To observation, poisonous gases in the environment, Sensors with high selectivity, high response and low operating temperature are required. In this work, pure SnO<sub>2</sub> nanoparticles w<span>&l...To observation, poisonous gases in the environment, Sensors with high selectivity, high response and low operating temperature are required. In this work, pure SnO<sub>2</sub> nanoparticles w<span><span><span style="font-family:;" "="">as</span></span></span><span><span><span style="font-family:;" "=""> prepared by using a simple and inexpensive technique </span></span></span><span><span><span style="font-family:;" "="">(</span></span></span><span><span><span style="font-family:;" "="">hydrothermal method</span></span></span><span><span><span style="font-family:;" "="">)</span></span></span><span><span><span style="font-family:;" "=""> without a template. Various confirmatory tests were performed to characterize SnO<sub>2</sub> nanoparticles such as energy</span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "="">dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Scan<span>ning Electron Microscopy (SEM) and Transition Electron Microscopy</span> (TEM), during the detection of the gas, we found that p</span></span></span><span style="font-family:Verdana;"></span><span><span><span style="font-family:;" "="">ure SnO<sub>2</sub> nanoparticles ha</span></span></span><span><span><span style="font-family:;" "="">s</span></span></span><span><span><span style="font-family:;" "=""> a high selectivity for ethanol to 100 ppm at a low temperature (180</span></span></span><span><span><span style="font-family:;" "="">°C<span>) and a high response (about 27</span></span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "="">s) and a low detection limit of 5 ppm, also it<span style="color:red;"> </span>h</span></span></span><span><span><span style="font-family:;" "="">ave</span></span></span><span><span><span style="font-family:" color:red;"=""> </span></span></span><span><span><span style="font-family:;" "="">response/recovery times about (4</span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "="">s, 2</span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "="">s) respectively. The distinctive sensing properties of SnO<sub>2</sub> sensor make it a promising candidate for ethanol detection. Furthermore, the gas-sensing mechanism have been examined.</span></span></span>展开更多
Fluorescent silicon quantum dots(Si QDs)were hydrothermally synthesized from a mixture of 3(2-aminoethylamino)propyl(dimethoxymethylsilane)(AEAPDMMS)and poly(vinylpyrrolidine)(PVP).The resulting Si QDs exhibited good ...Fluorescent silicon quantum dots(Si QDs)were hydrothermally synthesized from a mixture of 3(2-aminoethylamino)propyl(dimethoxymethylsilane)(AEAPDMMS)and poly(vinylpyrrolidine)(PVP).The resulting Si QDs exhibited good water solubility and high stability.Under the optimized conditions,the probe revealed an excellent linear fluorescence quenching effect on Co2+ranging from 1μmol/L to 120μmol/L with a limit of detection of 0.37μmol/L(based on 3 s/k).The quenching mechanism was studied,showing that static quenching(SQE)causes the main effect.Furthermore,the test paper based on Si QDs was prepared,which is cost-effective,high sensitivity,good selectivity,easy to use and show excellent anti-interference capability.This method was applied to analyze the content of Co2+in environmental water samples with satisfying results.展开更多
文摘To observation, poisonous gases in the environment, Sensors with high selectivity, high response and low operating temperature are required. In this work, pure SnO<sub>2</sub> nanoparticles w<span><span><span style="font-family:;" "="">as</span></span></span><span><span><span style="font-family:;" "=""> prepared by using a simple and inexpensive technique </span></span></span><span><span><span style="font-family:;" "="">(</span></span></span><span><span><span style="font-family:;" "="">hydrothermal method</span></span></span><span><span><span style="font-family:;" "="">)</span></span></span><span><span><span style="font-family:;" "=""> without a template. Various confirmatory tests were performed to characterize SnO<sub>2</sub> nanoparticles such as energy</span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "="">dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD), Scan<span>ning Electron Microscopy (SEM) and Transition Electron Microscopy</span> (TEM), during the detection of the gas, we found that p</span></span></span><span style="font-family:Verdana;"></span><span><span><span style="font-family:;" "="">ure SnO<sub>2</sub> nanoparticles ha</span></span></span><span><span><span style="font-family:;" "="">s</span></span></span><span><span><span style="font-family:;" "=""> a high selectivity for ethanol to 100 ppm at a low temperature (180</span></span></span><span><span><span style="font-family:;" "="">°C<span>) and a high response (about 27</span></span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "="">s) and a low detection limit of 5 ppm, also it<span style="color:red;"> </span>h</span></span></span><span><span><span style="font-family:;" "="">ave</span></span></span><span><span><span style="font-family:" color:red;"=""> </span></span></span><span><span><span style="font-family:;" "="">response/recovery times about (4</span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "="">s, 2</span></span></span><span><span><span style="font-family:;" "=""> </span></span></span><span><span><span style="font-family:;" "="">s) respectively. The distinctive sensing properties of SnO<sub>2</sub> sensor make it a promising candidate for ethanol detection. Furthermore, the gas-sensing mechanism have been examined.</span></span></span>
基金the National Natural Science Foundation of China(Nos.21874060,22074057 and 21775059).
文摘Fluorescent silicon quantum dots(Si QDs)were hydrothermally synthesized from a mixture of 3(2-aminoethylamino)propyl(dimethoxymethylsilane)(AEAPDMMS)and poly(vinylpyrrolidine)(PVP).The resulting Si QDs exhibited good water solubility and high stability.Under the optimized conditions,the probe revealed an excellent linear fluorescence quenching effect on Co2+ranging from 1μmol/L to 120μmol/L with a limit of detection of 0.37μmol/L(based on 3 s/k).The quenching mechanism was studied,showing that static quenching(SQE)causes the main effect.Furthermore,the test paper based on Si QDs was prepared,which is cost-effective,high sensitivity,good selectivity,easy to use and show excellent anti-interference capability.This method was applied to analyze the content of Co2+in environmental water samples with satisfying results.