓷研究. 展开更多
关键词 中国 古陶瓷 宋元时期 微量元素 科技考古 电感耦合等离子体质谱法 化学成分 磁州窑 吉州窑 龙泉务窑
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